Physical Sciences and Mathematics Commons^™

Effects Of Increasing Temperature And Acidification On The Growth And Competitive Success Of Alexandrium Catenella From The Gulf Of Maine, Drajad Seto

Electronic Theses and Dissertations

The increases in ocean temperature and pCO2 due to climate change are projected to affect the growth and future prevalence of Harmful Algal Blooms (HABs) in nearshore waters, but systematic studies on the effects these climate drivers have on harmful algal species are lacking. In particular, little is known about how future climate scenarios will affect the growth of the toxic dinoflagellate Alexandrium catenella, which produces the toxins responsible for paralytic shellfish poisoning (PSP) that threaten the health and economy of coastal communities in the Gulf of Maine. I examined growth responses of A. catenella and two other naturally co-occurring …

Investigations Into The Advancement Of Cryptotephra Geochemical Fingerprinting, Laura Hartman

Electronic Theses and Dissertations

The primary purpose of this work is to advance new sample preparation and analytical methods for ice core tephrochronology. When a volcanic source can be accurately identified using volcanic glass particle geochemistry, it may provide a robust time reference for the ice core’s timescale. The presence of an identifiable tephra layer may also suggest atmospheric pathways at the time of deposition, or assist in reconstructing volcanic forcing of climactic state for a specific event. One of the perpetual challenges in ice core based tephrochronological work is measuring the geochemical composition of ultra-fine particles (<10 >μm). Not only is it difficult …

Controls On Phosphorus Export From An Agricultural Watershed: Amsden Brook, Fort Fairfield, Maine Usa., Gregory J. Mcdonald

Electronic Theses and Dissertations

This study explores the sources and mechanisms of phosphorus (P) mobilization during base flow within the Amsden Brook watershed, Fort Fairfield, Maine, USA. Amsden Brook is an agriculturally dominated watershed drained by a spring-fed and perennial first- to second-order stream. We characterized the P concentrations within the watershed to investigate connections between soils, stream sediment, surface water, and groundwater. Waters were monitored monthly during the 2017 snow-free period for temperature, pH, dissolved oxygen, conductivity, soluble reactive P (SRP), total P, strong acid anions, strong base cations, dissolved organic carbon (DOC), Al, Fe, and Mn. Phosphorus speciation within soils and sediment …

Remote Sensing Of Icebergs In Greenland's Fjords And Coastal Waters, Jessica Scheick

Electronic Theses and Dissertations

Increases in ocean water temperature are implicated in driving recent accelerated rates of mass loss from the Greenland Ice Sheet. Icebergs provide a key tool for gaining insight into ice-ocean interactions and until recently have been relatively understudied. Here we develop several methods that exploit icebergs visible in optical satellite imagery to provide insight on the ice--ocean environment and explore how iceberg datasets can be used to examine the physics of iceberg decay and parent glacier properties. First, a semi-automated algorithm, which includes a machine learning-based cloud mask, is applied to six years (2000-2002 and 2013-2015) of the Landsat archive …

Stream Dynamics In The Headwaters Of Post-Glacial Watershed Systems, Brett Gerard

Electronic Theses and Dissertations

This dissertation summarizes research examining watershed processes across Northern New England, with an emphasis on the Central and Coastal regions of Maine. The research presented here focuses on the linkages between watershed geomorphic conditions, climate, and surface flow regimes driving stream channel hydraulic conditions and bed dynamics governing channel geometry. The geologic and human history of the landscape provides the context in which earth surface processes are examined within the dominant physiographic settings in Maine to describe vulnerabilities to climate change. Results are summarized to support the development of sustainability solutions for forecasted watershed management problems by natural resource management …

Climatic Range Filling Of North American Trees, Benjamin Seliger

Electronic Theses and Dissertations

Understanding the degree to which species distributions are controlled by climate is crucial for forecasting biodiversity responses to climate change. Climatic equilibrium, when species are found in all places which are climatically suitable, is a fundamental assumption of species distribution models, but there is evidence in support of climate disequilibria in species ranges. Long-lived, sessile organisms such as trees may be especially vulnerable to being outpaced by climate change, and thus prone to disequilibrium. In this dissertation, I tested the degree to which North American trees are in equilibrium with their potential climatic ranges using the ‘range filling’ metric, which …

Multispectral Classification Of Gulf Of Maine Surface Waters: Seasonal And Interannual Variability, Brianna M. King

Electronic Theses and Dissertations

Bio-optically, surface waters of the northeastern US continental shelf are strongly heterogeneous, exhibiting highly variable distributions in both time and space of suspended sediment, colored dissolved organic matter (CDOM), and phytoplankton concentration and community structure. These render the standard global NASA satellite chlorophyll algorithm suspect. However, spectral signatures of the water are well quantified by the actual satellite-based multispectral reflectance (Rrs) measurements. Here, we use 6 bands of Rrs measurements from 19 years (1998-2016) of monthly composite SeaWiFS and MODIS data to identify the spectral signatures of dominant water types present over the northeast shelf. A merged multivariate clustering approach …

Three-Dimensional Bedrock Channel Evolution With Smoothed Particle Hydrodynamics, Nick Richmond

Electronic Theses and Dissertations

Bedrock channels are responsible for balancing and communicating tectonic and climatic signals across landscapes, but it is difficult and dangerous to observe and measure the flows responsible for removing weakly-attached blocks of bedrock from the channel boundary. Consequently, quantitative descriptions of the dynamics of bedrock removal are scarce. Detailed numerical simulation of violent flows in three dimensions has been historically challenging due to technological limitations, but advances in computational fluid dynamics aided by high-performance computing have made it practical to generate approximate solutions to the governing equations of fluid dynamics. From these numerical solutions we gain detailed knowledge of the …

The Effects Of Seasonal Variations In Chemistry And Hydrology On The Microbial Community And Its Sulfide Oxidation Potential In A Naturally Acidic Maine Stream, Raymond C. Kahler Iii

Electronic Theses and Dissertations

Sulfide minerals oxidize through interaction with water and oxygen, releasing hydrogen ions. The process often occurs naturally near metal sulfide deposits, and can be accelerated through mining. Microorganisms accelerate the rate of sulfide oxidation. Acidified streams typically contain high metal concentrations (e.g. aluminum) and microbes in these systems may develop resistances to metal toxicity. Stream flow can affect sulfide oxidation and microbial community structure. Baseflow can influence stream chemistry from interactions with the surrounding bedrock, while stormflow affects stream chemistry and the local microbial community through dilution and addition of microbes transported by runoff. Microbial community composition is affected by …

Application Of Silicon Nanohair Textured P-N Junctions In A Photovoltaic Device, Michael Small

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for a silicon photovoltaic device which incorporates a nanohair textured p-n junction. The silicon nanowires are etched into a silicon wafer, comprising an epitaxial p-layer on n-substrate, via metal-assisted chemical etching (MACE). The resulting nanowires contain p-n junctions that lie along the length of the vertical nanowires. This construct has the potential to increase the optical bandwidth of a silicon photovoltaic device by allowing a greater amount of short wavelength light to reach the junction. In addition, the MACE method of nanofabrication has the potential for decreasing …

Modern And Paleoecological Perspectives On A Terrestrial-Marine Linkage In The Falkland Islands, Dulcinea V. Groff

Electronic Theses and Dissertations

The Falkland Islands are a biodiversity hotspot in the South Atlantic Ocean, with some of the world’s most important populations of seabirds and seals. The impact of climate change on these marine populations and their coastal breeding habitat in the Falklands is unknown. Coastal grasslands of Poa flabellata (tussac grass) form critical breeding habitat for wildlife, but have been heavily degraded by the introduction of livestock in the 17^th century. This dissertation investigates the impacts of global change (climate change, grazing) on P. flabellata and its sensitivity to the fecal nutrient subsidies provided by marine wildlife. Chapter 1 provides …

Physical And Chemical Response Of Small, North Temperate Lakes To Recovery From Acidification And Climate Change, Amanda Gavin

Electronic Theses and Dissertations

As the rate of sulfate (SO42-) deposition continues to decline and climate is trending towards warmer and wetter conditions, the biogeochemical and physical response of small, north temperate lakes is variable. In this study, we observed long-term chemical trends combined with seasonal water temperature patterns in the context of climate change and recovery from acidification in two remote lake populations in Maine: 29 high elevation lakes and eight low elevation lakes. Small, temperate lakes are the most abundant type of lake, making them a widely representative study sample to consider. Maine’s high elevation lakes (>600m) could potentially provide unique …

Thermochemical Conversion Of Guaiacol Over Unsupported Tungsten Oxide And Nickel Supported Catalysts, Pamela Ruiz Martinez

Electronic Theses and Dissertations

Interest in conversion of biomass into renewable fuels has motivated development of thermochemical methods for production of bio-oil and development of hydrodeoxygenation catalysts for upgrading the oil. Two types of catalysts were investigated. The catalytic activity of unsupported tungsten oxide bronze catalysts for the conversion of guaiacol was explored as a representative compound from bio-oil. The reactions were carried out in a trickle bed reactor at various concentrations of the reactant and hydrogen pressure, as well as varying catalyst activation and reaction temperatures. The reaction pathway from guaiacol to phenol by demethoxylation, followed by hydrogenation to cyclohexanol, and finally dehydration …

Three Examples Of Mondoromy Groups, Alice A. Wise

Electronic Theses and Dissertations

This thesis illustrates the notion of the Monodromy group of a global analytic function through three examples. One is a relatively simple finite example; the others are more complicated infinite cases, one abelian and one non-abelian, which show connections to other parts of mathematics.

Retreat Of The Antarctic Ice Sheet In The Southern Ross Embayment From Records At Amundsen And Liv Glaciers, Southern Transantarctic Mountains, Jillian Pelto

Electronic Theses and Dissertations

The Antarctic Ice Sheet contains ~58 m of global sea-level equivalent and thus its future behavior under global warming is of pressing concern. Examination of past ice-sheet behavior during periods of warming climate can afford insight useful for predicting future sea-level rise. This study focuses on a major unanswered question - namely, the cause of Antarctic Ice Sheet retreat following the last glaciation. Documenting the timing and nature of this deglaciation is crucial to understand the mechanisms behind ice-sheet behavior. Here, I examine how the marine portions of the ice sheet responded to the major warming that occurred at the …

Towards An Efficient, Scalable Stream Query Operator Framework For Representing And Analyzing Continuous Fields, John Whittier

Electronic Theses and Dissertations

Advancements in sensor technology have made it less expensive to deploy massive numbers of sensors to observe continuous geographic phenomena at high sample rates and stream live sensor observations. This fact has raised new challenges since sensor streams have pushed the limits of traditional geo-sensor data management technology. Data Stream Engines (DSEs) provide facilities for near real-time processing of streams, however, algorithms supporting representing and analyzing Spatio-Temporal (ST) phenomena are limited.

This dissertation investigates near real-time representation and analysis of continuous ST phenomena, observed by large numbers of mobile, asynchronously sampling sensors, using a DSE and proposes two novel stream …

Nitrogen Cycling During A Period Of Environmental Change, Kaizad Patel

Electronic Theses and Dissertations

Natural and anthropogenic disturbances have altered the N cycle on the regional to global scale. Although numerous studies have examined the effects of chronic atmospheric N deposition on ecosystem processes, less is known about intra-annual variability of these processes, or how these responses might be altered under conditions of changing climate. The work described in this dissertation focuses on the effects of a changing chemical and physical climate, particularly terrestrial N processes (a) during Maine’s changing winters, and (b) in response to chronic elevated N additions.

Subnivean winter soil processes were examined at the Dwight B. DeMerritt Forest (DBDF) and …

Principles And Guidelines For Advancement Of Touchscreen-Based Non-Visual Access To 2d Spatial Information, Hari Prasath Palani

Electronic Theses and Dissertations

Graphical materials such as graphs and maps are often inaccessible to millions of blind and visually-impaired (BVI) people, which negatively impacts their educational prospects, ability to travel, and vocational opportunities. To address this longstanding issue, a three-phase research program was conducted that builds on and extends previous work establishing touchscreen-based haptic cuing as a viable alternative for conveying digital graphics to BVI users. Although promising, this approach poses unique challenges that can only be addressed by schematizing the underlying graphical information based on perceptual and spatio-cognitive characteristics pertinent to touchscreen-based haptic access. Towards this end, this dissertation empirically identified a …

Understanding Student Development Of Science Literacy Skills In An Undergraduate Environmental Science Course, Molly Picillo

Electronic Theses and Dissertations

Educators are expected to instill a variety of skills in their students that are necessary to be competent citizens of society. One such set of skills, science literacy skills, broadly encompass the ability of an individual to evaluate reliability of data and information and critically analyze and interpret them (Gormally Brickman, Hallar, & Armstrong, 2009). These skills are utilized in everyday decision-making and given their pertinence, there is a need for citizens to be scientifically literate. Thus, educators need tools and assessments to help students develop these skills and analyze their science literacy. The aim of this study was to …

The Hilbert-Huang Transform: A Theoretical Framework And Applications To Leak Identification In Pressurized Space Modules, Kenneth R. Bundy

Electronic Theses and Dissertations

Any manned space mission must provide breathable air to its crew. For this reason, air leaks in spacecraft pose a danger to the mission and any astronauts on board. The purpose of this work is twofold: the first is to address the issue of air pressure loss from leaks in spacecraft. Air leaks present a danger to spacecraft crew, and so a method of finding air leaks when they occur is needed. Most leak detection systems localize the leak in some way. Instead, we address the identification of air leaks in a pressurized space module, we aim to determine the …

Mechanistic Studies Of Reducible Metal Oxides As Hydrodeoxygenation Catalysts, Akbar Mahdavi Shakib

Electronic Theses and Dissertations

Hydrodeoxygenation of phenol to benzene using ruthenium supported titania catalysts strongly varies depending on the support crystal structure and preparation conditions. Here, we performed spectroscopic characterization of titania supports to identify the surface impurities common to commercial and synthesized titania samples using a variety of spectroscopic methods. Sulfate impurities were detected for the commercial anatase samples and a procedure for their elimination was proposed so that inactive catalysts gained reactivity. Surface hydroxyls of different TiO2 samples (anatase, rutile, and pyrogenic) were identified using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments performed on vigorously cleaned surfaces and a facet-specific assignment …

Biomass Based Monomers For Synthesis Of Renewably Sourced Polymers, Anushka E. Vithanage

Electronic Theses and Dissertations

Limited fossil resources have raised research focus on synthesizing novel, sustainable polymers and renewably sourcing existing petroleum based polymers. This work presents the synthesis and ring opening polymerization (ROP) of a new functionalized lactone monomer, methoxy-δ-hexalactone (MDHL), to yield a functionalized polyester (polyMDHL). MDHL can be renewably sourced from hydroxymethylfurfural, a renewable platform chemical. MDHL was synthesized from methyl cyclopentanone-2-carboxylate by a five-step synthesis with a global yield of 23%. ROP of MDHL was conducted with benzyl alcohol initiator, catalyzed by diphenyl phosphate. 1H Nuclear Magnetic Resonance spectroscopy verified polyMDHL chemical structure. Targeting higher molecular weights for polyMDHL by increasing …

Chemically Cross-Linked Polysaccharide-Based Hydrogels Via Thiol-Norbornene Reaction As Sustainable Biomaterials, Nayereh Dadoo

Electronic Theses and Dissertations

Hydrogels are 3D polymeric networks with high water content and are widely being investigated for biomedical applications such as tissue engineering. Polysaccharides have been used to fabricate hydrogels due to their natural abundance, biocompatibility, and immunogeniety. Additionally, polysaccharide-based hydrogels can provide mechanical and biological cues similar to those of the natural environments. In this work, thiol-norbornene chemistry was used to fabricate polysaccharide-based hydrogels including hyaluronic acid (HA), carboxymethyl cellulose (CMC), and cellulose nanofibrils (CNFs). Hydrogels with tunable physical and mechanical properties were achieved. The properties of these hydrogels were spatiotemporally modified by photopatterning. Also, high stem cell viability was achieved …

Rediscovering The Interpersonal: Models Of Networked Communication In New Media Performance, Alicia Champlin

Electronic Theses and Dissertations

This paper examines the themes of human perception and participation within the contemporary paradigm and relates the hallmarks of the major paradigm shift which occurred in the mid-20th century from a structural view of the world to a systems view. In this context, the author’s creative practice is described, outlining a methodology for working with the communication networks and interpersonal feedback loops that help to define our relationships to each other and to media since that paradigm shift. This research is framed within a larger field of inquiry into the impact of contemporary New Media Art as we experience it. …

Fault-Adjacent Damage At The Base Of The Seismogenic Zone And Seismic Anisotropy Of Fold Structures, Won Joon Song

Electronic Theses and Dissertations

While earthquakes represent a major hazard to life and property, there are a number of open questions about how earthquake faults operate at depth, and how the energy released by earthquakes travels as elastic waves through Earth’s complexly deformed crustal rocks. The aims of my dissertation are to explore (a) the extent of co-seismic damage in an ancient earthquake fault exhumed from great depths, (b) the deformation processes and mechanics of the fault at depth during earthquake cycles, and (c) the role of different rock structures in determining the velocities of seismic waves.

When tectonic plates collide, deformation tends to …

A Glacial History Of Roberts Massif, Central Transantarctic Mountains, Antarctica, Using Cosmogenic 3he, 10be, And 21ne Surface Exposure Ages, Alexandra M. Balter

Electronic Theses and Dissertations

Ice-free areas at high elevation in the central Transantarctic Mountains preserve moraines and drift deposits that delineate the former thickness and extent of the East Antarctic Ice Sheet (EAIS); cosmogenic exposure ages on these features indicate when the ice sheet was as or more extensive than today. Approximately 30 existing cosmogenic-nuclide exposure ages from scattered locations within these deposits suggest that some moraines and drift sheets are at least 5 Ma old. Those ages imply that the age range of these deposits may span warm periods during the Miocene and Pliocene, during which the EAIS is hypothesized to have been …

Circulation, Cross-Shelf Exchange, And Blue Mussel (Mytilus Edulis) Population Connectivity In A Complex, Tidally Driven System, Leann M. Conlon

Electronic Theses and Dissertations

Because many marine species have a planktonic larval phase, an understanding of population connectivity (the exchange of individuals among populations) is critical for better understanding their adult populations. However, connectivity depends on both circulation patterns and any interacting biological factors. Of particular importance to organisms originating nearshore is the amount of cross-shelf exchange, as larvae within the slower moving coastal boundary layer experience shorter dispersal distances. I investigated circulation patterns and cross-shelf exchange along the Eastern Maine coast, a region with strong tidal currents and a complex coastline bounded in the offshore direction by a faster moving coastal current. I …

Spatio-Temporal Dynamics Of Atlantic Cod Bycatch In The Maine Lobster Fishery And Its Impacts On Stock Assessment, Robert E. Boenish

Electronic Theses and Dissertations

Of the most iconic fish species in the world, the Atlantic cod (Gadus morhua, hereafter, cod) has been a mainstay in the North Atlantic for centuries. While many global fish stocks have received increased pressure with the advent of new, more efficient fishing technology in the mid-20^th century, exceptional pressure has been placed on this prized gadoid. Bycatch, or the unintended catch of organisms, is one of the biggest global fisheries issues. Directly resulting from the failed recovery of cod in the GoM, attention has been placed as to possible sources of unaccounted catch. Among the most …

New Approaches To Mapping Forest Conditions And Landscape Change From Moderate Resolution Remote Sensing Data Across The Species-Rich And Structurally Diverse Atlantic Northern Forest Of Northeastern North America, Kasey R. Legaard

Electronic Theses and Dissertations

The sustainable management of forest landscapes requires an understanding of the functional relationships between management practices, changes in landscape conditions, and ecological response. This presents a substantial need of spatial information in support of both applied research and adaptive management. Satellite remote sensing has the potential to address much of this need, but forest conditions and patterns of change remain difficult to synthesize over large areas and long time periods. Compounding this problem is error in forest attribute maps and consequent uncertainty in subsequent analyses. The research described in this document is directed at these long-standing problems.

Chapter 1 demonstrates …

Developing A Risk Assessment Protocol To Quantify Distribution And Uptake Of Persistent Organic Pollutants In Glacial Outflows, Kimberley Rain Miner

Electronic Theses and Dissertations

Pollutants released by industrialized nations between 1960 and 2004 have been transported northward through atmospheric processes and deposited into glaciated alpine ecosystems. Many of these chemicals retain their original structure and are absorbed into the biota thousands of miles away from where they were originally utilized. With a warming climate increasing the melt of alpine glaciers, these glaciers may be introducing growing amounts of toxins into the watershed. While studies have demonstrated the existence of resident pollutants within glaciated ecosystems, no one has developed a risk assessment to identify sources and quantity of risk posed by these compounds when released …