Physical Sciences and Mathematics Commons^™

Integrated Geophysical Approach Using Electrical Resistivity Tomography And Multichannel Analysis Of Surface Wave In Assessing Wilson Spring Development, Ibrahim E. Ahmed

Doctoral Dissertations

"This research investigated fractured zones leading to preferential flow paths of Wilson Spring. In this context, electrical resistivity tomography (ERT) data and multi-channel analyses of surface waves (MASW) data were acquired at studied site with the purpose of mapping a variable depth to top of bedrock and geological structures.

Interpretation of the boreholes, MASW, and ERT data indicated that a depth to top of rock does vary significantly at the studied site due to many solution-widened fractures. Multiple near-vertical solution-widened fractures were mapped in the studied site based on the interpretation of the ERT data. The mapped solution-widened fractures appear …

Palynological Studies Of Holocene Lake Sediments In The Missouri Ozarks, Robert D. Haselwander

Doctoral Dissertations

"Five small lakes in southeast Missouri (Frisco, Pine Forest, and Bray Area lakes [Phelps County], and Cypress and Blue ponds [Bollinger County]) were cored for paleolimnological studies. Cores were evaluated for their sedimentology, palynology, and geochemistry. In two of these lakes (Bray Area and Pine Forest lakes) the planktonic algae were also studied in the water column, along with ecological parameters. Algae in the sediments were compared to algae in the water to understand the resistance of different species to decay, and a suggested methodology for this work is described. Reconstructions of the past environments around each lake were created …

Mechanisms For Improving Information Quality In Smartphone Crowdsensing Systems, Francesco Restuccia

Doctoral Dissertations

"Given its potential for a large variety of real-life applications, smartphone crowdsensing has recently gained tremendous attention from the research community. Smartphone crowdsensing is a paradigm that allows ordinary citizens to participate in large-scale sensing surveys by using user-friendly applications installed in their smartphones. In this way, fine-grained sensing information is obtained from smartphone users without employing fixed and expensive infrastructure, and with negligible maintenance costs.

Existing smartphone sensing systems depend completely on the participants' willingness to submit up-to-date and accurate information regarding the events being monitored. Therefore, it becomes paramount to scalably and effectively determine, enforce, and optimize the …

Small Sample Confidence Bands For The Survival Functions Under Proportional Hazards Model, Emad Mohamed Abdurasul

Doctoral Dissertations

"In this work, a saddlepoint-based method is developed for generating small sample confidence bands for the population survival function from the Kaplan-Meier (KM), the product limit (PL), and Abdushukurov-Cheng-Lin (ACL) survival function estimators, under the proportional hazards model. In the process the exact distribution of these estimators is derived and developed mid-population tolerance bands for said estimators. The proposed saddlepoint method depends upon the Mellin transform of the zero-truncated survival estimator which is derived for the KM, PL, and ACL estimators. These transforms are inverted via saddlepoint approximations to yield highly accurate approximations to the cumulative distribution functions of the …

Electrodeposition And Characterization Of Metals And Metal Oxides For Energy Conversion And Storage, Ying-Chau Liu

Doctoral Dissertations

"This dissertation investigates the electrodeposition of metal and metal oxide thin films applicable to solar water splitting cells. Paper I describes the synthesis of cobalt hydroxide, ß-Co(OH)₂, by electrochemically reducing tris(ethylenediamine)cobalt(III) in alkaline solution. Paper II presents a scheme to convert the ß-Co(OH)₂ to CoOOH and Co₃O₄ and compares their catalytic activity for the oxygen evolution reaction. Co₃O₄ appears to be a more active catalyst than CoOOH based on Tafel analysis. However, when the observed current densities are corrected for the measured electrochemically active surface area, the linear region of the …

Liposomal Delivery Of Pde5 Inhibitors And Ut-15c To Human Erythrocytes, Elizabeth Anne Bowles

Doctoral Dissertations

"Previous studies have shown that the controlled release of adenosine triphosphate (ATP) from human erythrocytes is an important mechanism for the regulation of vascular caliber. However, erythrocytes from patients with pulmonary arterial hypertension (PAH) fail to release ATP in response to the physiological stimuli of exposure to low oxygen tension or mechanical deformation of a magnitude these cells would encounter in the pulmonary circulation. This defect could be a significant contributor to the increased pulmonary vascular resistance (PVR) that is the cause of the pathological increase in vascular pressures in humans with PAH.

One important approach to the treatment of …

Spectroscopic And Spectro-Astrometric Analysis Of T Tauri Stars, Logan Ryan Brown

Doctoral Dissertations

"To understand our own solar origins, we must investigate the composition of the protoplanetary disk from which the solar system formed. To infer this, we study analogs to the early solar system called T Tauri stars. These objects are low-mass, pre-main sequence stars surrounded by circumstellar disks of material from which planets are believed to form. We present high-resolution, near-infrared spectroscopic data for the T Tauri stars DR Tau and AA Tau using NIRSPEC at the Keck II telescope. For DR Tau, a spectro-astrometric analysis was performed, obtaining sub-seeing spatial information on water emission. Alongside a disk model, we constrained …

Existence And Classification Of Nonoscillatory Solutions Of Two Dimensional Time Scale Systems, Özkan Özturk

Doctoral Dissertations

"During the past years, there has been an increasing interest in studying oscillation and nonoscillation criteria for dynamic equations and systems on time scales that harmonize the oscillation and nonoscillation theory for the continuous and discrete cases in order to combine them in one comprehensive theory and eliminate obscurity from both.

We not only classify nonoscillatory solutions of dynamic equations and systems on time scales but also guarantee the (non)existence of such solutions by using the Knaster fixed point theorem, Schauder - Tychonoff fixed point theorem, and Schauder fixed point theorem. The approach is based on the sign of nonoscillatory …

Geophysical Imaging Of Karst Features In Missouri, Jeremiah Chukwunonso Obi

Doctoral Dissertations

"Automated electrical resistivity tomography (ERT) supported with multichannel analysis of surface waves (MASW) and boring data were used to map karst related features in Missouri in order to understand karst processes better in Missouri. Previous works on karst in Missouri were mostly surficial mapping of bedrock outcrops and joints, which are not enough to define the internal structure of karst system, since most critical processes in karst occur underground. To understand these processes better, the density, placement and pattern of karst related features like solution-widened joints and voids, as well as top of bedrock were mapped. In the course of …

Fully Differential Study Of Projectile Coherence Effects In Ionization Of Molecular Hydrogen And Atomic Helium, Thusitha Priyantha Arthanayaka

Doctoral Dissertations

"It has been well established, that projectile coherent properties are important for the study of atomic fragmentation processes. Recent studies of ionization of molecular hydrogen had demonstrated that measured double differential cross sections (DDCS) are very sensitive to the coherent length of the projectile. These measurements have been performed with varied coherence length of the projectiles by controlling the geometry of the collimating slits, which are placed before the target. Later, fully differential cross sections (FDCS) for a coherent and an incoherent projectile beam has been study for the same collision system and the results confirmed the important role of …

Detecting, Segmenting And Tracking Bio-Medical Objects, Mingzhong Li

Doctoral Dissertations

"Studying the behavior patterns of biomedical objects helps scientists understand the underlying mechanisms. With computer vision techniques, automated monitoring can be implemented for efficient and effective analysis in biomedical studies. Promising applications have been carried out in various research topics, including insect group monitoring, malignant cell detection and segmentation, human organ segmentation and nano-particle tracking.

In general, applications of computer vision techniques in monitoring biomedical objects include the following stages: detection, segmentation and tracking. Challenges in each stage will potentially lead to unsatisfactory results of automated monitoring. These challenges include different foreground-background contrast, fast motion blur, clutter, object overlap and …

Methodology Investigations For Shear Wave Splitting Analysis, Fansheng Kong

Doctoral Dissertations

"Over the past several decades, shear wave splitting analyses have been increasingly utilized to delineate mantle structure and probe mantle dynamics. However, the reported splitting parameters (fast polarization orientations and splitting times) are frequently inconsistent among different studies, partially due to the different techniques used to estimate the splitting parameters. Here the study conduct research on methodology investigations for shear wave splitting analysis, which are composed of two sub-topics, i.e., a systematic comparison of the transverse minimization (TM) and the splitting intensity (SI) techniques and applicability of the multiple-event stacking technique (MES). Numerical experiments are conducted using both synthetic and …

Seismic Anisotropy And Mantle Dynamics Beneath The Central And Western United States, Bin Yang

Doctoral Dissertations

"Various tectonic features and the recent availability of high-quality broadband seismic data from the USArray and other seismic stations in the central and western United States (CWUS) provide a distinct opportunity to test different anisotropy-forming mechanisms. For the first part of the study, a total of 4138 pairs of well-defined shear wave splitting (SWS) parameters observed at 445 stations on the northern Great Plains show systematic spatial variations of anisotropic characteristics. Azimuthally invariant fast orientations subparallel to the absolute plate motion (APM) direction are observed at most of the stations on the Superior Craton and the southern Yavapai province, indicating …

The Role Of Pre-Existing Basement Fabrics In The Initiation Of Continental Rifting: The Okavango Rift Zone, Botswana, Angelica Alvarez Naranjo

Doctoral Dissertations

"Integrated geophysical, remote sensing, and field investigations of the Okavango Rift Zone (ORZ), Botswana indicate that a feedback between optimum-oriented basement structures and fluid flow influence the nucleation and growth of continental rifts in their incipient stages. The ORZ, the youngest rift of the East African Rift System, occurs within a Proterozoic inter-cratonic suture zone - the NE-trending Precambrian Damara/Ghanzi-Chobe orogenic belts. The Pleistocene to Holocene ORZ forms a ~450 km long and ~100 km wide half-graben bounded by NE-trending normal faults. Basement units within the Damara/Ghanzi-Chobe orogenic belts exhibit a well-developed NE-trending linear fabric (045-065) defined by parallel limbs …

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan

Doctoral Dissertations

"As the rapid growing of nanotechnology, the release of engineered nanoparticles (ENPs) into the environment is inevitable. After entering the real environment, ENPs tend to react with different components of the ecosystem (e.g. water, soil, air, plants) and make their characterization difficult. Analyzing ENPs in these complex matrices still remains as a grand challenge. ENPs characterization is normally the first step of risk assessment. Current analytical techniques have shown some limitations in revealing the unique characteristics of ENPs in complex matrices and reliable analytical techniques are in urgent need. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) is an emerging …

Bioactivity/Cytotoxicity Of Micro-/Nano-Materials And Novel Development Of Fiber-Optic Probes For Single Cell Monitoring, Qingbo Yang

Doctoral Dissertations

"Manufactured nano-/micro-materials (MNMs) have been widely used and their interactions with niche biological environment are highly concerned for both of their biohazardous and bioactive effects, whereas no available comprehensive evaluations or regulations have been provided yet. This dissertation thus focuses on three major aspects: 1) fundamental toxicity understandings of a typical MNMs (zinc oxide nanoparticles), 2) bioactivity evaluations of representative bioactive MNMs, and 3) development of novel micro-probes for high spatial resolution monitoring. Firstly, the NP's concentration, irradiation, hydrodynamic size, and the localized pH, ionic strength, NP zeta-potential as well as dissolved oxygen levels were found correlated with the production …

Blended Learning In Chemistry Laboratory Courses: Enhancing Learning Outcomes And Aligning Student Needs With Available Resources, Shayna Brianne Burchett

Doctoral Dissertations

"Freshman science courses are intended to prepare students for the rigor and expectations of subsequent college science. While secondary education aims to prepare students for the college curriculum, many incoming freshman lack the sense of responsibility for their own learning that is essential for success in a college-level course. The freshman general-chemistry laboratory course at Missouri University of Science and Technology (Missouri S&T) was identified as a bottleneck course with a demand beyond accommodation capacity. To address the bottleneck and develop a sense of learner responsibility, a decision was made to investigate laboratory course delivery strategies. As a result of …

Assessment Of Highway Condition Using Combined Geophysical Surveys, Abdallah Alhadi Dera

Doctoral Dissertations

"Four pavement sections were investigated using ground penetrating radar (GPR) and Ultrasonic Surface Wave (USW). The objective of this research was to compare the effectiveness of two non-destructive geophysical tools, GPR and the PSPA, in assessing the condition of the pavements, composed of different construction materials. The GPR data were acquired using a 1.5 GHz antenna along five traverses spaced at two ft. intervals approximately 1000 ft. long. On the other hand, the PSPA data were acquired at the stations spaced at 1000 ft. along the five GPR traverses. Core samples were collected at each site to constrain the interpretation …

Continuous Flow Reactor For Carbonic Acid Hydrolysis/Pretreatment Of Microalgal Biomass To Produce Bioethanol, Nicholas Dudenhoeffer

Doctoral Dissertations

"In order to maximize bioethanol production an efficient pretreatment method for the hydrolysis of polysaccharides to fermentable sugars is necessary. Commonly used pretreatment methods are the slow enzymatic hydrolysis and the corrosive mineral acid hydrolysis process that requires a post-treatment neutralization step and generates waste stream. We investigated the high temperature water with carbonic acid catalyst as an alternative method. Carbonic acid generated from dissolved CO₂ is inexpensive and environmentally benign, and easily removed by decompression. A high pressure continuous flow reactor that can continuously process the wet biomass stream and perform the carbonic acid hydrolysis in-situ using the …

Modeling Daily Electricity Load Curve Using Cubic Splines And Functional Principal Components, Abdelmonaem Salem Jornaz

Doctoral Dissertations

"Forecasting electricity load is very important to the electric utilities as well as producers of power because accurate predictions can cut down costs by avoiding power shortages or surpluses. Of specific interest is the 24-hour daily electricity load profile, which provides insight into periods of high demand and periods where the use of electricity is at a minimum. Researchers have proposed many approaches to modeling electricity prices, real-time load, and day-ahead demand, with varying success. In this dissertation three new approaches to modeling and forecasting the 24-hour daily electricity load profiles are presented. The application of the proposed methods is …

Contribution Of New Thiol Antioxidant In The Treatment Of Acetaminophen Toxicity, Ahdab Naeem Khayyat

Doctoral Dissertations

"Acetaminophen (N-acetyl-p-aminophenol, APAP) is one of the most widely used over-the-counter antipyretic analgesic medications. It is safe at therapeutic doses, but an overdose can result in severe hepato-nephrotoxicity, a leading cause of drug-induced acute liver failure in the U.S. Although a few different mechanisms have been proposed for APAP-induced toxicity, a significant amount of evidence has pointed to the potential involvement of oxidative stress in acetaminophen toxicity. Depletion of glutathione (GSH) is one of the initiating steps in APAP-induced toxicity; therefore, one strategy for restricting organ damage is to restore GSH levels by using GSH prodrugs like N-acetylcysteine (NAC). Although …

Azimuthal Anisotropy Beneath North Central Africa From Shear Wave Splitting Analysis, Awad Abdussalam Henish Lemnifi

Doctoral Dissertations

"This study represents the first multi-station investigation of azimuthal anisotropy beneath the interior of north central Africa, including Libya and adjacent regions, using shear wave splitting (SWS) analysis. Data used in the study include recently available broadband seismic data obtained from 15 stations managed by the Libyan Center for Remote Sensing and Space Science, and those from five other stations at which data are publicly accessible. A total of 583 pairs of high-quality SWS measurements utilizing the PKS, SKKS, and SKS phases demonstrate primarily N-S fast orientations with an average splitting delay time of approximately 1.2 s. An absence of …

Synthesis And Functionalization Of A Triaryldiamine-Base Photoconductive/Photorefractive Composite, And Its Application To Aberrated Image Restoration, Yichen Liang

Doctoral Dissertations

"Organic photorefractive (PR) composites have recently emerged as an important class of materials for applications including high-density data storage, optical communication, and biomedical imaging. In an effort to further improve their performance, this study focused on the utilization of functionalized semiconductor nanocrystals to photosensitize triaryamine (TPD)-based PR composites, as well as the application of TPD-based PR composites in the restoration of aberrated optical information. A novel approach to functionalize CdSe quantum dot (QCdSe) was firstly introduced where the sulfonated triarydiamine (STPD) was used as charge-transporting ligand to passivate QCdSe. TPD-based photoconductive and PR composites were photosensitized with the STPD-passivated QCdSe …

Construction Of Multi-State Potential Energy Surfaces For Spectroscopy And Dynamics, Phalgun Lolur

Doctoral Dissertations

"This dissertation is about construction and visualization of multi-state Born-Oppenheimer potential energy surfaces which are essential for studying spectroscopy and dynamics. A potential energy surface is a mathematical function that represents the energy of a system as a function of its molecular geometry. The Born-Oppenheimer approximation enables us to solve the Schrödinger equation by separating the nuclear and electronic motions. Construction of potential energy surfaces has become a basic and crucial operation for chemists in order to compute various electronic states of molecules for understanding the spectroscopy, kinetics and dynamics of molecules. These methods have been used to successfully (i) …

Boundary Control Of Parabolic Pde Using Adaptive Dynamic Programming, Behzad Talaei

Doctoral Dissertations

"In this dissertation, novel adaptive/approximate dynamic programming (ADP) based state and output feedback control methods are presented for distributed parameter systems (DPS) which are expressed as uncertain parabolic partial differential equations (PDEs) in one and two dimensional domains. In the first step, the output feedback control design using an early lumping method is introduced after model reduction. Subsequently controllers were developed in four stages; Unlike current approaches in the literature, state and output feedback approaches were designed without utilizing model reduction for uncertain linear, coupled nonlinear and two-dimensional parabolic PDEs, respectively. In all of these techniques, the infinite horizon cost …

Models Of Leader Elections And Their Applications, Stephen Curtis Jackson

Doctoral Dissertations

"New research about cyber-physical systems is rapidly changing the way we think about critical infrastructures such as the power grid. Changing requirements for the generation, storage, and availability of power are all driving the development of the smart-grid. Many smart-grid projects disperse power generation across a wide area and control devices with a distributed system. However, in a distributed system, the state of processes is hard to determine due to isolation of memory. By using information flow security models, we reason about a process's beliefs of the system state in a distributed system. Information flow analysis aided in the creation …

Pointwise And Uniform Convergence Of Fourier Series On Su(2), Donald Forrest Myers

Doctoral Dissertations

"Let f be a Lipschitz function on the special unitary group SU (2). We prove that the Fourier partial sums of f converge to f uniformly on SU (2), thereby extending theorems of Caccioppoli, Mayer, and a special case of Ragozin. Pointwise convergence theorems for the Fourier series of functions on SU (2), due to Liu and Qian, were obtained by Clifford algebra techniques. We obtain similar versions of these theorems using simpler proof techniques: classical harmonic analysis and group theory"--Abstract, page iii.

Algorithms Leveraging Smartphone Sensing For Analyzing Explosion Events, Srinivas Chakravarthi Thandu

Doctoral Dissertations

"The increasing frequency of explosive disasters throughout the world in recent years have created a clear need for the systems to monitor for them continuously to improve the post-disaster emergency events such as rescue and recovery operations. Disasters both man-made and natural are unfortunate and not preferred, however monitoring them may be a lifesaving phenomenon in emergency scenarios. Dedicated sensors deployed in the public places and their associated networks to monitor such events may be inadequate and must be complemented for making the monitoring more pervasive and effective. In the recent past, modern smartphones with significant processing, networking and storage …

Dft Investigations Of Hydrogen Storage Materials, Gang Wang

Doctoral Dissertations

"Hydrogen serves as a promising new energy source having no pollution and abundant on earth. However the most difficult problem of applying hydrogen is to store it effectively and safely, which is smartly resolved by attempting to keep hydrogen in some metal hydrides to reach a high hydrogen density in a safe way. There are several promising metal hydrides, the thermodynamic and chemical properties of which are to be investigated in this dissertation.

Sodium alanate (NaAlH₄) is one of the promising metal hydrides with high hydrogen storage capacity around 7.4 wt. % and relatively low decomposition temperature of …

Unconventional Phase Transitions In Random Systems, Hatem Nuri Barghathi

Doctoral Dissertations

"In this thesis we study the effects of different types of disorder and quasiperiodic modulations on quantum, classical and nonequilibrium phase transitions. After a brief introduction, we examine the effect of topological disorder on phase transitions and explain a host of violations of the Harris and Imry-Ma criteria that predict the fate of disordered phase transitions. We identify a class of random and quasiperiodic lattices in which a topological constraint introduces strong anticorrelations leading to modifications of the Harris and Imry-Ma criteria for such lattices. We investigate whether or not the Imry-Ma criterion, that predicts that random field disorder destroys …