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Missouri University of Science and Technology
Chemical and Biochemical Engineering Faculty Research & Creative Works
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- Advanced Measurement Techniques (1)
- Carbon nanotube composites (1)
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- Dopamine oxidation (1)
- Dopamine sensor (1)
- Engineering Research (1)
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- Fluidized Beds (1)
- Gamma Ray Computed Tomographies (1)
- Gamma Ray Densitometry (1)
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- Metal chalcogenide nanostructures (1)
- Non-Invasive Measurement Technique (1)
- Nonenzymatic biosensor (1)
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Articles 1 - 14 of 14
Full-Text Articles in Physical Sciences and Mathematics
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon nanotube-encapsulated nickel selenide composite nanostructures were used as nonenzymatic electrochemical sensors for dopamine detection. These composite nanostructures were synthesized through a simple, one-step, and environmentally friendly chemical vapor deposition method, wherein the CNTs were formed in situ from pyrolysis of a carbon-rich metallo-organic precursor. The composition and morphology of these hybrid NiSe2-filled carbon nanostructures were confirmed by powder X-ray diffraction, Raman, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy images. Electrochemical tests demonstrated that the as-synthesized hybrid nanostructures exhibited outstanding electrocatalytic performance toward dopamine oxidation, with a high sensitivity of 19.62 μA μM-1 cm-2, low detection limit, broad linear …
Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn Morrison
Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn Morrison
Chemical and Biochemical Engineering Faculty Research & Creative Works
Coating compositions and methods for using the same are disclosed. The coating compositions can include an aminosilica adsorbent. The coating compositions can adsorb CO2.
System And Process For Upgrading Hydrocarbons, Dennis N. Bingham, Kerry M. Klingler, Joseph D. Smith, Terry D. Turner, Bruce M. Wilding
System And Process For Upgrading Hydrocarbons, Dennis N. Bingham, Kerry M. Klingler, Joseph D. Smith, Terry D. Turner, Bruce M. Wilding
Chemical and Biochemical Engineering Faculty Research & Creative Works
In one embodiment, a system for upgrading a hydrocarbon material may include a black wax upgrade subsystem and a molten salt gasification (MSG) subsystem. The black wax upgrade subsystem and the MSG subsystem may be located within a common pressure boundary, such as within a pressure vessel. Gaseous materials produced by the MSG subsystem may be used in the process carried out within the black wax upgrade subsystem. For example, hydrogen may pass through a gaseous transfer interface to interact with black wax feed material to hydrogenate such material during a cracking process. In one embodiment, the gaseous transfer interface …
Scale-Up And On-Line Monitoring Of Gas-Solid Systems Using Advanced And Non-Invasive Measurement Techniques, Muthanna H. Al-Dahhan, Shreekanta Aradhya, Faraj Zaid, Neven Ali, Thaar Aljuwaya
Scale-Up And On-Line Monitoring Of Gas-Solid Systems Using Advanced And Non-Invasive Measurement Techniques, Muthanna H. Al-Dahhan, Shreekanta Aradhya, Faraj Zaid, Neven Ali, Thaar Aljuwaya
Chemical and Biochemical Engineering Faculty Research & Creative Works
Industry relies on gas-solid systems for numerous processes. Flow dynamics play an important role in achieving the desired results. The present study proposes, validates and demonstrates a novel mechanistic scale-up approach based on maintaining similar radial profile or cross sectional distribution of gas holdup in two different gas-solid systems in order to achieve hydrodynamics similarity using advanced measurement techniques. This new methodology for scale-up and design has been implemented on gas-solid spouted bed which has been used for drying, granulation and coating. The development can be extrapolated to other gas-solid systems encountered in phosphate processes.
Final State Distributions For Electron Capture From Orientated Rydberg Atoms, Jee-Ching Wang, Ronald E. Olson
Final State Distributions For Electron Capture From Orientated Rydberg Atoms, Jee-Ching Wang, Ronald E. Olson
Chemical and Biochemical Engineering Faculty Research & Creative Works
Final state nim distributions are studied for electron capture from orientated circular Rydberg atoms. Strong orientation effects are found for all quantum numbers at collision speeds comparable to the electron orbital speed. Predominant population of large m states is observed when the plane of the circular orbit is nearly perpendicular to the incident direction of the projectile. The Ini distributions show structures due to quasi-Thomas scattering even at low relative collision velocities. © 1993 IOP Publishing Ltd.
Ionic Charge Dependence Of The Zero Degree Binary Encounter Peak For Partially Stripped Heavy Ions, W. Wolff, H. E. Wolff, J. L. Shinpaugh, Jee-Ching Wang, Ronald E. Olson, D. Fainstein, S. Lencinas, U. Bechthold, R. Herrmann, H. Schmidt-Bocking
Ionic Charge Dependence Of The Zero Degree Binary Encounter Peak For Partially Stripped Heavy Ions, W. Wolff, H. E. Wolff, J. L. Shinpaugh, Jee-Ching Wang, Ronald E. Olson, D. Fainstein, S. Lencinas, U. Bechthold, R. Herrmann, H. Schmidt-Bocking
Chemical and Biochemical Engineering Faculty Research & Creative Works
We report on the measurements of double differential cross sections, at zero degree, for the production of secondary electrons from the collision of 0, 6 MeV amu-1 Cu5+, I7+, Au11+, U13+, Cu19+, t23+ and Au29+ projectiles with H2 and He. The shapes and positions of the observed binary encounter electron peaks are compared with continuum distorted wave-eikonal initial state (CDW-EIS), impulse approximation and classical trajectory Monte Carlo calculations, as well as with predictions from an adiabatic resonant tunnelling model recently proposed by Fainstein and co-workers. The …
Dependence Of Binary Encounter Electron Production On The Charge State Of The Recoil Ion, Jee-Ching Wang, Ronald E. Olson, H. Wolf, J. Shinpaugh, W. Wolff, H. Schmidt Böcking
Dependence Of Binary Encounter Electron Production On The Charge State Of The Recoil Ion, Jee-Ching Wang, Ronald E. Olson, H. Wolf, J. Shinpaugh, W. Wolff, H. Schmidt Böcking
Chemical and Biochemical Engineering Faculty Research & Creative Works
We study the dependence of the production of binary encounter electrons on the charge state of recoil ions for 2.4 MeV u-l Xe21+ on He and Ar. Doubly differential cross sections of electron emission are calculated with the ncrMC method. We find that the contributions to the binary electron cross section from various recoil ion charge states reach a maximum near Ar5+ for the Ar target. In the case of the He target; double ionization dominates over single ionization for alt ejected electron energies above 100 eV. However, an unexpected local drop of double ionization in the …
Plasma Polymerization Of Tetrafluoroethylene. Iii. Capacitive Audio Frequency (10 Khz) And Ac Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Plasma Polymerization Of Tetrafluoroethylene. Iii. Capacitive Audio Frequency (10 Khz) And Ac Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Chemical and Biochemical Engineering Faculty Research & Creative Works
The plasma polymerization of tetrafluoroethylene (TFE) is studied in a capacitively coupled system with internal electrodes using a 10 kHz (af) and a 60 Hz (ac) source. The emphasis is on identifying conditions that are compatible with continuous coating of plasma polymer on a substrate moving through the center of the interelectrode gap. Operation at a pressure below 100 mTorr is most favorable for deposition of a substantial portion of the plasma polymer on this substrate. Plasma polymer deposited in this way is characterized by ESCA and by deposition rate data and compared to that deposited using rf power in …
Plasma Polymerization Of Tetrafluoroethylene. Ii. Capacitive Radio Frequency Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Plasma Polymerization Of Tetrafluoroethylene. Ii. Capacitive Radio Frequency Discharge, N. (Nicholas) C. Morosoff, H. Yasuda, E. S. Brandt, C. N. Reilley
Chemical and Biochemical Engineering Faculty Research & Creative Works
The plasma polymerization of tetrafluoroethylene (TFE) is studied in a capacitively coupled system with internal electrodes using radio frequency (13.56 MHz) power. The emphasis is on identifying conditions that are compatible with continuous coating of plasma polymer on a substrate moving through the center of the interelectrode gap. At high pressure (500 mTorr), deposition of plasma polymer is primarily on the electrodes rather than on a substrate placed midway between electrodes. Glow is observed in only part of the interelectrode gap at low powers and fills the gap only at high power levels. The use of a magnetic field effects …
The Mechanism Of The Electrooxidation Of Acetylene On Gold, James W. Johnson, J. L. Reed, William Joseph James
The Mechanism Of The Electrooxidation Of Acetylene On Gold, James W. Johnson, J. L. Reed, William Joseph James
Chemical and Biochemical Engineering Faculty Research & Creative Works
Acetylene has been oxidized anodically in aqueous solutions at 80 °C on gold electrodes. It was found that the partial oxidation to CO2 was accompanied by a polymer formation. Effects of potential, acetylene partial pressure, pH, and temperature on the rate (current) were measured. A discontinuity in the Tafel curves was noted that indicated a change in the reaction mechanism with potential. The discontinuity was also pH dependent. A mechanism involving the discharge of H2O and/or OH− has been proposed that is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.
The Anodic Dissolution Of Cadmium, James W. Johnson, E. Deng, S. C. Lai, William Joseph James
The Anodic Dissolution Of Cadmium, James W. Johnson, E. Deng, S. C. Lai, William Joseph James
Chemical and Biochemical Engineering Faculty Research & Creative Works
The anodic dissolution of cadmium has been studied in aqueous solutions containing Cl−, Br−, I−, Ac−, SO4=, and NO3− ions. The normal valence (+2) was found in all solutions with the exception of NO3−. The apparent valence (calculated) of cadmium ions in nitrate solutions varied from 1.2 to 2.0 and was found to be a function of NO3− concentration, current density, and temperature. An anodic dissolution mechanism has been proposed involving local corrosion and disintegration of the anode which is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.
The Effect Of Concentration On The Viscosities Of Solutions Of Linear Flexible High Polymers, Lung Yu Chou, Jacques L. Zakin
The Effect Of Concentration On The Viscosities Of Solutions Of Linear Flexible High Polymers, Lung Yu Chou, Jacques L. Zakin
Chemical and Biochemical Engineering Faculty Research & Creative Works
Viscosity-concentration results in the moderately concentrated range for four samples of polyisobutylene (molecular weights of 1.3 x 104 to 1.0 x 106) in cyclohexane (concentrations up to 4.7 g./dl.) and in benzene (concentrations up to 7.0 g./dl.) at 24°C. (a theta solvent) showed molecular weight and goodness of solvent dependencies similar to those reported earlier for three other polymers. For polyisobutylene, polystyrene, and a copolymer of styrene and methyl methaerylate in good solvents, viscosity-concentration data plotted as ηsp. C[η] vs. k′[η]C fit a single curve. The linear region of this curve suggests that the Huggins equation is useful to C[η] …
Handlos And Baron Model: Short Contact Times, J. Patel, Robert M. Wellek
Handlos And Baron Model: Short Contact Times, J. Patel, Robert M. Wellek
Chemical and Biochemical Engineering Faculty Research & Creative Works
No abstract provided.
Radial Pressure Gradient In Turbulent Pipe Flow, Gary Kent Patterson, Walter J. Ewbank, Virgil A. Sandborn
Radial Pressure Gradient In Turbulent Pipe Flow, Gary Kent Patterson, Walter J. Ewbank, Virgil A. Sandborn
Chemical and Biochemical Engineering Faculty Research & Creative Works
Measurements made with a Prandtl static pressure probe have demonstrated that a radial pressure gradient does exist in turbulent pipe flow with approximately the magnitude predicted by Sandborn from hot-wire anemometry measurements.