Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 5 of 5
Full-Text Articles in Physical Sciences and Mathematics
Slow Magnetic Relaxation And Electron Delocalization In An S = 9/2 Iron(Ii/Iii) Complex With Two Crystallographically Inequivalent Iron Sites, Susanta Hazra, Sujit Sasmal, Michel Fleck, Fernande Grandjean, Moulay T. Sougrati, Meenakshi Ghosh, T. David Harris, Pierre Bonville, Gary J. Long, Sasankasekhar Mohanta
Slow Magnetic Relaxation And Electron Delocalization In An S = 9/2 Iron(Ii/Iii) Complex With Two Crystallographically Inequivalent Iron Sites, Susanta Hazra, Sujit Sasmal, Michel Fleck, Fernande Grandjean, Moulay T. Sougrati, Meenakshi Ghosh, T. David Harris, Pierre Bonville, Gary J. Long, Sasankasekhar Mohanta
Chemistry Faculty Research & Creative Works
The magnetic, electronic, and Mössbauer spectral properties of Fe 2L(µ-OAc)2ClO4, 1, where L is the dianion of the tetraimino-diphenolate macrocyclic ligand, H2L, indicate that 1 is a class III mixed valence iron(II/III) complex with an electron that is fully delocalized between two crystallographically inequivalent iron sites to yield a [Fe2]V cationic configuration with a St 9/2 ground state. Fits of the dc magnetic susceptibility between 2 and 300K and of the isofield variable-temperature magnetization of 1 yield an isotropic magnetic exchange parameter, J, of -32(2) cm-1 for an …
Magnetic Properties Of (Γ-Fe₂O₃)₈₀Ag₂₀ Nanocomposites Prepared In Reverse Micelles, Joan A. Wiemann, Jianbiao Dai, Jinke Tang, Gary J. Long, Leonard Spinu
Magnetic Properties Of (Γ-Fe₂O₃)₈₀Ag₂₀ Nanocomposites Prepared In Reverse Micelles, Joan A. Wiemann, Jianbiao Dai, Jinke Tang, Gary J. Long, Leonard Spinu
Chemistry Faculty Research & Creative Works
The magnetic properties of nanoparticles of gamma-Fe2O3 prepared by reverse micelles have been studied by dc magnetization, transverse ac susceptibility, and Mössbauer spectroscopy. The nanoparticles of gamma-Fe2O3 in the nanocomposite (gamma-Fe2O3)80Ag20 exhibit superparamagnetic behavior. The blocking temperatures determined by the three methods indicate the superparamagnetic nature of (gamma-Fe2O3)80Ag20 above 70-80 K and show correlation with measuring time. The average particle diameter obtained by transmission electron microscopy of the gamma-Fe2O3 particles is ~10 nm and that of the Ag particles is ~20 nm. The average particle size determined from the magnetic analyses for the gamma-Fe2O3 particles is ~12 nm. Mössbauer spectra …
A Magnetic And Mössbauer Spectral Study Of The Spin Reorientation In Ndfe₁₁Ti And Ndfe₁₁Th, Cristina Piquer, Fernande Grandjean, Olivier Isnard, Viorel Pop, Gary J. Long
A Magnetic And Mössbauer Spectral Study Of The Spin Reorientation In Ndfe₁₁Ti And Ndfe₁₁Th, Cristina Piquer, Fernande Grandjean, Olivier Isnard, Viorel Pop, Gary J. Long
Chemistry Faculty Research & Creative Works
The influence of hydrogenation on the spin reorientation in the presence of neodymium was investigated in NdFe11Ti and NdFe11TH. The magnetic properties of these compounds were determined by utilizing ac magnetic susceptibility, thermomagnetic, and iron-57 Mössbauer spectral analysis. It was found that the these compounds had two advantages as hard magnetic materials such as: a high iron content yielding high magnetization and a high Curie temperature. The investigation results show that these compounds undergo a spin-reorientation transition at ~185 K and at 100± K, from an axial magnetic phase at high temperature to a basal magnetic …
Study Of The Electronic Properties Of Some Ytterbium Filled Skutterudites By Magnetic Susceptibility And X-Ray Absorption And Tin-119 Mössbauer Spectroscopy, Fernande Grandjean, Gary J. Long, Bernard M. Mahieu, Ji Hui Yang, Gregory P. Meisner, Donald T. Morelli
Study Of The Electronic Properties Of Some Ytterbium Filled Skutterudites By Magnetic Susceptibility And X-Ray Absorption And Tin-119 Mössbauer Spectroscopy, Fernande Grandjean, Gary J. Long, Bernard M. Mahieu, Ji Hui Yang, Gregory P. Meisner, Donald T. Morelli
Chemistry Faculty Research & Creative Works
Magnetic susceptibility, ytterbium LIII-edge x-ray absorption and tin-119 Mössbauer spectral measurements have been carried out to probe the electronic structure of ytterbium and tin in the filled or partially filled skutterudite compounds, YbyCo4Sb12-xSnx, over a range of x and y values. The ytterbium valence obtained from the magnetic susceptibility and ytterbium LIII-edge x-ray absorption measurements is in excellent agreement and clearly reveals an evolution from intermediate valence ytterbium for x=0 to nearly divalent ytterbium for x=0.8. This evolution parallels an increase in the unit cell volume and hence …
Magnetic And Mössbauer Spectral Study Of Erfe₁₁Ti And Erfe₁₁Tih, Cristina Piquer, Raphäel P. Hermann, Fernande Grandjean, Gary J. Long, Olivier Isnard
Magnetic And Mössbauer Spectral Study Of Erfe₁₁Ti And Erfe₁₁Tih, Cristina Piquer, Raphäel P. Hermann, Fernande Grandjean, Gary J. Long, Olivier Isnard
Chemistry Faculty Research & Creative Works
The influence of the insertion of hydrogen into the crystal lattice of ErFe11Ti upon its spin reorientation was investigated. It was found that the insertion of hydrogen into ErFe11Ti to form ErFe11TiH expanded the lattice by 1% and increased the Curie temperature by 56 K. The presence of one titanium near neighbor in the environment of an iron site decreased the hyperfine field by ~2T and changed the isomer shift by ~0.05 mm/s.