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Full-Text Articles in Physical Sciences and Mathematics

Giant Interlayer Magnetoresistances And Strong Anisotropy In P-Type Sb2te3 Single Crystals, Zengji Yue, Xiaolin Wang, S Dou Dec 2013

Giant Interlayer Magnetoresistances And Strong Anisotropy In P-Type Sb2te3 Single Crystals, Zengji Yue, Xiaolin Wang, S Dou

Zengji Yue

Anisotropic interlayer magneto-transport properties have been studied over a broad range of temperatures and magnetic fields in p-type Sb2Te3 single crystals. Giant interlayer magnetoresistance (MR) of up to 400% was observed, which exhibits quadratic field dependences in low fields and becomes linear at high fields without any trend towards saturation. The interlayer MR displays strong anisotropy and is attributable to the anisotropy of the Fermi surface. The observed giant anisotropic interlayer MR could find applications in p-type Sb2Te3 based magneto-electronic devices.


Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou Jul 2013

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Jianli Wang

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …


Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou Jun 2013

Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou

Shi Xue Dou

Magnetic properties and the magnetocaloric effect (MCE) have been investigated in La0.7Ca0.3MnO3 single crystal with applied field along both the ab-plane and the c-direction. Due to the magnetocrystalline anisotropy, the crystal exhibits anisotropy in the MCE. Upon application of a 5 T field, the magnetic entropy changes (SM), reaching values of 7.668 J/(kg K) and 6.412 J/(kg K) for both the ab-plane and the c-direction, respectively. A magnetic entropy change of 3.3 J/(kg K) was achieved for a magnetic field change of 1.5 T at the Curie temperature, TC = 245 K. Due to the absence of grains in the …


Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou Jun 2013

Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou

Shi Xue Dou

Polycrystalline (PC) and single crystalline (SC) samples of La0.7Ca0.3CoO3 (LCCO) with the perovskite structure were synthesized by conventional solid-state reaction and the floating-zone growth method. We conducted isothermal magnetization measurements of the PC and SC samples at temperatures from 2.8 K to 140 K, and evaluated the magnetic entropy change (−ΔSM) under zero field cooling (ZFC) and field cooling (FC) to 2.8 K. An interesting result has been obtained, where the −ΔSM–T curves in the low temperature range show totally different features between the ZFC and FC cooling procedures. The −ΔSM shows a large inverse irreversibility value for the ZFC …


Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou Jun 2013

Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou

Shi Xue Dou

Large single crystals of α-NaxCoO2 (x=0.91, 0.92, and 0.93) have been successfully fabricated by using the traveling solvent floating zone method. Details on the crystal growth are discussed. The crystal structures were characterized using powder x-ray diffraction and Rietveld refinement. The magnetic susceptibility measurements show that the magnetic properties depend strongly on x. The compound was found to be antiferromagnetic at TN ≈ 20 K for x=0.91 and x=0.92, and paramagnetic for x=0.93. The in-plane and out-of-plane anisotropies were observed for the x=0.91 crystals. In addition, the derived anisotropic g-factor ratios (gab /gc) from the anisotropic susceptibility along H||ab and …


Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou Jun 2013

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Shi Xue Dou

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …


Very Strong Intrinsic Flux Pinning And Vortex Avalanches In (Ba, K)Fe2as2 Superconducting Single Crystals, Xiaolin Wang, Shaban R. Ghorbani, Sung-Ik Lee, S X. Dou, C T Lin, T H. Johansen, K.H Muller, Zhenxiang Cheng, Germanas Peleckis, M Shabazi, A.J Qviller, V Yurchenko, G.L Sun, D.L Sun Jun 2013

Very Strong Intrinsic Flux Pinning And Vortex Avalanches In (Ba, K)Fe2as2 Superconducting Single Crystals, Xiaolin Wang, Shaban R. Ghorbani, Sung-Ik Lee, S X. Dou, C T Lin, T H. Johansen, K.H Muller, Zhenxiang Cheng, Germanas Peleckis, M Shabazi, A.J Qviller, V Yurchenko, G.L Sun, D.L Sun

Shi Xue Dou

We report that the (Ba,K)Fe2As2 crystal with Tc=32 K shows a pinning potential, U0, as high as 104 K, with U0 showing very little field dependence. The (Ba,K)Fe2As2 single crystals become isotropic at low temperatures and high magnetic fields, resulting in a very rigid vortex lattice, even in fields very close to Hc2. The isotropic rigid vortices observed in the two-dimensional (2D) (Ba,K)Fe2As2 distinguish this compound from 2D high-Tc cuprate superconductors with 2D vortices. The vortex avalanches were also observed at low temperatures in the (Ba,K)Fe2As2 crystal. It is proposed that it is the K substitution that induces both almost …


Flux Pinning And Vortex Transitions In Doped Bafe2as2 Single Crystals, S R. Ghorbani, X L. Wang, M Shabazi, S X. Dou, K Y. Choi, C T. Lin Jun 2013

Flux Pinning And Vortex Transitions In Doped Bafe2as2 Single Crystals, S R. Ghorbani, X L. Wang, M Shabazi, S X. Dou, K Y. Choi, C T. Lin

Shi Xue Dou

The vortex liquid-to-glass transition has been studied in Ba0.72K0.28Fe2As2 (BaK-122), Ba(Fe0.91Co0.09)2As2(BaCo-122), and Ba(Fe0.95Ni0.05)2As2(BaNi-122) single crystal with superconducting transition temperature, Tc=31.7, 17.3, and 18 K, respectively, by magnetoresistance measurements. For temperatures below Tc, the resistivity curves were measured in magnetic fields within the range of 0≤B≤13 T, and the pinning potential was scaled according to a modified model for vortex liquid resistivity. Good scaling of the resistivity q(B, T) and the effective pinning energy U0(B,T) were obtained. The vortex state is three-dimensional at temperatures lower than a characteristic temperature T*. The vortex phase diagram was determined based on the evolution of …


Josephson-Vortex Flow Resistance In Bi2sr2ca2cu3oy Single Crystals And Its Possible Application In The Manipulation Of Spin And Charge Textures In Diluted Magnetic Semiconductors, Xiaolin Wang, C T Lin, B Liang, S Yu, S Ooi, K Hirata, S Y Ding, Dongqi Shi, S X. Dou, Zhi W. Lin, Jian G. Zhu Jun 2013

Josephson-Vortex Flow Resistance In Bi2sr2ca2cu3oy Single Crystals And Its Possible Application In The Manipulation Of Spin And Charge Textures In Diluted Magnetic Semiconductors, Xiaolin Wang, C T Lin, B Liang, S Yu, S Ooi, K Hirata, S Y Ding, Dongqi Shi, S X. Dou, Zhi W. Lin, Jian G. Zhu

Shi Xue Dou

In this work, the flow of the Josephson vortices (JVs) has been studied for the highly anisotropic Bi2Sr2Ca2Cu3Oy (Bi2223) single crystals. A giant flow of JVs or giant positive magnetoresistance (MR) of over 500%-2000% was obtained in fields of 0.1-5 T and remained almost constant over a wide temperature range from 110 down to 4 K, in contrast to superconducting vortices (SVs), which only produced MR in the vicinity of Tc. The flow of the JVs is expected to be much faster than that of SVs. It is proposed that the Josephson vortices could be used to manipulate the spin …


Magnetic Anisotropy Of Naxcoo2 Single Crystals, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou Jun 2013

Magnetic Anisotropy Of Naxcoo2 Single Crystals, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou

Shi Xue Dou

We report the magnetic properties of single crystals of NaxCoO2 (x=0.42, 0.82, and 0.87). The magnetic susceptibility measurements revealed considerable anisotropy along H parallel to ab and H parallel to c for the as-grown single crystals. It was found that an antiferromagnetic transition with a Neel temperature T-N=21 K occurred for the x=0.82 sample, and there was a paramagnetic phase for the x=0.87 sample over a wide temperature range from 2 to 300 K, but the sample with x=0.42 shows a monotonic increase of chi with increasing temperature above similar to 100 K. In addition, the x=0.82 sample has the …


Equivalent Dose Distributions From Single Grains Of Quartz At Sibudu, South Africa: Context, Causes And Consequences For Optical Dating Of Archaeological Deposits, Richard Roberts, Zenobia Jacobs, Geoffrey Duller, Ann Wintle Mar 2013

Equivalent Dose Distributions From Single Grains Of Quartz At Sibudu, South Africa: Context, Causes And Consequences For Optical Dating Of Archaeological Deposits, Richard Roberts, Zenobia Jacobs, Geoffrey Duller, Ann Wintle

Richard G Roberts

No abstract provided.


Single-Grain Osl Dating Of Glaciofluvial Quartz Constrains Reid Glaciation In Nw Canada To Mis 6, Martina Demuro, D Froese, Lee Arnold, Richard Roberts Mar 2013

Single-Grain Osl Dating Of Glaciofluvial Quartz Constrains Reid Glaciation In Nw Canada To Mis 6, Martina Demuro, D Froese, Lee Arnold, Richard Roberts

Richard G Roberts

Improved chronological control on the penultimate advance of the Cordilleran Ice Sheet in northwest Canada (the Reid glaciation) is required for a better understanding of late Quaternary palaeoclimatic and palaeoenvironmental change in eastern Beringia. However, reliable dating of glaciation events beyond the last glacial maximum is commonly hindered by a lack of directly dateable material. In this study we (i) provide the first combined minimum and maximum age constraint on the Reid glaciation at Ash Bend, its reference locale in the Stewart River valley, northwestern Canadian Cordillera, using single-grain optically stimulated luminescence dating of quartz; and (ii) compare the timing …


An Improved Osl Chronology For The Still Bay Layers At Blombos Cave, South Africa: Further Tests Of Single-Grain Dating Procedures And A Re-Evaluation Of The Timing Of The Still Bay Industry Across Southern Africa, Zenobia Jacobs, Elspeth Hayes, Richard Roberts, Rex Galbraith, Christopher Henshilwood Mar 2013

An Improved Osl Chronology For The Still Bay Layers At Blombos Cave, South Africa: Further Tests Of Single-Grain Dating Procedures And A Re-Evaluation Of The Timing Of The Still Bay Industry Across Southern Africa, Zenobia Jacobs, Elspeth Hayes, Richard Roberts, Rex Galbraith, Christopher Henshilwood

Richard G Roberts

This paper presents a series of new single-grain optically stimulated luminescence (OSL) ages for the Still Bay at Blombos Cave, South Africa, and compares them to previously published OSL, thermoluminescence (TL) and electron-spin resonance (ESR) ages for this site. Details are provided about the measurement and analytical procedures, including a discussion of the characteristics of the OSL signals of individual quartz grains. This forms the basis for further investigations into the sensitivity of the equivalent dose (De) estimates to a range of different analytical approaches, including changes in the size of the test dose, the choice of signal integration interval, …


Optically Stimulated Luminescence Dating Of Single And Multiple Grains Of Quartz From Perennially Frozen Loess In Western Yukon Territory, Canada: Comparison With Radiocarbon Chronologies For The Late Pleistocene Dawson Tephra, Richard Roberts, Lee Arnold, Martina Demuro, F Brock, D Froese, C Bronk Ramsey Mar 2013

Optically Stimulated Luminescence Dating Of Single And Multiple Grains Of Quartz From Perennially Frozen Loess In Western Yukon Territory, Canada: Comparison With Radiocarbon Chronologies For The Late Pleistocene Dawson Tephra, Richard Roberts, Lee Arnold, Martina Demuro, F Brock, D Froese, C Bronk Ramsey

Richard G Roberts

No abstract provided.


Single-Grain Osl Chronologies For Middle Palaeolithic Deposits At El Mnasra And El Harhoura 2, Morocco: Implications For Late Pleistocene Human-Environment Interactions Along The Atlantic Coast Of Northwest Africa, Zenobia Jacobs, Richard Roberts, Roland Nespoulet, M El Hajraoui, Andre Debenath Mar 2013

Single-Grain Osl Chronologies For Middle Palaeolithic Deposits At El Mnasra And El Harhoura 2, Morocco: Implications For Late Pleistocene Human-Environment Interactions Along The Atlantic Coast Of Northwest Africa, Zenobia Jacobs, Richard Roberts, Roland Nespoulet, M El Hajraoui, Andre Debenath

Richard G Roberts

Optically stimulated luminescence (OSL) measurements were made on individual, sand-sized grains of quartz from Middle Palaeolithic deposits at two cave sites (El Harhoura 2 and El Mnasra) on the Atlantic coast of Morocco. We were able to calculate OSL ages for 32 of the 33 samples collected from the Middle Palaeolithic deposits, including the earliest and latest Aterian levels at both sites. These ages reveal periods of occupation between about 110 and 95 ka (thousands of years ago), and at ~75 ka. A late Middle Palaeolithic occupation of El Harhoura 2 is also recorded at ~55 ka. Our single-grain OSL …


Single-Grain Optical Dating Of Grave-Infill Associated With Human Burials At Lake Mungo Australia, Jonathon Olley, Richard Roberts, Hiroyuki Yoshida, James M Bowler Mar 2013

Single-Grain Optical Dating Of Grave-Infill Associated With Human Burials At Lake Mungo Australia, Jonathon Olley, Richard Roberts, Hiroyuki Yoshida, James M Bowler

Richard G Roberts

Recent age constraints on Australia's oldest human remains (Mungo I and III), found at Lake Mungo in western New South Wales, relied on optical dating of sands from the same stratigraphic units as those into which the remains had been inserted (42±3 ka) and those that overlay the graves (38±2 ka), giving a burial age of 40±2 ka. This indirect means of dating the burials was necessary because the original site from which the remains had been excavated had been completely eroded away. At the time of the original excavation of the Mungo III grave, blocks of sediment from the …


Single-Grain Osl Dating At La Grotte Des Contrebandiers ('Smugglers' Cave'), Morocco: Improved Age Constraints For The Middle Paleolithic Levels, Richard Roberts, Zenobia Jacobs, Michael Meyer, V Aldeias, M El Hajraoui, H Dibbie Mar 2013

Single-Grain Osl Dating At La Grotte Des Contrebandiers ('Smugglers' Cave'), Morocco: Improved Age Constraints For The Middle Paleolithic Levels, Richard Roberts, Zenobia Jacobs, Michael Meyer, V Aldeias, M El Hajraoui, H Dibbie

Richard G Roberts

Optically stimulated luminescence (OSL) measurements of individual quartz grains are reported for Middle Paleolithic (MP) or Middle Stone Age (MSA) deposits in La Grotte des Contrebandiers, Morocco. Single-grain measurements enable rejection of grains that may lead to under- or over-estimation of age due to malign luminescence properties or remobilisation of grains after burial. We identified the former using a range of experimental procedures and objective rejection criteria. Three post-depositional factors influenced the distribution pattern of equivalent dose (De) values for the remaining single grains: the disintegration of roof spall liberating unbleached, older grains into otherwise well-bleached sediments; the intrusion of …


Photocatalytic Oxidation Of Methanol Using Titanium Dioxide/Single-Walled Carbon Nanotube Composite, Jun Chen, Carol M. Lynam, Chonlada Dechakiatkrai, Gordon G. Wallace, Sukon Phanichphant Mar 2013

Photocatalytic Oxidation Of Methanol Using Titanium Dioxide/Single-Walled Carbon Nanotube Composite, Jun Chen, Carol M. Lynam, Chonlada Dechakiatkrai, Gordon G. Wallace, Sukon Phanichphant

Gordon Wallace

Titanium dioxide/single-walled carbon nanotube TiO2/SWNT composites were prepared for photocatalytic applications. Thecomposites were characterized using UV-visible and Raman spectroscopy, zeta-potential measurements, cyclic voltammetrycoupled with a photoreactor, scanning electron microscopy, and transmission electron microscopy coupled with energy dispersiveX-ray spectroscopy. The photocatalytic activity of TiO2 and the TiO2/SWNT composite was investigated using the photo-oxidationof methanol in sulfuric acid as supporting electrolyte. The results indicate that the TiO2/SWNT composite enhances the photocatalyticactivity compared to TiO2 alone. Electrochemical studies of the TiO2/SWNT composite were also carried out in varioussupporting electrolytes and the presence of SWNTs was shown to increase the current achieved in voltammetric …


Direct Ascorbic Acid Detection With Ferritin Immobilized On Single-Walled Carbon Nanotubes, Chonlada Dechakiatkrai, Jun Chen, Carol M. Lynam, Kwang Min Shin, Seon Jeong Kim, Sukon Phanichphant, Gordon G. Wallace Mar 2013

Direct Ascorbic Acid Detection With Ferritin Immobilized On Single-Walled Carbon Nanotubes, Chonlada Dechakiatkrai, Jun Chen, Carol M. Lynam, Kwang Min Shin, Seon Jeong Kim, Sukon Phanichphant, Gordon G. Wallace

Gordon Wallace

Ferritin protein was noncovalently immobilized onto single-walled carbon nanotubes (SWNTs). This SWNT/ferritin composite was characterized using cyclic voltammetry, UV-visible spectroscopy, Raman spectroscopy, and high-resolution transmission electron microscopy. The use of the SWNT/ferritin film as an amperometric biosensor was demonstrated by sensing ascorbic acid in phosphate-buffered saline solution with a sensitivity of 767 uAmg. It demonstrated that ferritin protein bound to SWNTs enhances the oxidation reaction of ascorbic acid over 11-fold.


Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler Feb 2013

Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler

Shulei Chou

Free-standingsingle-walledcarbonnanotube/SnO2 (SWCNT/SnO2) anodepaper was prepared by vacuum filtration of SWCNT/SnO2 hybrid material which was synthesized by the polyol method. From field emission scanning electron microscopy and transmission electron microscopy, the CNTs form a three-dimensional nanoporous network, in which ultra-fine SnO2 nanoparticles, which had crystallite sizes of less than 5 nm, were distributed, predominately as groups of nanoparticles on the surfaces of singlewalled CNT bundles. Electrochemical measurements demonstrated that the anodepaper with 34 wt.% SnO2 had excellent cyclic retention, with the high specific capacity of 454 mAh g−1 beyond 100 cycles at a current …