Physical Sciences and Mathematics Commons^™

Computer Investigation Of The Variation Of Conductivity With Concentration, Larry Macpeers Shadwick

Masters Theses

Computer programs were developed tor the conductance equations of R. M. Fuoss and L. Onsager as well as for the conductance equations of T. J. Murphy and E. G. D. Cohen. These programs were used to calculate values from selected conductance measurements. The resulting values were compared with values produced by other computer programs using the equations of Fuoss and Onsager as well as the equations of E. Pitts. The comparisons demonstrated the equations of Murphy and Cohen to be the equal of or superior to the other equations for the majority of cases. The equations of Pitta were superior …

The Isolation And Purification Of A Fluorescent Compound From Pseudomonas, Thomas M. Davey

Masters Theses

Fluorescence in certain land snails has been found to arise from a bacteria carried by the snails. The bacteria, a genus of Pseudomonas, produce a pigment complex in iron-deficient media. The pigment complex consists of both fluorescent and non-fluorescent pigments. One of the fluorescent compounds was isolated and purified by paper chromatography using several different solvent systems.

Absorption and fluorescent spectra of the compound at a number of pH values were measured and the changes with pH of both the intensity and the color of the fluorescence were observed. The purified compound was ninhydrin negative but after acid hydrolysis …

Numerical Study Of Slow Motion Of A Smoke Filament, Tapan Sen

Masters Theses

No abstract provided.

The Consideration Of Some Aspects Of Two Methods Used To Study Ion Association, Richard Karl Gard

Masters Theses

An investigation was made into the possibility of determining thermodynamic ion association equilibrium constants for salts important in the study of seawater using spectrophotometry and ion selective electrodes. Calcium sulfate was used as the test salt. The success of the spectrophotometric method was found to depend upon the choice of a suitable indicator and refinement of the proper instrumental techniques. The indicators investigated were 1-(2'-hydroxy-1'-benzeneazo)-2-hydroxynaphthalene, 1-(2'-hydroxy-5'-chloro-1'-benzeneazo)-2-hydroxynaphthalene, and ammonium purpurate (murexide). Ammonium purpurate was found to be the most suitable indicator. Spectra of these three indicators and their calcium complexes at pH 10 are included in the paper. The ion selective …

Mechanistic Studies Of Cobalt Super Nucleophiles, Audrey Yeh Ku

Masters Theses

A study was initiated on the hypothesis, by Ugi and co-workers, that cyclopropyl, cyclobutyl, and cyclopentyl electrophiles might undergo nucleophilic substitution reactions with retention of configuration.

A simple, high yield synthesis of both cis and trans-2-phenylcyclopropyl chlorides from styrene and chloroform is described. Reaction of each of these alkylating agents with the very nucleophilic cobaloxime super-nucleophile ultimately gave peroxy compounds which appear to arise from insertion of oxygen into the carbon-cobalt bond.

Neither trans-2-phenylcyclopentyl tosylate nor trans-2-phenylcyclohexyl tosylate would alkylate low valent cobaloximes under standard conditions.

A partial synthesis of the 2-phenylcyclobutyl tosylate is described along with suggestions for future …

The Conductance Of Some Polyvalent Electrolytes, Jack Lee Worthington

Masters Theses

A new compound, 1,3,5-triphenylbenzene-4' ,4",4"'-trisulfonic acid, was synthesized by treating triphenylbenzene in 1,2-dichloroethane with chlorosulfonic acid. The reaction appears to be quantitative. Conductance measurements were then made on the sodium, potassium, and lanthanum salts of this new acid and of 1,3,5-benzenetrisulfonic acid.

The choice of these acids was based on two factors: 1) the desire to prepare a 3-3 symmetrical unassociated electrolyte which would allow the determination of a more reliable equivalent ionic conductance value for La³⁺ and 2) an interest in using the Murphy-Cohen equation to determine solute parameters such as association constants if association is present.

Conductance …

A Study Of Organochlorine Insecticides In Freshwater Crayfish -- Analytical Problems And Biomonitoring Survey, Robert C. Vanderjack

Masters Theses

Crayfish were collected from 3 sites on Polecat Creek, Coles County, Illinois in early spring, early summer, and late summer of 1972. Pesticides were extracted from the crayfish tissue in a one step procedure utilizing a Florisil elution column. Analysis was by electron capture gas chromatography. Pesticide residues in the nannogram range were analyzed and background contamination was an important consideration. Sources of background contamination were investigated and teflon stopcocks, Florisil, and residues on “cleaned” glassware were found to be major contamination sources. Distilled water used in flushing glassware should also be considered a potential contamination source.

Aldrin, dieldrin, and …

The Fauna And Paleoecology Of The Charleston Quarry Shale, James Karl Gilliam

Masters Theses

The fauna and paleoecology of a late-Pennsylvanian shale contained in the Livingston Limestone of eastern Illinois is here defined. The name, Charleston quarry shale, is informally used for this shale in the area of the Charleston Stone Company quarry, northeast of Charleston, Illinois (SEC. 32, T. 13N., R. 10E., Coles Co.).

The fauna consists mostly of bryozoans, brachiopods and crinoids distributed throughout three distinct zones in the Charleston quarry shale. This fauna inhabited an offshore quiet bottom area in a shallow, warm, marine epicontinental sea which covered the area in the late-Pennsylvanian geologic period. The depth of water above the …