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Articles 1 - 23 of 23
Full-Text Articles in Physical Sciences and Mathematics
Geothermal Energy And Its Impacts On The Environment, Aditi Gorthy, Nathan Tran, Laureen Pierre-Louis
Geothermal Energy And Its Impacts On The Environment, Aditi Gorthy, Nathan Tran, Laureen Pierre-Louis
Mako: NSU Undergraduate Student Journal
From the multitude of energy sources that we have developed throughout the eons, renewable energy or “clean energy” has been on the rise to combat global warming and climate change which burning nonrenewable sources of energy have contributed to. Before geothermal energy is used as part of the mainstream energy sources some aspects must be analyzed and resolved. Unfortunately, geothermal power plants still release pollutants, such as carbon dioxide and sulfur dioxide, into the environment and cause general environmental disruptions due to drilling and changes in land formations. Recent and future studies have been and should be conducted to find …
Polychlorinated Organic Contaminants In Baleen From North Pacific Ocean Whales, Briana R. Coulter
Polychlorinated Organic Contaminants In Baleen From North Pacific Ocean Whales, Briana R. Coulter
All HCAS Student Capstones, Theses, and Dissertations
Persistent organic pollutants (POP) have been detected and analyzed in various baleen whale tissues (blubber, muscles, liver, etc.) This study concentrated on detecting 7 polychlorinated biphenyls (PCB) and 14 organochlorine pesticides from baleen, a baleen whale tissue never before analyzed for POPs. These data were used to investigate temporal and geographic trends by sampling at every 1 cm interval along the length of the baleen plate. Four species of baleen whales stranded in the North Pacific Ocean were included in this study: gray (n=2), humpback (n=2), minke (n=1), and blue (n=1) whales. Organic contaminant concentrations were analyzed with respect to …
The Variability Of Seawater Carbonate Chemistry In Two Florida Urban Mangrove Ecosystems, Alexandrina R. Rangel
The Variability Of Seawater Carbonate Chemistry In Two Florida Urban Mangrove Ecosystems, Alexandrina R. Rangel
All HCAS Student Capstones, Theses, and Dissertations
Anthropogenic carbon dioxide (CO2) emissions into the atmosphere are yielding serious impacts across the world’s ocean, including ocean acidification, sea level rise, and increasing seawater temperature. However, these changes are not occurring uniformly across all marine ecosystems. Coastal ecosystems, such as mangroves, already experience extreme and variable environmental conditions due to natural biogeochemical and physical processes. The goal of this study was to document small-scale variability in two urban mangrove ecosystems to gain insight into how ocean acidification will manifest within these systems. Using a stand-up paddleboard, a suite of sensors, and traditional bottle sampling techniques, we measured …
Effects Of Nitrogen Depletion On The Biosorption Capacities Of Neochloris Minuta And Neochloris Alveolaris For Five Heavy Metals, Dimitri Giarikos, Jessica Brown, Reza Razeghifard, Duy Vo, Ammy Castillo, Nikhil Nagabandi, Justin Gaffney, Miriam Zelden, Anna Antakshinova, Sara Rodriguez, Safiyah Muhammad
Effects Of Nitrogen Depletion On The Biosorption Capacities Of Neochloris Minuta And Neochloris Alveolaris For Five Heavy Metals, Dimitri Giarikos, Jessica Brown, Reza Razeghifard, Duy Vo, Ammy Castillo, Nikhil Nagabandi, Justin Gaffney, Miriam Zelden, Anna Antakshinova, Sara Rodriguez, Safiyah Muhammad
Chemistry and Physics Faculty Articles
Neochloris minuta and Neochloris alveolaris grown in nitrogen-rich (+ N) and nitrogen-depleted (-N) media were tested for their heavy metal maximum biosorption capacities (qmax) and adsorption percent efficiencies (R%). By removing nitrogen from the growth media, both algal species showed an increase in their lipid content and a decrease in their protein content. Langmuir and Freundlich adsorption isotherms were used to determine the qmax and adsorption efficiencies of the + N and −N algae in the recovery of Pb2+, Cd2+, Zn2+, Cu2+, and Ni2+. When comparing the …
Assessing The Ecological Risk Of Heavy Metal Sediment Contamination From Port Everglades Florida, Dimitri G. Giarikos, Laura White, Amy C. Hirons
Assessing The Ecological Risk Of Heavy Metal Sediment Contamination From Port Everglades Florida, Dimitri G. Giarikos, Laura White, Amy C. Hirons
SECLER Data
Port sediments are often contaminated with metals and organic compounds from anthropogenic sources. Port dredging can remobilize contaminated sediments, resulting in harmful impacts to the benthic community. Twelve sediment cores were collected from four Port Everglades, Florida sites and a control site; surface sediment was collected at two nearby coral reef sites. Sediment cores, sampled every 5 cm, were quantified for 14 heavy metals using induced coupled plasma mass spectrometry (ICPMS). Geo-accumulation index shows moderate-to-strong contamination of As and Mo in port sediments, and potential ecological risk indicates moderate-to-significantly high overall metal contamination. Arsenic port sediment concentrations exceed threshold effect …
Heavy Metal Accumulation In Seagrasses In Southeastern Florida, Erin Smith
Heavy Metal Accumulation In Seagrasses In Southeastern Florida, Erin Smith
HCNSO Student Theses and Dissertations
Seagrass beds are among the most ecologically important systems in the marine environment. They provide the primary production to nearby coral reef and mangrove communities, and seagrasses comprise a large component of the diets of many marine organisms including fishes, small invertebrate species, and many protected species such as manatees and sea turtles. This consumption provides a pathway for many contaminants to enter the marine food web via the seagrasses. The coastal location of seagrass beds causes them to be especially susceptible to anthropogenic pollution, including accumulation of heavy metals, which has been shown to have many adverse health effects …
Dietary Transfer Of Heavy Metals In Manatees, E. M. Smith, Dimitri Giarikos, A. Daniels, Amy Hirons
Dietary Transfer Of Heavy Metals In Manatees, E. M. Smith, Dimitri Giarikos, A. Daniels, Amy Hirons
Chemistry and Physics Faculty Proceedings, Presentations, Speeches, Lectures
In recent decades, manatees and dugongs globally have exhibited potentially detrimental levels of a variety of heavy metals in their body tissues. The threatened Florida manatee (Trichechus manatus latirostris), which is a subspecies of the West Indian manatee (Trichechus manatus), has shown corresponding high levels of heavy metals in their blood, skin, liver, and kidneys. As obligate herbivores, these animals rely heavily upon seagrasses as a major component of their diet. Globally, seagrasses at low latitudes have high levels of heavy metals in their tissues. Detrimental levels of heavy metals in Sirenians have not been established …
North Pacific Marine Mammals Populations Rocked By Heavy Metal Concentrations, Pilar Ferdinando, Chitra Gotluru, Tanya Juneja, Kevin Cash, Karanja Sekou, Emily Pope, L. K. Duffy, Dimitri Giarikos, Amy Hirons
North Pacific Marine Mammals Populations Rocked By Heavy Metal Concentrations, Pilar Ferdinando, Chitra Gotluru, Tanya Juneja, Kevin Cash, Karanja Sekou, Emily Pope, L. K. Duffy, Dimitri Giarikos, Amy Hirons
Chemistry and Physics Faculty Proceedings, Presentations, Speeches, Lectures
No abstract provided.
Water-Soluble Soa From Alkene Ozonolysis: Composition And Droplet Activation Kinetics Inferences From Analysis Of Ccn Activity, A. Asa-Awuku, A. Nenes, Song Gao, R. C. Flagan, John H. Seinfeld
Water-Soluble Soa From Alkene Ozonolysis: Composition And Droplet Activation Kinetics Inferences From Analysis Of Ccn Activity, A. Asa-Awuku, A. Nenes, Song Gao, R. C. Flagan, John H. Seinfeld
Chemistry and Physics Faculty Articles
Cloud formation characteristics of the water-soluble organic fraction (WSOC) of secondary organic aerosol (SOA) formed from the ozonolysis of alkene hydrocarbons (terpinolene, 1-methlycycloheptene and cycloheptene) are studied. Based on size-resolved measurements of CCN activity (of the pure and salted WSOC samples) we estimate the average molar volume and surface tension depression associated with the WSOC using Köhler Theory Analysis (KTA). Consistent with known speciation, the results suggest that the WSOC are composed of low molecular weight species, with an effective molar mass below 200 g mol−1. The water-soluble carbon is also surface-active, depressing surface tension 10–15% from that of pure …
Characterization Of Polar Organic Components In Fine Aerosols In The Southeastern United States: Identity, Origin, And Evolution, Song Gao, Jason D. Surratt, Eladio M. Knipping, Eric S. Edgerton, Mona Shahgholi, John H. Seinfeld
Characterization Of Polar Organic Components In Fine Aerosols In The Southeastern United States: Identity, Origin, And Evolution, Song Gao, Jason D. Surratt, Eladio M. Knipping, Eric S. Edgerton, Mona Shahgholi, John H. Seinfeld
Chemistry and Physics Faculty Articles
Filter samples of fine aerosols collected in the Southeastern United States in June 2004 were analyzed for the characterization of polar organic components. Four analytical techniques, liquid chromatography –mass spectrometry, ion trap mass spectrometry, laser desorption ionization mass spectrometry, and high-resolution mass spectrometry, were used for identification and quantification. Forty distinct species were detected, comprising on average 7.2% and 1.1% of the total particulate organic mass at three inland sites and a coastal site, respectively. The relative abundance of these species displays a rather consistent distribution pattern in the inland region, whereas a different pattern is found at the coastal …
Gas-Phase Products And Secondary Aerosol Yields From The Ozonolysis Of Ten Different Terpenes, Anita Lee, Allen H. Goldstein, Melita D. Keywood, Song Gao, Varuntida Varutbangkul, Roya Bahreini, Nga L. Ng, Richard C. Flagan, John H. Seinfeld
Gas-Phase Products And Secondary Aerosol Yields From The Ozonolysis Of Ten Different Terpenes, Anita Lee, Allen H. Goldstein, Melita D. Keywood, Song Gao, Varuntida Varutbangkul, Roya Bahreini, Nga L. Ng, Richard C. Flagan, John H. Seinfeld
Chemistry and Physics Faculty Articles
The ozonolyses of six monoterpenes (α-pinene, β-pinene, 3-carene, terpinolene, α-terpinene, and myrcene), two sesquiterpenes (α-humulene and β-caryophyllene), and two oxygenated terpenes (methyl chavicol and linalool) were conducted individually in Teflon chambers to examine the gas-phase oxidation product and secondary organic aerosol (SOA) yields from these reactions. Particle size distribution and number concentration were monitored and allowed for the calculation of the SOA yield from each experiment, which ranged from 1 to 54%. A proton transfer reaction mass spectrometer (PTR-MS) was used to monitor the evolution of gas-phase products, identified by their mass to charge ratio (m/z). …
Measurements Of Secondary Organic Aerosol From Oxidation Of Cycloalkenes, Terpenes, And M-Xylene Using An Aerodyne Aerosol Mass Spectrometer, Roya Bahreini, Melita D. Keywood, Nga L. Ng, Varuntida Varutbangkul, Song Gao, Richard C. Flagan, John H. Seinfeld, D. R. Worsnop, J. L. Jimenez
Measurements Of Secondary Organic Aerosol From Oxidation Of Cycloalkenes, Terpenes, And M-Xylene Using An Aerodyne Aerosol Mass Spectrometer, Roya Bahreini, Melita D. Keywood, Nga L. Ng, Varuntida Varutbangkul, Song Gao, Richard C. Flagan, John H. Seinfeld, D. R. Worsnop, J. L. Jimenez
Chemistry and Physics Faculty Articles
The Aerodyne aerosol mass spectrometer (AMS) was used to characterize physical and chemical properties of secondary organic aerosol (SOA) formed during ozonolysis of cycloalkenes and biogenic hydrocarbons and photooxidation of m-xylene. Comparison of mass and volume distributions from the AMS and differential mobility analyzers yielded estimates of “effective” density of the SOA in the range of 0.64−1.45 g/cm3, depending on the particular system. Increased contribution of the fragment at m/z 44, CO2+ ion fragment of oxygenated organics, and higher “Δ” values, based on ion series analysis of the mass spectra, in nucleation experiments …
Aerosol Properties And Chemical Apportionment Of Aerosol Optical Depth At Locations Off The U.S. East Coast In July And August 2001, Brian I. Magi, Peter V. Hobbs, Thomas W. Kirchstetter, Tihomir Novakov, Dean A. Hegg, Song Gao, Jens Redemann, Beat Schmid
Aerosol Properties And Chemical Apportionment Of Aerosol Optical Depth At Locations Off The U.S. East Coast In July And August 2001, Brian I. Magi, Peter V. Hobbs, Thomas W. Kirchstetter, Tihomir Novakov, Dean A. Hegg, Song Gao, Jens Redemann, Beat Schmid
Chemistry and Physics Faculty Articles
Airborne in situ measurements of vertical profiles of the aerosol light scattering coefficient, light absorption coefficient, and single scattering albedo (ω0) are presented for locations off the East Coast of the United States in July–August 2001. The profiles were obtained in relatively clean air, dominated by airflows that had passed over Canada and the Atlantic Ocean. Comparisons of aerosol optical depths (AODs) at 550 nm derived from airborne in situ and sun-photometer measurements agree, on average, to within 0.034 ± 0.021. A frequency distribution of ω0 measured in the atmospheric boundary layer off the coast yields …
Emissions From Miombo Woodland And Dambo Grassland Savanna Fires, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Donald R. Blake, Song Gao, Thomas W. Kirchstetter
Emissions From Miombo Woodland And Dambo Grassland Savanna Fires, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Donald R. Blake, Song Gao, Thomas W. Kirchstetter
Chemistry and Physics Faculty Articles
Airborne measurements of trace gases and particles over and downwind of two prescribed savanna fires in Zambia are described. The measurements include profiles through the smoke plumes of condensation nucleus concentrations and normalized excess mixing ratios of particles and gases, emission factors for 42 trace gases and seven particulate species, and vertical profiles of ambient conditions. The fires were ignited in plots of miombo woodland savanna, the most prevalent savanna type in southern Africa, and dambo grassland savanna, an important enclave of miombo woodland ecosystems. Emission factors for the two fires are combined with measurements of fuel loading, combustion factors, …
Distributions Of Trace Gases And Aerosols During The Dry Biomass Burning Season In Southern Africa, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Donald R. Blake, Song Gao, Thomas W. Kirchstetter
Distributions Of Trace Gases And Aerosols During The Dry Biomass Burning Season In Southern Africa, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Donald R. Blake, Song Gao, Thomas W. Kirchstetter
Chemistry and Physics Faculty Articles
Vertical profiles in the lower troposphere of temperature, relative humidity, sulfur dioxide (SO2), ozone (O3), condensation nuclei (CN), and carbon monoxide (CO), and horizontal distributions of twenty gaseous and particulate species, are presented for five regions of southern Africa during the dry biomass burning season of 2000. The regions are the semiarid savannas of northeast South Africa and northern Botswana, the savanna-forest mosaic of coastal Mozambique, the humid savanna of southern Zambia, and the desert of western Namibia. The highest average concentrations of carbon dioxide (CO2), CO, methane (CH4), O3, …
Emissions Of Trace Gases And Particles From Savanna Fires In Southern Africa, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Isaac T. Bertschi, Donald R. Blake, Isobel J. Simpson, Song Gao, Thomas W. Kirchstetter, Tihomir Novakov
Emissions Of Trace Gases And Particles From Savanna Fires In Southern Africa, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Isaac T. Bertschi, Donald R. Blake, Isobel J. Simpson, Song Gao, Thomas W. Kirchstetter, Tihomir Novakov
Chemistry and Physics Faculty Articles
Airborne measurements made on initial smoke from 10 savanna fires in southern Africa provide quantitative data on emissions of 50 gaseous and particulate species, including carbon dioxide, carbon monoxide, sulfur dioxide, nitrogen oxides, methane, ammonia, dimethyl sulfide, nonmethane organic compounds, halocarbons, gaseous organic acids, aerosol ionic components, carbonaceous aerosols, and condensation nuclei (CN). Measurements of several of the gaseous species by gas chromatography and Fourier transform infrared spectroscopy are compared. Emission ratios and emission factors are given for eight species that have not been reported previously for biomass burning of savanna in southern Africa (namely, dimethyl sulfide, methyl nitrate, five …
Evolution Of Gases And Particles From A Savanna Fire In South Africa, Peter V. Hobbs, Parikhit Sinha, Robert J. Yokelson, Ted J. Christian, Donald R. Blake, Song Gao, Thomas W. Kirchstetter, Tihomir Novakov, Peter Pilewskie
Evolution Of Gases And Particles From A Savanna Fire In South Africa, Peter V. Hobbs, Parikhit Sinha, Robert J. Yokelson, Ted J. Christian, Donald R. Blake, Song Gao, Thomas W. Kirchstetter, Tihomir Novakov, Peter Pilewskie
Chemistry and Physics Faculty Articles
Airborne measurements of particles and gases from a 1000-ha savanna fire in South Africa are presented. These measurements represent the most extensive data set reported on the aging of biomass smoke. The measurements include total concentrations of particles (CN), particle sizes, particulate organic carbon and black carbon, light-scattering coefficients, downwelling UV fluxes, and mixing ratios for 42 trace gases and 7 particulate species. The ratios of excess nitrate, ozone, and gaseous acetic acid to excess CO increased significantly as the smoke aged over ∼40–45 min, indicating that these species were formed by photochemistry in the plume. For 17 other species, …
Water-Soluble Organic Components In Aerosols Associated With Savanna Fires In Southern Africa: Identification, Evolution, And Distribution, Song Gao, Dean A. Hegg, Peter V. Hobbs, Thomas W. Kirchstetter, Brian I. Magi, Martin Sadilek
Water-Soluble Organic Components In Aerosols Associated With Savanna Fires In Southern Africa: Identification, Evolution, And Distribution, Song Gao, Dean A. Hegg, Peter V. Hobbs, Thomas W. Kirchstetter, Brian I. Magi, Martin Sadilek
Chemistry and Physics Faculty Articles
During the SAFARI 2000 field campaign, both smoke aerosols from savanna fires and haze aerosols in the boundary layer and in the free troposphere were collected from an aircraft in southern Africa. These aerosol samples were analyzed for their water-soluble chemical components, particularly the organic species. A novel technique, electrospray ionization-ion trap mass spectrometry, was used concurrently with an ion chromatography system to analyze for carbohydrate species. Seven carbohydrates, seven organic acids, five metallic elements, and three inorganic anions were identified and quantified. On the average, these 22 species comprised 36% and 27% of the total aerosol mass in haze …
Clear-Column Radiative Closure During Ace-Asia: Comparison Of Multiwavelength Extinction Derived From Particle Size And Composition With Results From Sun Photometry, J. Wang, Richard C. Flagan, John H. Seinfeld, Haflidi Jonsson, D. R. Collins, P. B. Russell, Beat Schmid, Jens Redemann, J. M. Livingston, Song Gao, Dean A. Hegg, E. J. Welton
Clear-Column Radiative Closure During Ace-Asia: Comparison Of Multiwavelength Extinction Derived From Particle Size And Composition With Results From Sun Photometry, J. Wang, Richard C. Flagan, John H. Seinfeld, Haflidi Jonsson, D. R. Collins, P. B. Russell, Beat Schmid, Jens Redemann, J. M. Livingston, Song Gao, Dean A. Hegg, E. J. Welton
Chemistry and Physics Faculty Articles
From March to May 2001, aerosol size distributions and chemical compositions were measured using differential mobility analyzers (DMA), an aerodynamic particle sizer (APS), Micro-Orifice Uniform Deposit Impactors (MOUDI), and denuder samplers onboard the Twin Otter aircraft as part of the Aerosol Characterization Experiment (ACE)-Asia campaign. Of the 19 research flights, measurements on four flights that represented different aerosol characteristics are analyzed in detail. Clear-column radiative closure is studied by comparing aerosol extinctions predicted using in situ aerosol size distribution and chemical composition measurements to those derived from the 14-wavelength NASA Ames Airborne Tracking Sun photometer (AATS-14). In the boundary layer, …
Experimental And Modeling Studies Of Secondary Organic Aerosol Formation And Some Applications To The Marine Boundary Layer, Song Gao, Dean A. Hegg, Glendon Frick, Peter F. Caffrey, Louise Pasternack, Chris Cantrell, William Sullivan, John Ambrusko, Thomas Albrechcinski, Thomas W. Kirchstetter
Experimental And Modeling Studies Of Secondary Organic Aerosol Formation And Some Applications To The Marine Boundary Layer, Song Gao, Dean A. Hegg, Glendon Frick, Peter F. Caffrey, Louise Pasternack, Chris Cantrell, William Sullivan, John Ambrusko, Thomas Albrechcinski, Thomas W. Kirchstetter
Chemistry and Physics Faculty Articles
A series of controlled experiments were carried out in the Calspan Corporation's 600 m3environmental chamber to study some secondary organic aerosol formation processes. Three precursor-ozone systems were studied: cyclopentene-ozone, cyclohexene-ozone, and α-pineneozone. Additionally, SO2 was added to the initial gas mixture in several instances and was likely present at trace levels in the ostensibly organic-only experiments. It was found that all three systems readily formed new submicron aerosols at very low reactant levels. The chemical composition of formed aerosols was consistent with some previous studies, but the yields of organic products were found to be lower in …
Sulfur Dioxide Uptake And Oxidation In Sea-Salt Aerosol, William Hoppel, Louise Pasternack, Peter F. Caffrey, Glendon Frick, James Fitzgerald, Dean A. Hegg, Song Gao, John Ambrusko, Thomas Albrechcinski
Sulfur Dioxide Uptake And Oxidation In Sea-Salt Aerosol, William Hoppel, Louise Pasternack, Peter F. Caffrey, Glendon Frick, James Fitzgerald, Dean A. Hegg, Song Gao, John Ambrusko, Thomas Albrechcinski
Chemistry and Physics Faculty Articles
Measurements of SO2 and O3 uptake by sea-salt and NaCl aerosol were made in a 600 m3environmental chamber by measuring the rate of SO2 and O3 depletion during nebulization of seawater and NaCl solutions. The experiments were carried out with starting relative humidity between 80% and 92%, with SO2 concentrations between 35 and 60 ppb, and ozone concentrations between O and 110 ppb. For NaCl, no SO2 or O3uptake was observed. For sea-salt aerosol, uptake in the range of 0.21 and 1.2 millimoles of S per liter of (nebulized) seawater …
In-Cloud Oxidation Of So2 By O3 And H2o2: Cloud Chamber Measurements And Modeling Of Particle Growth, Peter F. Caffrey, William Hoppel, Glendon Frick, Louise Pasternack, James Fitzgerald, Dean A. Hegg, Song Gao, W. R. Leaitch, Nicole Shantz, Thomas Albrechcinski, John Ambrusko
In-Cloud Oxidation Of So2 By O3 And H2o2: Cloud Chamber Measurements And Modeling Of Particle Growth, Peter F. Caffrey, William Hoppel, Glendon Frick, Louise Pasternack, James Fitzgerald, Dean A. Hegg, Song Gao, W. R. Leaitch, Nicole Shantz, Thomas Albrechcinski, John Ambrusko
Chemistry and Physics Faculty Articles
Controlled cloud chamber experiments were conducted to measure particle growth resulting from the oxidation of SO2 by O3 and H2O2 in cloud droplets formed on sulfuric acid seed aerosol. Clouds were formed in a 590 m3 environmental chamber with total liquid water contents ranging from 0.3–0.6 g m−3 and reactant gas concentrations <10 ppbv for SO2 and H2O2 and <70 ppbv for O3. Aerosol growth was measured by comparison of differential mobility analyzer size distributions before and after each 3–4 min cloud cycle. Predictions of aerosol growth were then made with a full microphysical cloud …
Particle Formation And Growth From Ozonolysis Of Α-Pinene, William Hoppel, James Fitzgerald, Glendon Frick, Peter F. Caffrey, Louise Pasternack, Dean A. Hegg, Song Gao, W. Richard Leaitch, Nicole Shantz, Chris Cantrell, Thomas Albrechcinski, John Ambrusko, William Sullivan
Particle Formation And Growth From Ozonolysis Of Α-Pinene, William Hoppel, James Fitzgerald, Glendon Frick, Peter F. Caffrey, Louise Pasternack, Dean A. Hegg, Song Gao, W. Richard Leaitch, Nicole Shantz, Chris Cantrell, Thomas Albrechcinski, John Ambrusko, William Sullivan
Chemistry and Physics Faculty Articles
Observations of particle nucleation and growth during ozonolysis of α-pinene were carried out in Calspan's 600 m3 environmental chamber utilizing relatively low concentrations of α-pinene (15 ppb) and ozone (100 ppb). Model simulations with a comprehensive sectional aerosol model which incorporated the relevant gas-phase chemistry show that the observed evolution of the size distribution could be simulated within the accuracy of the experiment by assuming only one condensable product produced with a molar yield of 5% to 6% and a saturation vapor pressure (SVP) of about 0.01 ppb or less. While only one component was required to simulate the …