Physical Sciences and Mathematics Commons^™

The Impact Of Dutch Disease: The Case Of Nigeria, Halimat Atinuke Laguda

Masters Theses

Nigeria, over the years, has been showing a rapid appreciation of the domestic currency, a rise in real wages and the service sector and a slow-down in the industrial production which are all signs of presence of Dutch disease which predicts that a country with large natural resource rents may experience a de-industrialization and a lower long term economic growth. This paper analyses the impact of Dutch disease in Nigeria Ordinary Least square method, Two-Stage Least Square and Autoregressive Distributed Lag with a system of equation from 1981 to 2017 and found that the real wage rate emphasizes on the …

Studying Carbon Dioxide Solvent Properties By Microwave Spectroscopic Investigations Of Vinyl Fluoride/Carbon Dioxide Clusters And Developing New Approaches To Decode Rotational Spectra, Prashansa Kannangara

Masters Theses

Supercritical carbon dioxide (sc-C0₂) is an excellent green solvent, but its properties are not thoroughly understood. For example, fluorinated compounds have higher than expected solubility in sc-C0₂. Microwave spectroscopy is one way to learn more about sc-C0₂ because it can be used to determine detailed structures of small clusters of molecules. The purpose of this investigation was to study weak hydrogen bonding interactions in complexes of fluorinated ethylene (solute) with carbon dioxide (C0₂, solvent). Investigations on dimers with one C0₂ molecule and fluorinated ethylene were carried out previously and found two different …

Solvation Properites Of Supercritical Carbon Dioxide Using Chirped-Pulse Fourier-Transform Microwave Spectra Of Carbon Dioxide / 1, 1-Difluoroethene (Dfe) Mixtures, Tulana Ariyaratne Subasinghe Arachchige

Masters Theses

Supercritical carbon dioxide (sc-C0₂) is a highly utilized industrial substance identified as an excellent solvent and a surfactant, which is cheaper and less hazardous than other typical solvents. The higher solubility of fluorinated hydrocarbons than their hydrocarbon (HC) analogs is not well understood and the theory behind the microsolvation of sc-C0₂ cannot be fully explained with the existing chemical information. Microwave spectroscopy is a good method of identifying the structural arrangement of clusters made from fluorinated HCs and C0₂. I n this project, microwave scans of the four different mixtures of 1 , 1-difluoroethene (DFE) …

Impacts Of Plant-Microbe Interactions On Seedling Performance In A Riparian Forest Invaded By Lonicera Maackii, Taylor E. K. Strehl

Masters Theses

Soil microbes have profound impacts on plant growth and survival and can either promote or inhibit plant dominance. Exotic plants are often strongly invasive because they have escaped their natural enemies, potentially including antagonistic soil microbes. I examined how the invasive shrub Lonicera maackii and a common native tree, Acer negundo, responded to soil microbial communities to determine the role of soil microbes in regulating invasion success. This was done by growing both species with microbes from invaded (L. maackii) and uninvaded (A. negundo) soils collected from three locations within a riparian forest. Seedlings were …

Identifying Priority Conservation Areas And Strategies For Myotis Sodalis (Chiroptera: Vespertilionidae) Via Habitat And Connectivity Modeling, Ashleigh B. Cable

Masters Theses

Myotis sodalis, the Indiana bat, is a federally endangered bat species in the United States of America (USA). Conservation efforts are typically focused at identified maternity sites at local scales, however, the species is a regional migrant that interacts with its environment at multiple spatial scales. We are limited in our knowledge of landscape-level requirements of this species, especially in large areas such as Illinois, USA, where a wide range of environmental and landscape conditions exist. Many previous M. sodalis habitat studies have limited their focus to smaller spatial scales. Due to limitations in funding, personnel, and time, it …

Hidden Symmetries In Classical Mechanics And Related Number Theory Dynamical System, Mohsin Md Abdul Karim

Masters Theses

Classical Mechanics consists of three parts: Newtonian, Lagrangian and Hamiltonian Mechanics, where each part is a special extension of the previous part. Each part has explicit symmetries (the explicit Laws of Motion), which, in turn, generate implicit or hidden symmetries (like the Law of Conservation of Energy, etc). In this Master's Thesis, different types of hidden symmetries are considered; they are reflected in the Noether Theorem and the Poincare Recurrence Theorem applied to Lagrangian and Hamiltonian Systems respectively.

The Poincare Recurrence Theorem is also applicable to some number theory problems, which can be considered as dynamical systems. In …

Variation In Leaf Morphology Of An Alpine Shrub Community Along Environmental Gradients, Abdulssalam Khafsha

Masters Theses

Mountains represent complex environment gradients which strongly affect local temperature regimes and rainfall. These changes in climate conditions drive a diversity of plant responses. As alpine environments are expected to change dramatically in response to climate change, understanding plant responses to environmental variation is critical in these environments. Although they are a critical component of alpine communities, the environmental responses of shrubs have been much less examined than trees, representing an important knowledge gap. Leaves, as the primary photosynthetic organs on plants, would be expected to respond strongly to local climate conditions. In this study, I documented how the leaf …

Synthesis, Characterization And Mechanistic Studies Of Biomimetic Dinuclear Copper(Ii) Complexes, Millaniyage Nuwanthaka Prasad Jayaweera

Masters Theses

Dinuclear copper complexes are significant synthetic targets due to their use as model compounds for the active sites of type 3 copper proteins like catechol oxidase. A distinct class of ligands used in these studies are built on a phenol core to witch various donor side-arms were appended at the 2 and 6 positions of the arene ring. In our quest to quantify the influence of electron donating or withdrawing groups attached to the central arene ring, we have designed a set of ligands that, upon coordination to copper(II) centers, would produce complexes of the general structure. During this research …

Developing A Basket-Shaped Host Molecule Based On P-Tert-Butylcalix[4]Arene Featuring Urea Groups For Encapsulating Volatile Guest Molecules, Lokugama Widanelage Vidula Priyadarshana

Masters Theses

Molecular baskets are a group of synthetic host molecules which are designed to govern the inclusion of small guest molecules. The basic structural features of basket-shaped host molecules are a cavity for holding a much smaller guest molecule and tunable gates for keeping the guest molecule inside. These types of gates can be tuned by changing temperature, concentration, pH, etc. In this research group's previous study, a molecular basket of cal ix[ 4]arene with carboxylic acid groups was synthesized by functionalizing calix[4]arene's phenol hydroxyl groups with benzyl bromide building blocks. In the study detailed here, 1 , l '-((5-(bromomethyl)-1,3-phenylene)bis(methylene))bis(3-isopropylurea) was …

Synthesis Toward A Molecular Container Based On P-Tert-Butylcalix[4]Arene With Gate Features, Balasooriya Appuhamilage Dinesh Madushan Balasooriya

Masters Theses

Nowadays molecular and supramolecular chemistry have endless examples for the development of smart devices. Among those applications, nano-baskets of calixarenes play vital roles in host-guest chemistry. One of the main appealing concepts of this field is the development of host molecules with gate features. These hosts are designed and constructed for the delivery of chemical or biochemical species that are volatile, or reactive, or sensitive to normal solution environment and they are mainly functioned by predefined groups that are responsive toward stimuli such as concentration, temperature, pH and so on. In our previous study, we found that benzyl bromides can …

Complex Varieties As Minima, Richard Koss

Masters Theses

We will explore various numeric methods of finding roots of an analytic function over some open set of the complex plane. We will discuss a method of visually observing the roots, a gradient descent method for finding the roots of an analytic function, a gradient descent method for solving systems of analytic functions, and finally a method of descent that uses osculating circles to find roots of an analytic function. Of particular interest to this thesis are roots of complex polynomials. There will be examples, code snippets, and outputs of programs to illustrate all of these methods.