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Conduction And Thermal Properties Of A Proton Conducting Polymer Electrolyte Based On Poly (Epsilon-Caprolactone), Siti Rohana Majid, Woo H. J., Arof A. K.
Conduction And Thermal Properties Of A Proton Conducting Polymer Electrolyte Based On Poly (Epsilon-Caprolactone), Siti Rohana Majid, Woo H. J., Arof A. K.
Siti Rohana Majid
A proton conducting polymer electrolyte based on poly(epsilon-caprolactone) (PCL) complexed with different concentrations of ammonium thiocyanate (NH(4)SCN) salt has been investigated. The ionic conductivity of the solid polymer electrolyte (SPE) of pure PCL obtained at room temperature is 1.86 x 10(-11) S cm(-1). The maximum ionic conductivity achieved in the solution-cast films at room temperature is 1.01 x 10(-4) S cm(-1) for PCL incorporated with 26 wt.% NH(4)SCN. The calculated dielectric constant at selected frequencies follows the same trend as conductivity, concluding an increase in number density of ions with the salt content. DSC thermogram shows that the degree of …
Preparation And Characterization Of Magnesium Ion Gel Polymer Electrolytes For Application In Electrical Double Layer Capacitors, Siti Rohana Majid, Asmara S. N., Kufian M. Z., Arof A. K.
Preparation And Characterization Of Magnesium Ion Gel Polymer Electrolytes For Application In Electrical Double Layer Capacitors, Siti Rohana Majid, Asmara S. N., Kufian M. Z., Arof A. K.
Siti Rohana Majid
This work describes the preparation and characterization of poly (methyl methacrylate) (PMMA) based gel polymer electrolytes with magnesium triflate (Mg(CF(3)SO(3))(2)) as the ion providing salt. Liquid electrolytes containing 0.4 M Mg(CF(3)SO(3))(2) in solvents comprising different ratios of ethylene carbonate (EC) and diethyl carbonate (DEC) have been prepared at room temperature. The highest conducting electrolyte contains EC and DEC in the weight ratio of 2:1. To the highest conducting liquid electrolyte, 25-50 wt.% PMMA has been added and the mixtures were heated at 80 degrees C for 2 min to form gel polymer electrolytes. The gel electrolyte with composition 40 wt.% …