Physical Sciences and Mathematics Commons^™

Hydrogeology And Chemical Characterization Of Hydrocarbon In Domestic Water Wells, Rancho Villa Subdivision, Rogers, Arkansas, Janelle Renee Sherman

Graduate Theses and Dissertations

This project is centered on the Rancho Villa community in Rogers, Arkansas where several residents have had hydrocarbon contamination in their domestic water wells. The goal of this project was to understand the hydrogeology in the study area, characterize the contaminant chemically, and determine the source of the contaminant. The hydrogeology of the area was determined from previous theses. Seventeen samples were taken from the wells in the Rancho Villa community; each sample was analyzed for geochemical parameters and by Gas Chromatography/Mass Spectrometry (GC/MS) for organic compounds analysis. Four of the 17 samples had a visible non-aqueous layer of hydrocarbon …

Infrared Spectra Analysis Of Thermally Altered Iron Phyllosilicates And The Implications For Mars, William Thomas Bryan

Graduate Theses and Dissertations

This study looks at two iron-rich phyllosilicates, which may be present on Mars. The minerals, greenalite and hisingerite, are rich in iron-II and iron-III, respectively. Small samples (~0.40 grams) of each mineral were crushed and heated in a Lindberg Tube Oven for approximately twenty-four hours at temperatures selected to mimic lava flows and impact events. Following heating, each sample was placed in a Fourier Transform Infrared (FT-IR) spectrometer to collect the near- and mid-infrared spectra. The spectra allowed for these terrestrial analogs to be analyzed with regards to how their structure breaks down with increasing temperature. The samples' colors were …

Long-Term Residue And Water Management Effects On Soil Respiration And Soil Aggregate Stability In A Wheat-Soybean, Double-Crop System In Eastern Arkansas, Sharon Faye Smith

Graduate Theses and Dissertations

Sustainability in agriculture is paramount to assuring continued production from our most naturally fertile soils. Storing carbon (C) in soil as organic matter through sustainable agricultural management practices can both remove atmospheric C and improve soil quality. The objective of this study was to evaluate the long-term effects of water management (irrigation and dryland), residue management [burn and no-burn, conventional (CT) and no-tillage (NT)] and residue/fertility level (high and low) on soil respiration and aggregate stability in a wheat- (Triticum aestivum L.) soybean [Glycine max (L.) Merr.], double-crop system in a silt-loam soil (Aquic Fraglossudalf) in the Mississippi River Delta …

Bedrock Geological Map Of The Rockhouse Quadrangle, Carroll And Madison Counties, Arkansas, Douglas Eben Jones

Graduate Theses and Dissertations

A digital geologic map of the Rockhouse quadrangle, Carroll and Madison counties, Arkansas, was created on a 1:24,000 scale using ArcMap 10 and Photoshop CS4. The data obtained in the field are digitized onto the United States Geological Survey (USGS) digital raster graphic (DRG) of the Rockhouse quadrangle. The geology in the Rockhouse quadrangle consist entirely of sedimentary rocks that are Paleozoic ranging from Lower Ordovician to Mississippian in age. The Ordovician System is represented by the Cotter, Powell, Everton, and St. Peter Formations. The Cotter and Powell are the prominent bluff forming units throughout the quadrangle and along the …

Quantitative Trait Loci Associated With Waterlogging Tolerance In A Soft Red Winter Wheat Mapping Population, Diana Carolina Ballesteros Benavides

Graduate Theses and Dissertations

Waterlogging is caused when water stays superficially in the soil for an extended period of time, creating an anaerobic environment which decreases plant growth and grain yield at maturity. Despite the impact of waterlogging on wheat production both globally and in the southeastern U.S., very little is known about the genetic control of waterlogging tolerance in wheat. The objective of this study was to determine the amount of genetic variation for vegetative stage waterlogging tolerance present within a wheat recombinant inbred line (RIL) population and to identify quantitative trait loci (QTL) associated with tolerance and productivity. Experiments were carried out …

Sedimentary Provenance Of The Wedington Member, Fayetteville Shale, From Age Relations Of Detrital Zircons, William Tyson Cains

Graduate Theses and Dissertations

U-Pb geochronology of detrital zircons collected from the Chesterian Wedington Sandstone allows interpretation of sediment provenance and dispersal patterns in the southern midcontinent during the Late Mississippian. Detrital zircons analyzed from six samples of Wedington Sandstone yielded a final result of 565 concordant analyses used for interpretation. Results are plotted as Probability-Density Plots to interpret the spectrum of ages. Significant peaks occurred at 350-500 Ma, 950-1250 Ma, 1300-1500 Ma, 1600-1800 Ma, 1800-2300 Ma, and >2500 Ma. These peaks are interpreted as sourced by crystalline rocks within the Laurentian craton from Taconic-Acadian, Grenville, Midcontinent Granite-Rhyolite, Yavapai-Mazatzal, Paleoproterozoic, and Superior Provinces. The …

Insights Into The Timing, Origin, And Deformation Of The Highland Mountains Gneiss Dome In Southwestern Montana, Usa, Lane Markes Boyer

Graduate Theses and Dissertations

The Highland Mountains of southwestern Montana offer a unique view of the Archean igneous and metamorphic rocks within the Great Falls tectonic zone (GFTZ). A Paleoproterozoic structural gneiss dome has been interpreted in the southern extent of the Highland Mountains. The ∼ 130km² of exhumed metamorphic rocks and gneiss dome exposed in the Highland Mountains are the primary focus of this research. The formation of the Highland Mountains gneiss dome is proposed to be directly related to a northwest-side down detachment (the Steels Pass shear zone) that formed during terrane collision along the GFTZ. The field investigation determined foliation …

Analysis Of Tripolitic Chert In The Boone Formation (Lower Mississippian, Osagean), Northwest Arkansas And Southwestern Missouri, Paul Marchand Minor

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas and southwestern Missouri exposes a nearly complete sequence of Lower Mississippian chert-bearing carbonates deposited by a single 3rd order transgression and regression. An abundant amount of chert that has replaced limestone highlights the Boone, but little is understood about the timing and development of chert in Lower Mississippian carbonates. Interpretation of the diagenetic history of the chert, in particular tripolite, has significant implications beyond the outcrop. Determining the origin, timing, and extent of tripolitic chert in the Lower Mississippian System improves reservoir characterization in subsurface petroleum reservoirs in the mid-continent that are laterally equivalent …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

A Geomechanical Study Of The Mississippian Boone Formation, Karen Nicole Mason Buckland

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas is a chert-limestone sequence analogous to the subsurface Mississippi Lime reservoir in parts of Oklahoma and Kansas. It has low permeability and produces via horizontal drilling and hydraulic fracturing. The response to stimulation by fracturing is dependent on the quantity of chert in the area. Chert nodules and laterally extensive chert layers in the sequence are variable. Locally, cm- to dm-scale chert bedding is continuous and comprises up to 50% of the outcrop. Elsewhere, the chert is nodular and intermittent.

Samples collected from representative outcrops spanning the thickness and aerial extent of the formation …

Biodiesel Transesterification Byproducts As Soil Amendments, Solomon Parker

Graduate Theses and Dissertations

For every ten kilograms of biodiesel that is produced from the transesterification of vegetable oil, approximately 1 kg of glycerol is produced as a byproduct. Also known as glycerin, it is a chemical used in many products including cosmetics, foods, and desiccants. However, the crude glycerol created during biodiesel production is tainted with potassium hydroxide and methanol making it unsuitable for commercial use without costly refinement. With increase in production of biodiesel driven by rising fuel prices, the market has become glutted with glycerol and it is on the threshold of becoming a waste product. Common methods for disposing glycerol …

Litter Conditioning Is Differentially Affected By Leaf Species, Phosphorus Enrichment, And Light Availability, Erin E. Scott

Graduate Theses and Dissertations

Anthropogenic enrichment of nitrogen and phosphorus is one of the most pervasive and detrimental threats to aquatic ecosystems worldwide. In streams that rely on allochthonous basal food resources, such as leaves, nutrient pollution can result in altered food quality and decreased carbon (C) standing stocks. However, the magnitude and mechanisms of this change in quality are poorly understood. Laboratory microcosm studies were conducted to 1) quantify the response of litter C:P to a gradient of phosphorus (P) enrichment (0, 0.05, and 0.5 mg SRP/L) across leaf species with variable levels of degradability (sugar maple and oak), and 2) quantify the …

Magnesium Isotopic Compositions Of The Moon And Achondrites: Implications For Their Origin And Evolution, Fatemeh Sedaghatpour

Graduate Theses and Dissertations

The main objectives of this thesis are to estimate Mg isotopic compositions of the Moon and achondrites, to understand the behavior of Mg isotopes during magmatic differentiation processes in different planetary bodies, and to evaluate the extent of Mg isotopic heterogeneity in the solar system. In order to achieve these goals, Mg isotopes have been measured for 47 well-characterized lunar samples and 22 differentiated meteorites by MC-ICPMS. The limited Mg isotopic variations among mare and highland regolith, mare breccias, and highland impact-melt rocks reflect negligible Mg isotope fractionation during lunar surface processes (e.g. solar wind, cosmic rays, micrometeorite bombardments, meteorite …

Breckenridge Shelter Geoarchaeology, Trevor John Seekamp

Graduate Theses and Dissertations

My graduate research mainly focuses on Breckenridge Shelter (3CR002), Carroll County, Arkansas. As a geoarchaeologist, my concerns are geomorphological and geological processes affecting the shelter and surrounding hill slope. Breckenridge is one of several similar, Pine Hollow bluff shelters, about Beaver Lake, an impoundment of the White River, in northwest Arkansas.

Subsurface Stratigraphy And Characterization Of Mississippian (Osagean To Meramecian) Carbonate Reservoirs Of The Northern Anadarko Shelf, North-Central Oklahoma, Brett Robert Wittman

Graduate Theses and Dissertations

Mississippian carbonate strata of the midcontinent contain prolific oil and gas reservoirs. Production from these carbonates has been primarily from two reservoir types, the Mississippi "chat" and recently denser chert-rich mudstone intervals. The"chat" interval is a high porosity chert residuum associated with the both the Osagean and basal Pennsylvanian unconformity. The distribution of the "chat" reservoir is discontinuous and heterogeneous. Recent horizontal drilling successes have reinvigorated academic and industry interest in the Lower Mississippian. Much of the activity is now targeting lower porosity, cherty, mudstone intervals of the Reeds Spring and Cowley Formations, which were previously considered to be non-economic. …

Variability In The Hydraulic Conductivity Of A Test Pad Liner System Using Different Testing Techniques, Matthew Jonathan Nanak

Graduate Theses and Dissertations

Historic methods (the time lag approach, the velocity approach, and the Z-t approach), utilized to reduce two stage borehole test data, were evaluated. Two of the historic methods provided viable results and were used for this research project. Additionally, these two methods are recommended for reducing two stage borehole test data in the future.

Flexible wall permeameter and soil index laboratory testing were conducted on the soil used to construct three environmentally controlled compacted clay liners (test pads) to develop a zone of acceptance (placement window). Using the results from the laboratory testing, two acceptance criterions were evaluated, while one …

Classification Of Satellite Time Series-Derived Land Surface Phenology Focused On The Northern Fertile Crescent, Brian Embree Bunker

Graduate Theses and Dissertations

Land surface phenology describes events in a seasonal vegetation cycle and can be used in a variety of applications from predicting onset of future drought conditions, to revealing potential limits of historical dry farming, to guiding more accurate dating of archeological sites. Traditional methods of monitoring vegetation phenology use data collected in situ. However, vegetation health indices derived from satellite remote sensor data, such as the normalized difference vegetation index (NDVI), have been used as proxy for vegetation phenology due to their repeated acquisition and broad area coverage. Land surface phenology is accessible in the NDVI satellite record when images …

Geophysical Surveys And Archaeological Insights At Fort Pierre Chouteau A Frontier Trading Post On The Middle Missouri, Margaret Maurine Patton

Graduate Theses and Dissertations

Fort Pierre Chouteau in present day South Dakota was the most important fur trading post of the American Fur Company in the 1830s, serving as a regional hub for the fur trade. The Fort was sold to the U.S. Military in 1855 for use as a base in the Sioux Wars but was abandoned in 1856. Geophysical surveys and previous excavations indicate evidence of both occupations. Geophysics is an important tool for determining the extent of archaeological sites, yet the relationships between geophysical anomalies and excavation features may not be readily evident. Initial geophysical surveys (Kvamme 2007) were completed to …

Groundcover Management System And Nutrient Source Impact Physical Soil Quality Indicators In An Organically Managed Apple Orchard, Neal Mays

Graduate Theses and Dissertations

In March 2006, four groundcover management systems (GMS) and two nutrient sources (NS) were implemented for their ability to alter the soil physical condition of a newly established, organically managed apple (Malus x domestica Borkh.) orchard. Annual applications of municipal green compost (GC), shredded office paper (SP), wood chips (WC), and mow-blow (MB) grass mulch were utilized as GMS, and NS supplied to trees were from composted poultry litter (PL), a commercial organic fertilizer (CF), or an untreated control (NF) in a 4x3 factorial study. An established, conventionally-managed orchard was located adjacent to the organic research orchard on the same …

Influence Of Organic Groundcovers On Mycorrhizal Colonization And Symbiosis Of Organically Managed Fruit Crops, Raven Anai Bough, Curt R. Rom

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Ground covers have the potential to impact the crop rhizosphere biology, which includes organisms such as arbuscular mycorrhizal fungi (AMF), which in turn affect the crop host plant through symbiosis. There has been evidence that a ground cover that provides a suitable environment for colonization of AMF and subsequent symbiosis could be a tool in organic fruit production. The objective of this research was to compare colonization of AMF in strawberry plant (Frageria x ananassa cv. Radiance) and apple rootstocks (Malus x domestica, cv. M. 26) grown in a greenhouse affected by various ground cover treatments. Inoculation was achieved by …

The Influence Of Poultry Litter Biochar On Early Season Cotton Growth, Taylor D. Coomer, David E. Longer, Derrick M. Oosterhuis, Dimitra A. Loka

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Cotton is known for being sensitive to cool, wet soils, especially in the early stages of growth. Amendments to soil can aid cotton seedlings in development and nutrient uptake. However, soil amendments can be costly and detrimental to the environment, and alternatives such as the addition of biochar have been considered. Biochar is produced from biomass that has gone through pyrolysis and has been shown to improve plant yield, microbial response, soil structure, soil cation–exchange capacity, and water use efficiency. This study was conducted to evaluate the effect of biochar on early season cotton growth. The aim of this study …

Evaluation Of Cover Crops In High Tunnel Vegetable Rotation, Tyler A. Patrick, Neal Mays, Jason Mcafee, Curt R. Rom

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Organic vegetable production within high tunnels allows for an extended growing season, crop protection, and environmental control. The USDA National Organic Program (NOP) standards mandate evidence that the soil has been maintained and improved over the course of production. Previous studies have indicated the potential of cover crops for reducing competitive vegetation, and improving soil quality, thus resulting in greater plant growth, nutrient uptake, and yield. However, there has been limited work in the confines of high tunnels as part of a tunnel-system rotation. Ten nitrogen-fixing and ten non-legume cover crops were established under a high tunnel and evaluated for …

Distribution Of Soil Density At A Bottomland Hardwood Forest Wetland Restoration, Chicot County, Arkansas, B. E. Sleeper, Robert L. Ficklin

Journal of the Arkansas Academy of Science

Bottomland hardwood forest (BLHF) soils provide a myriad of ecosystem services, yet much information is lacking with respect to how soil physical properties influence biogeochemical cycling along topographic gradients. Current patterns of vegetation at a 149ha wetland restoration site in Chicot County, Arkansas, suggest the presence of ecologically significant variation in soil properties within the Perry Clay soil series. A study was initiated in the Lower Mississippi Alluvial Valley (LMAV) to map soil bulk density and texture as well as to identify the interrelationships between soil physical properties, soil organic carbon, and total nitrogen. A random grid was used to …

Morphometric Analysis Of Dinosaur Tracks From Southwest Arkansas, R. Shell, Stephen K. Boss

Journal of the Arkansas Academy of Science

Dinosaur trackways were discovered in Cretaceous De Queen Limestone strata in Howard County, Arkansas, in June 2011. Multiple trackways with variably sized tridactyl tracks were exposed in a commercial quarry, suggesting multiple theropod species or adult and juvenile tracks of a single species. Results of morphometric analyses of 32 plaster casts from selected trackways are reported in an effort to identify the specific track-making dinosaurs and differentiate large and small tracks. Track measurements included length and width of each track, the lengths and widths of each digit impression, and the angular spread (divarication) between digit impressions. Twenty-nine plaster casts were …