Physical Sciences and Mathematics Commons^™

Localised Galvanic Corrosion Processes In Thermal Spray Coated/Cast Aluminium Alloy Systems, David Culliton, Tony Betts, David Kennedy

Conference Papers

Cast Aluminium Alloys, because of the propensity of aluminium to react with impurities and alloying elements, are prone to developing IM impurities during the solidification process. These IM phases can act, in some fluids, as initiation sites for localised corrosion processes, resulting in degradation phenomena, such as pitting. Whilst Thermal Spray coatings can improve the wear resistance of Cast Aluminium Alloys, their corrosion performance may be hampered by the presence of through porosity within the coating.

The present work details some preliminary studies of the localised corrosion processes occurring at the interface area between a Thermal Spray coating and a …

The Application Of Web 2.0 Technologies As An Experimental Method Of Teaching Remote Sensing At Dit, Ireland, Avril Behan

Conference Papers

This paper describes the implementation of an experimental method of delivery for a module of remote sensing material to second year students on the BSc (Hons) in Geomatics at the Dublin Institute of Technology. The project began as a reaction to poor levels of student engagement and unsatisfactory grades, as well as the requirement to focus more on real-world type problems due to the implementation of a work-placement semester for third year students. Both pedagogical considerations (movement towards formative feedback, interactivity and group-based work) and the effect of technological drivers, such as the popularity of the internet in general and …

An Exploration Of A Discrete Rhombohedral Lattice Of Possible Engineering Or Physical Relevance (Revised Version) 2008, Jim Mcgovern

Conference Papers

A particular discrete rhombohedral lattice consisting of four symmetrically interlaced cuboctahedral point lattices is described that is interesting because of the high degree of symmetry it exhibits. The four constituent cuboctahedral lattices are denoted by four colours and the composite lattice is referred to as a 4-colour rhombohedral lattice. Each point of the 4-colour lattice can be referenced by an integer 4-tuple containing only the positive non-zero integers (the counting numbers). The relationship between the discrete rhombohedral lattice and a discrete Cartesian lattice is explained. Some interesting aspects of the lattice and of the counting-number 4-tuple coordinate system are pointed …

Metrology And Proportion In The Ecclesiastical Architecture Of Medieval Ireland, Avril Behan, Rachel Moss

Conference Papers

The aim of this paper is to examine the extent to which detailed empirical analysis of the metrology and proportional systems used in the design of Irish ecclesiastical architecture can be analysed to provide historical information not otherwise available. Focussing on a relatively limited sample of window tracery designs as a case study, it will first set out to establish what, if any, systems were in use, and then what light these might shed on the background, training and work practices of the masons, and, by association, the patrons responsible for employing them.

An Exploration Of A Discrete Rhombohedral Lattice Of Possible Engineering Or Physical Relevance, Jim Mcgovern

Conference Papers

A particular discrete rhombohedral lattice consisting of four symmetrically interlaced cuboctahedral or cubic point lattices is described that is interesting because of the high degree of symmetry it exhibits. The four constituent lattices are denoted by four colours and the composite lattice is referred to as a 4-colour rhombohedral lattice. Each point of the 4-colour lattice can be referenced by an integer 4-tuple containing only the positive non-zero integers (the counting numbers). The relationship between the discrete rhombohedral lattice and a discrete Cartesian lattice is explained. Some interesting aspects of the lattice and of the counting-number 4-tuple coordinate system are …

Targeted Drug Delivery Systems For Cancer Therapy, Antonio Clementi, Christine O'Connor, Mary Mcnamara, A. Mazzaglia, M. C. Aversa, A. Giuffrida

Conference Papers

The role of cyclodextrin’s (CD) in drug delivery has advanced in recent years and this may be attributed to its biocompatibility and well established synthesis. Chemical modification of CDs has shown to extend the physicochemical properties and the host capacity for a variety of drugs. β-CD has been widely used in the early stages of pharmaceutical applications because of its ready availability and its cavity size suitability for a wide range of drugs. Chemical modification of β-CD has proven to enhance aqueous solubilisation, microbiological stability and reduced toxicity in previous studies.1 Folate Receptors are over-expressed in several human cancers including …

Photochemical Studies Of Nutraceuticals In The Presence Of Cyclodextrins, Zlata Tofzikovskaya, Christine O'Connor, Mary Mcnamara

Conference Papers

The photostability studies of Folic acid and Menadione Sodium Bisulfite, also known as vitamin K3, were carried out in their aqueous solutions at room temperature. Solutions of Folic acid ( 4.8 x 10-5 M) and Menadione Sodium Bisulfite (4.0 x 10-4 M) were exposed to ultraviolet radiation at a wavelength of 365 nm. During exposure absorbance of both solutions was measured using a Perkin Elmer Lamda 900 UV/VIS/NIR Spectrometer. During the stability tests it was noted that addition of β Cyclodextrin (1:1 ratio) to aqueous solutions containing the vitamin slowed down the photodegradation process. The unique shape of Cyclodextrins allows …

Hoe-Based Espi Systems, Emilia Mihaylova, Viswanath Bavigadda, Raghavendra Jallapuram, Vincent Toal

Conference Papers

Electronic speckle pattern interferometry (ESPI) is a full-field measurement technique, capable of displaying vibrational mode shapes. Two electronic speckle pattern interferometers using reflection holographic optical elements (RHOEs) are presented. In the first ESPI system the RHOE is designed to create the speckled reference beam. A partially reflective glass plate provides illumination of the object along the normal to its surface, ensuring that the system is sensitive only to out-of-plane displacement of the object. It is demonstrated that the HOE-based system can be used for vibration measurements. Phase shifting can be implemented for fringe analysis. In the second ESPI system a …

Optimising Design Parameters Of Enzyme-Channelling Biosensors, Dana Mackey, Tony Killard

Conference Papers

Two mathematical models for an electrochemical biosensor are proposed and compared with a view to determining the ratio of two immobilized enzymes which maximizes the amperometric signal amplitude.

Whole Field Out-Of-Plane Vibration Analysis With A Hoe-Based Espi System, Emilia Mihaylova, Viswanath Bavigadda, Raghavendra Jallapuram, Vincent Toal

Conference Papers

Electronic speckle pattern interferometry (ESPI) is a full-field measurement technique, capable of displaying vibrational mode shapes. A simple optical set-up for an ESPI system using a holographic optical element (HOE) is presented. The HOE is designed to create a speckled reference beam in the interferometer. A partially reflective glass plate provides illumination of the object along the normal to its surface, ensuring that the system is sensitive only to out-of-plane displacement of the object. It is demonstrated that the HOE-based system can be used for vibration measurements. Phase shifting can be implemented for fringe analysis. A big advantage of the …