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Articles 1 - 14 of 14
Full-Text Articles in Physical Sciences and Mathematics
Hammett Correlations Of The Amide Proton Chemical Shift In A Series Of 1-Tosyl-3-(4-Substituted Phenyl)Ureas, Frank L. Setliff, Melody K. Harrison
Hammett Correlations Of The Amide Proton Chemical Shift In A Series Of 1-Tosyl-3-(4-Substituted Phenyl)Ureas, Frank L. Setliff, Melody K. Harrison
Journal of the Arkansas Academy of Science
No abstract provided.
Double Cysteine Mutations In Staphylococcal Nuclease: The Effect Of Artificially Introduced Disulfide Bonds On Protein Structure And Stability, Anna Terry
Inquiry: The University of Arkansas Undergraduate Research Journal
Since a protein's function depends on its structure, basic research in protein structure facilitates the solution of many practical problems, such as the synthesis of more effective medicines. With this larger goal in sight, the purpose of this research project is to understand better the chemical principles that underlie protein structure and stability. Disulfide bonds are a potentially stabilizing feature of many proteins. They may form between cysteine residues in close proximity to one another if the orientation is favorable. Often found in proteins produced by organisms that grow at high temperatures, disulfide bonds may anchor side chains together, making …
Design, Implementation, And Evaluation Of Virtual Interface Architecture For Power Pc Machines, Ben Mckenzie
Design, Implementation, And Evaluation Of Virtual Interface Architecture For Power Pc Machines, Ben Mckenzie
Inquiry: The University of Arkansas Undergraduate Research Journal
The Virtual Interface Architecture (VIA) standard is a low-latency protocol that was designed for use in high-performance networks. VIA improves performance by reducing overhead in messaging. This research has two components. The first part of this research project is the development of a new tool for measuring the performance of a VIA implementation and comparing it to the more traditional high-overhead protocols used on the Internet. The development of the tool represents a significant contribution in and of itself, since the tool has been put into the public domain and will likely become useful by Lima users, both for measuring …
An Analysis Of The Theory Of Functions Of One Real Variable, Robert J. Reed
An Analysis Of The Theory Of Functions Of One Real Variable, Robert J. Reed
Inquiry: The University of Arkansas Undergraduate Research Journal
Few undergraduates are aware that the Riemann integral taught in introductory calculus courses has only limited application-essentially this integral can be used only to integrate continuous functions over intervals. The necessity to integrate a broader class of functions over a wider range of sets that arises in many applications motivates the theory of abstract integration and functional analysis. The founder of this theory was the French mathematician Henri Lebesgue, who in 1902 defined the "Lebesgue measure" of subsets of the real line. The purpose of this project is to elucidate the theory of abstract measure spaces and of important spaces …
Hypothetical Origins Of Paleozoic Fossils From The Gulf Coastal Plain Of Arkansas, Karen Arbuckle
Hypothetical Origins Of Paleozoic Fossils From The Gulf Coastal Plain Of Arkansas, Karen Arbuckle
Journal of the Arkansas Academy of Science
A fauna of reworked Paleozoic fossils has been found in chert pebbles from the Gulf Coastal Plain in eastern Columbia County, Arkansas, although the nearest mapped exposure of Mississippian and Pennsylvanian rocks are fifty-five miles northward in the southern edge of the Ouachita Mountains. The surficial rocks at the collection site have been referred to the Claiborne Group of Eocene age by the authors of the geological map of Arkansas. Additional outcrops containing similar Paleozoic fossils have been found within a 15-mile radius. The fauna includes both lacy and twig-like bryozoans, articulate brachiopods, tabulate and rugose corals, stalked echinoderms, gastropods, …
Physicochemical Characteristics And Macroinvertebrate Assemblages Of Riffles Upstream And Downstream Of A Streambank Impacted By Unrestricted Cattle Access, Ronald L. Johnson, Daniel D. Ward, Richard S. Grippo
Physicochemical Characteristics And Macroinvertebrate Assemblages Of Riffles Upstream And Downstream Of A Streambank Impacted By Unrestricted Cattle Access, Ronald L. Johnson, Daniel D. Ward, Richard S. Grippo
Journal of the Arkansas Academy of Science
Riparian zones are important contributors to stream ecosystem health. Alteration of such areas can change stream structure and function, resulting in modified productivity and hydrologic patterns. We studied two riffle sites on the South Fork of the Spring River in Fulton County, AR upstream and downstream of a streambank ostensibly degraded by unrestricted cattle access. The two sites were measured for differences in physical habitat (including bank width, stream velocity, depth, substrate composition, and embeddedness), chemical characteristics (including dissolved oxygen, pH, conductivity, turbidity and total suspended solids) and biological characteristics (including benthic macroinvertebrate community composition, similarity, and standing crop). Measurements …
Wave Profile For Antiforce Class Ii Waves, Rory Roberts, Mostafa Hemmati
Wave Profile For Antiforce Class Ii Waves, Rory Roberts, Mostafa Hemmati
Journal of the Arkansas Academy of Science
Breakdown waves propagating in the opposite direction of the applied electric field force are referred to as antiforce waves. Breakdown waves moving into a pre-ionized medium are referred to as Class II waves. Using a one-dimensional, steady state, three-fluid, hydrodynamical model and considering the electrons as the main element in propagation of ionizing waves, we have derived the proper boundary conditions for antiforce waves moving into a preionized medium. Using the new boundary conditions and for several current values ahead of the wave, the set of electron fluid dynamical equations (equations of conservation of mass, momentum, and energy coupled with …
Large Pleistocene Box Turtle From Southwest Arkansas, Leo Carson Davis, John G. Scoggins, J. Alan Holman
Large Pleistocene Box Turtle From Southwest Arkansas, Leo Carson Davis, John G. Scoggins, J. Alan Holman
Journal of the Arkansas Academy of Science
No abstract provided.
Versatile Apparatus For Measuring Kinetics Of Gaseous Reactions By A Relative Method, Edmond W. Wilson Jr., Holly A. Sawyer, Amber A. Sawyer
Versatile Apparatus For Measuring Kinetics Of Gaseous Reactions By A Relative Method, Edmond W. Wilson Jr., Holly A. Sawyer, Amber A. Sawyer
Journal of the Arkansas Academy of Science
It is important that accurate, reproducible values for the rates of chemical reactions occurring in the atmosphere be obtained. The value of accurate kinetics measurements is to improve the accuracy of mathematical models used to forecast the state of the atmosphere. We describe a versatile, robust apparatus for obtaining atmospheric reaction rate values and their temperature dependencies by a relative method. This relative method has the advantage over absolute methods in that errors due to impurities and adsorption on walls of the reaction apparatus are minimized. In addition, relative values serve as an important verification for absolute values. The apparatus …
Preparation Of An Electrophilic 3-Methylindole Derivative: Difficulties In Forming A Stable, Suitable Material For The Preparation Of Tryptophan, Jason Boggs, Mariah Mcmasters, Robert W. Curley Jr., Michael J. Panigot
Preparation Of An Electrophilic 3-Methylindole Derivative: Difficulties In Forming A Stable, Suitable Material For The Preparation Of Tryptophan, Jason Boggs, Mariah Mcmasters, Robert W. Curley Jr., Michael J. Panigot
Journal of the Arkansas Academy of Science
In an attempt to prepare stereoselectively beta-deuterated tryptophan, N-protected indole-3-methanol compounds were prepared with model studies being done on undeuterated material. Conversion of these compounds to electrophilic species proved exceptionally difficult and resulted in very low yields or recovered starting material only. A summary of the current results utilizing N-tosyl indole-3-methanol will be presented as well as efforts using N-Boc indole-3-methanol.
Reaction Of Alpine-Borane With Aldehydes: Reactivity Rate Assessment By Observation Of The Disappearance Of The Carbonyl N - Pi* Peak By Uv-Visible Spectroscopy, Layla Bland, Michael J. Panigot
Reaction Of Alpine-Borane With Aldehydes: Reactivity Rate Assessment By Observation Of The Disappearance Of The Carbonyl N - Pi* Peak By Uv-Visible Spectroscopy, Layla Bland, Michael J. Panigot
Journal of the Arkansas Academy of Science
Due to an unexpectedly difficult reduction of indole-3-carbaldehyde and of isobutyraldehyde using the chiral reducing agent Alpine-Borane, the reactivity of several aliphatic, aromatic, and unsaturated aldehydes was investigated. This was done in order to determine whether there was a relationship between aldehyde structure and reduction rate. It was found that aliphatic aldehydes and aromatic aldehydes with no strongly electron-donating groups on the arene ring reduced faster than unsaturated aldehydes.
Hammett Correlations Of The Sulfonamide Proton Chemical Shift In A Series Of N-(Substituted Aryl)-P-Toluenesulfonamides, Frank L. Setliff, Tyson K. Spradlin
Hammett Correlations Of The Sulfonamide Proton Chemical Shift In A Series Of N-(Substituted Aryl)-P-Toluenesulfonamides, Frank L. Setliff, Tyson K. Spradlin
Journal of the Arkansas Academy of Science
No abstract provided.
Study Of The Amplitude Of Pressure And Thrust Oscillations In A Lab-Scale Hybrid Rocket, Ann Wright, Lawrence Dunn, Brian Alford, Justin Patton, M. Keith Hudson
Study Of The Amplitude Of Pressure And Thrust Oscillations In A Lab-Scale Hybrid Rocket, Ann Wright, Lawrence Dunn, Brian Alford, Justin Patton, M. Keith Hudson
Journal of the Arkansas Academy of Science
Hybrid rockets are being studied as a potential replacement for the solid rocket boosters on the NASA space shuttle. One physical characteristic of hybrid rockets that must be understood and overcome is potentially severe pressure oscillations during combustion. Pressure oscillations inside the rocket combustion chamber lead to oscillations in the thrust of the rocket. These oscillations are damaging to potential human passengers and cargo and must be minimized. Current theories surmise that the oscillations are caused by combustion chamber geometry, oxygen feed line parameters, and/or fuel combustion characteristics. This study focuses on the role of the fuel characteristics in pressure …
Studies Of Tryptophans In Membrane- Spanning "Walp" Peptides By Deuterium Nmr Spectroscopy, Nichole Reed
Studies Of Tryptophans In Membrane- Spanning "Walp" Peptides By Deuterium Nmr Spectroscopy, Nichole Reed
Inquiry: The University of Arkansas Undergraduate Research Journal
WALP pep tides of sequence acetyl-Gly-Trp-Trp-(Leu-Ala)-Trp-Trp-Ala-ethanolamine insert into lipid bilayers as membrane-spanning a-helices and modulate the lipid phase behavior as functions of n and the lipid acyl chain length. A key feature of the WALP peptides is the positioning of tryptophan (Trp) indole rings at the membrane/water interface. For the examples WALP19 with n = 6.5 and WALP23 with n = 8.5, we have labeled individual indoles with deuterium and incorporated the labeled peptides in oriented, hydrated bilayers of Dimyristoyl-phosphatidylcholine (DMPC). Deuterium NMR spectra from these samples show sharp resonances when the membrane normal is aligned either parallel (Beta = …