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Physical Sciences and Mathematics Commons™

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Technological University Dublin

Series

1999

Articles 1 - 11 of 11

Full-Text Articles in Physical Sciences and Mathematics

Characterisation Of The Effects Of Time And Pressure On A Group Of Electronic Voltage Standards, James Kevin Armstrong Dec 1999

Characterisation Of The Effects Of Time And Pressure On A Group Of Electronic Voltage Standards, James Kevin Armstrong

Masters

Although primary metrology laboratories use standards based on the Josephson effect to maintain a local reference standard for dc voltage, artefact standards are still the standard of choice in many secondary laboratories. The National Metrology Laboratory, Dublin maintains a local reference standard for dc voltage by means of an ensemble of Zener-diode based electronic voltage standard units. Electronic voltage standards have a number of shortcomings over Josephson standards for use as a local reference standard. In particular their output voltages are influenced by several external factors. In order to make optimum use of the NML reference standard it is important …

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The Design And Construction Of An Out-Of-Plane Sensitive Electronic Speckle Pattern Interferometer For Non-Destructive Testing Applications, Alexander Burden Aug 1999

The Design And Construction Of An Out-Of-Plane Sensitive Electronic Speckle Pattern Interferometer For Non-Destructive Testing Applications, Alexander Burden

Masters

There are many non-destructive testing (NDT) techniques use din industry, which employ acoustic emission, ultrasound, X-rays and thermography. Optical interferometric methodology is being increasingly used in industry. Electronic Speckle Pattern Interferometry (ESPI) is one of the principal optical interferometric techniques used in NDT to measure deformations. Optical surface metrology offers many advantages over conventional methods. These include greater sensitivity, improved lateral and vertical resolution, non-contact and full field measurement. Conventional methods of NDT however continue to be chosen over ESPI. The objective of this thesis is focused on making ESPI more feasible as a NDT technique for use in industry. …

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Sketch-Based Image Queries In Topographic Databases, James Carswell Jun 1999

Sketch-Based Image Queries In Topographic Databases, James Carswell

Articles

In this paper we present the development of a system prototype for sketch-based queries for the content-based retrieval of digital images from topographic databases. We discuss our overall strategy and associated algorithmic and implementation aspects, and present associated database design issues. The query tools devised in this research are employing user-provided sketches of the shape and spatial configuration of the object(s) which should appear in the images to be retrieved. Our matching tool is inspired by least-squares matching (lsm), and represents an extension of lsm to function with a variety of raster representations. Our strategy makes use of a hierarchical …

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An Investigation Into The Use Of The Virtual Reality Modelling Language (Vrml) As A Means Of Distribution Virtual Reality Tourist Information Across The World Wide Web, Hugh Mcatamney, Ciaran Mcdonnell May 1999

An Investigation Into The Use Of The Virtual Reality Modelling Language (Vrml) As A Means Of Distribution Virtual Reality Tourist Information Across The World Wide Web, Hugh Mcatamney, Ciaran Mcdonnell

Conference papers

The purpose of the work described was to investigate the use of the Virtual Reality Modelling Language (VRML) as a tool to distribute tourist information across the web. This was done by the creation of a web site containing two Virtual Reality models of tourist interest. These were then valuated using a number of techniques both online and offline. This paper describes the methods used to create and evaluate these models as well as giving a overview of some of the results obtained.

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Temperature Dependence Of Stark Width Of The 463.054 Nm Nii Spectral Line, Vladimir Milosavljevic, Ruzica Konjevic, Stevan Djenize Mar 1999

Temperature Dependence Of Stark Width Of The 463.054 Nm Nii Spectral Line, Vladimir Milosavljevic, Ruzica Konjevic, Stevan Djenize

Articles

Stark width of the 463.054 nm singly ionized nitrogen spectral line, that belong to transition, have been measured in a linear pulsed, low pressure, arc discharge. The working gas was helium-nitrogen-oxygen mixture. Electron densities of 0.751023 to 1.451023 were determined in the electron temperature range between 30000 K - 38000 K. The measured values have been compared with our calculated data, using the modified semiempirical approximation. On the basis of the agreement among experimental and theoretical Stark width data, the isolated 463.054 nm NII spectral line can be recommended as convenient spectral line for plasma diagnostics.

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Note On The Voltammetry Of Ferrocene Carboxylate In Aqueous Solution, John Cassidy, John O'Gorman, M. Ronane, Enda Howard Jan 1999

Note On The Voltammetry Of Ferrocene Carboxylate In Aqueous Solution, John Cassidy, John O'Gorman, M. Ronane, Enda Howard

Articles

Cyclic voltammetry of ferrocene dicarboxylate in aqueous solutions at high pH, in the presence of oxygen, showed evidence of an EC' mechanism where the oxidised form of ferrocene dicarboxylate reacts with H02- , which had been produced at a lower potential. However, an analogous experiment with ferrocene carboxylate yielded a cyclic voltammogram with a post peak: following the anodic peak: for ferrocene carboxylate. The reason for the post peak: is not clear but may be due to a delay in the reaction between the oxidised form of ferrocene carboxylate and H02-.

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A Feature Library Approach To On-Line Image Querying And Retrieval For Topographic Applications, James Carswell Jan 1999

A Feature Library Approach To On-Line Image Querying And Retrieval For Topographic Applications, James Carswell

Conference papers

In this paper we address the problem of content-based image retrieval using queries on shape and topology. We focus on the particularities of image databases encountered in typical topographic applications, and present the development of a spatial data management system that enables such queries. The query uses as input user-provided sketches of the shape and spatial configuration of the object (or objects) which should appear in the images to be retrieved. The objective of the search is to retrieve images that contain a configuration of objects sufficiently similar to the one specified in the query. Our novel approach introduces the …

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The Development And Validation Of A Methodology For The Analysis Of Polyaromatic Hydrocarbons In Air Particulates (Indoor And Outdoor), Kathryn O'Malley Jan 1999

The Development And Validation Of A Methodology For The Analysis Of Polyaromatic Hydrocarbons In Air Particulates (Indoor And Outdoor), Kathryn O'Malley

Masters

PAH form a large class of ubiquitous pollutants mainly of anthropogenic origin. Several PAH found in air particulates have been identified as carcinogens and mutagens. Sixteen of these PAH have been listed by the USEPA as priority pollutants. This research is concerned with the development and optimisation of a method for the analysis of these sixteen PAH in air particulates. Soxhlet and ultrasonic extraction procedures were investigated to optimise the recoveries from spiked glass fibre filters with a standard 1ppm mixture of the 16PAH. Standard mixtures of the 16 PAH were analysed by HPLC with fluorescence detection with approx. linearity …

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Experimental Observation Of Individual Single Wall Nanotube Species By Raman Microscopy, G. S. Duesberg, W. Blau, Hugh Byrne, J. Muster, M. Burghard, S. Roth Jan 1999

Experimental Observation Of Individual Single Wall Nanotube Species By Raman Microscopy, G. S. Duesberg, W. Blau, Hugh Byrne, J. Muster, M. Burghard, S. Roth

Articles

Individual single-wall carbon nanotubes (SWNT) or small ropes of SWNTs with the same diameter have been characterised by Raman spectroscopy. Highly pure, length-selected SWNTs adsorbed onto substrates designed for surface-enhanced Raman spectroscopy were investigated with a Raman microscope. Various spectra, each with a distinct sharp peak in the radial breathing mode area and four C–C stretching modes could be observed. The modes also showed a strong variation in the relative intensities. In correlation with theoretical predictions this should establish Raman microscopy as a non-destructive nano-technological tool, capable of determining the diameter, symmetry and position of individual SWNTs.

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Use Of Excel To Obtain Voltammetric Information On Microelectrodes, Enda Howard, John Cassidy Jan 1999

Use Of Excel To Obtain Voltammetric Information On Microelectrodes, Enda Howard, John Cassidy

Articles

The use of curve fitting for the analysis and interpretation of voltammetric data obtained while working with micro electrodes is discussed as a useful exercise for introducing students to the principle of problem solving using least-squares curve-fitting techniques. The advantages associated with this approach to data processing over the approach where the limiting current (i L) alone is used are discussed and its limitations are highlighted. This technique was applied to the determination of unknown concentrations of ferrocyanide and the most satisfactory recovery of concentrations was found when both the va1ues of the formal potential (EO') and concentration ( C) …

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Studies On The Amylolytic Breakdown Of Damaged Starch In Cereal And Non-Cereal Flours, Karen Bailey Jan 1999

Studies On The Amylolytic Breakdown Of Damaged Starch In Cereal And Non-Cereal Flours, Karen Bailey

Masters

The term starch damage refers to a number of changes to the starch granule structure, which are detectable by different analytical techniques. Damaged starch is the substrate for amylases, which in turn provides carbohydrates that are used in the production of certain foods and food ingredients; as a result, therefore, determination of levels in flours is a procedure carried out routinely by many manufacturers of starch based products. Enzymatic assay methods emulate the susceptibility of damaged starch granules to enzymatic attack. The first aim of this study was to evaluate enzymatic methods(1,2) to determine damaged starch in wheat flours and …

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