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Louisiana State University

Stable isotopes

Geochemistry

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Full-Text Articles in Physical Sciences and Mathematics

Snapshots Of Coastal Ecology During Glacial And Deglacial Intervals: A Multiproxy Assessment Of Northern Gulf Of Mexico Sediment Cores, Kendall Emilie Brome Nov 2022

Snapshots Of Coastal Ecology During Glacial And Deglacial Intervals: A Multiproxy Assessment Of Northern Gulf Of Mexico Sediment Cores, Kendall Emilie Brome

LSU Master's Theses

Terrestrial ecosystems along exposed continental shelves during times of relatively low sea level and glaciation are rarely preserved due to the mechanically erosive nature of marine transgression and regression. In this study, I investigate the geochemical and palynological characteristics of two well-preserved sites in the northern Gulf of Mexico (NGOM) to determine the ecologic settings and subsequent mechanisms of preservation in this region. Both sites contain preserved terrigenous sediments of previously exposed coastal margins; the first is located at the Alabama Underwater Forest (~13 km south of Gulf Shores, AL, at ~15 mbsl), and optically stimulated luminescence dates to 72–56 …


Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato Sep 2021

Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato

LSU Master's Theses

The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (2H) and oxygen (18O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …


High-Dimensional Isotope Relationships, Yuyang He Aug 2018

High-Dimensional Isotope Relationships, Yuyang He

LSU Doctoral Dissertations

High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'18 …


When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare Nov 2017

When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare

LSU Doctoral Dissertations

The Antarctic Ice Sheets (AIS) began to retreat from their Last Glacial Maximum (LGM) position sometime after 19,000 years ago. However, the corrosive waters circulating around Antarctica has prevented the recovery of radiocarbon-dateable material, hindering the development of deglacial chronologies. During Expedition NBP1502B to the eastern Ross Sea, an unprecedented quantity of fossil foraminifera and bivalves were recovered. Radiocarbon-dated specimens have been used to constrain the timing of West-AIS retreat from Whales Deep basin and Ross Bank. Whales Deep samples show that the WAIS retreated from its LGM position on the continental shelf edge by 14,700 ± 400 calibrated radiocarbon …