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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Clemson University

2009

Nanoparticles

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Synthesis And Characterization Of Metallic, Core-Shell And Composite Nanoparticles, Amar Kumbhar Dec 2009

Synthesis And Characterization Of Metallic, Core-Shell And Composite Nanoparticles, Amar Kumbhar

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ABSTRACT
Silver nanoparticles exhibit size, shape and the surrounding dielectric medium dependent optical properties (scattering and absorption) in the visible spectral region. These optical properties can be explained in terms of the collective oscillation of the 'free conduction band electrons' or 'surface plasmons' induced by an external electromagnetic field. Dipole and Quadrupole Plasmon resonances have been observed for silver particles less than 100nm in diameter prepared using various synthetic techniques. However higher order resonances have been elusive due to lack of experimental techniques to prepare colloidal solutions of large silver nanoparticles in the size range above 100nm. Controlled hydrogen reduction …


Effect Of Cosb3 Nanoparticles On The Thermoelectric Properties Of Filled And Unfilled Cosb3 Skutterudites, Paola Alboni Aug 2009

Effect Of Cosb3 Nanoparticles On The Thermoelectric Properties Of Filled And Unfilled Cosb3 Skutterudites, Paola Alboni

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This study explores the possibility of somewhat decoupling the electrical and thermal conduction, thereby being able to limit the thermal conduction while minimizing the effect on the electrical conduction. The approach is using a nanoparticle layer with a slight compositional mismatch as compared to the bulk skutterudite. A hydrothermal nanoparticle-plating technique has been employed to grow a layer of CoSb3 nanoparticles on the surface of skutterudite bulk matrix grains. Skutterudites of various forms were fabricated and studied in order to assess the effect of this nano-plated layer as a viable method in the improvement of thermoelectric properties of CoSb …