Physical Sciences and Mathematics Commons^™

Investigation Of The Association Of Exposures To Fire-Related Hazards With Pulmonary Function Of Firefighters, David G. Goldfarb

Dissertations and Theses

Background. Firefighters are habitually exposed to hazardous toxicants which place them at an elevated risk for numerous adverse health outcomes. An example of this is the associations observed in other works between inhalation of combustion byproducts from urban structural fires and both acute and chronic pulmonary dysfunction. To-date, the characterization of firefighters’ exposures to dangerous chemicals in smoke from non-wildfire incidents, both directly through personal monitoring and indirectly from work-related records is scarce. Prior works investigating the association between routine firefighting and pulmonary function have relied on crude metrics such as years of service and numbers of responses to …

A Real-Time 3d Object Detection, Recognition And Presentation System On A Mobile Device For Assistive Navigation, Jin Chen

Dissertations and Theses

This thesis proposes an integrated solution for 3D object detection, recognition, and presentation to increase accessibility for various user groups in indoor areas through a mobile application. The system has three major components: a 3D object detection module, an object tracking and update module, and a voice and AR-enhanced interface. The 3D object detection module consists of pre-trained 2D object detectors and 3D bounding box estimation methods to detect the 3D poses and sizes of the objects in each camera frame. This module can easily adapt to various 2D object detectors (e.g., YOLO, SSD, Mask RCNN) based on the requested …

Analysis Of Blue Fountain Pen Ink By Uv-Vis Spectroscopy, Atr-Ftir Spectroscopy, And Thin Layer Chromatography Enhanced With Rgb Spot Evaluation To Construct A Database For Comparison And Identification., Elliot D. Quinteros

Dissertations and Theses

Pen ink can be a crucial piece of physical evidence in the area of Forensic Science. For example, evidence such as notes, letters, printed documents, checks, currency, ransom notes, and books may contain ink. Analysis of ink is typically done for identification or differentiation purposes. To improve existing methods, it was proposed to create a database with many samples and experimental information. The methods used and evaluated were thin-layer chromatography (TLC) enhanced with RGB spot evaluation, UV-Vis spectroscopy, and ATR-FTIR spectroscopy. All three methods were used to analyze 89 fountain pen ink samples. All three methods were able to discriminate …

Sea Surface Temperatures And Vertical Wind Shear As Precursors To Tropical Cyclone Activity In The Caribbean And An Expanding Main Developing Region, Keneshia Hibbert

Dissertations and Theses

Sea surface temperatures and vertical wind shear are essential to tropical cyclone formation. TCs need warm SSTs and low shear for genesis. Increasing SSTs and VWS changes influence storm development. This work analyzes SST and VWS trends for the Caribbean, surrounding region, and the Atlantic hurricane main developing region from 1982 to 2020. Storm intensity increases significantly during this period. Annual and seasonal trends show regional SSTs in the MDR are warming annually (0.0219°C yr^-1) and per season (0.0280°C yr^-1). Simultaneously, VWS decreases during the late rainfall season at 0.0556m/s yr^-1 in the MDR and …

A Citizen-Science Approach For Urban Flood Risk Analysis Using Data Science And Machine Learning, Candace Agonafir

Dissertations and Theses

Street flooding is problematic in urban areas, where impervious surfaces, such as concrete, brick, and asphalt prevail, impeding the infiltration of water into the ground. During rain events, water ponds and rise to levels that cause considerable economic damage and physical harm. The main goal of this dissertation is to develop novel approaches toward the comprehension of urban flood risk using data science techniques on crowd-sourced data. This is accomplished by developing a series of data-driven models to identify flood factors of significance and localized areas of flood vulnerability in New York City (NYC). First, the infrastructural (catch basin clogs, …

Poly(Β-Gal-Thr): A New Scalable Synthetic Mucin, Manuel A. Lema

Dissertations and Theses

A method for the preparation of glycosylated polypeptides via the nucleophilic ring-opening polymerization of a glycosylated N-carboxyanhydride (NCA) monomer is reported. The synthesis of 2,3,4,6-tetraacetyl-β-galactose-threonine N-carboxyanhydride (β-AcO-Gal-Thr-NCA) monomer in 5 steps with an 8 % overall yield is described, and the single-crystal X-ray structure is provided. The effect of a series of Ni⁰-based organometallic initiators, nucleophilic amine initiators, co-catalysts, and solvents on the polymerization were explored. The kinetics of the three most promising conditions were studied in greater detail. The conditions that provided the highest yield, low polydispersity (Ð), and …

A Temporal Examination Of The Connections Between Convective Available Potential Energy And Convective System Development, Chad A. Small

Dissertations and Theses

In 1983, the World Climate Research Programme launched its first project: the International Satellite Cloud Climatology Project (ISCCP). While the ISCCP has succeeded in many of its cataloging and analytical goals, one of its flagship products, the Convection Tracking (CT) Database does not contain certain environmental parameters that are essential in understanding how, and when, convection is initiated or intensified. The development of mesoscale convection – notably, convective systems (CS) – is also largely dependent on parameters like convective available potential energy (CAPE) which the ISCCP CT Database does not record. By tying information on CAPE to CS, discoveries in …

Evaluation Of Snow And Streamflow In The National Water Model With Analysis Using Machine Learning, Engela Sthapit

Dissertations and Theses

Snow has great influence on land-atmosphere interactions and snowmelt from the mountains is a vital water source for downstream communities dependent on snow fed lakes, rivers and streams. This study explored the snow and streamflow prediction capabilities of process-based numerical prediction and data-driven machine learning models.

The overall goal of this study was to understand the deficiencies in the NOAA’s National Water Model (NWM) to represent snow, subsequently streamflow, and recognize the areas where it could be improved for future model developments. The goal was also to evaluate if the recent advancements in machine learning techniques is useful for predicting …

Data Fusion And Synergy Of Active And Passive Remote Sensing; An Application For Freeze Thaw Detections, Zahra Sharifnezhadazizi

Dissertations and Theses

There has been a recent evolvement in the field of remote sensing after increase of number satellites and sensors data which could be fused to produce new data and products. These efforts are mainly focused on using of simultaneous observations from different platforms with different spatial and temporal resolutions. The research dissertation aims to enhance the synergy use of active and passive microwave observations and examine the results in detection land freeze and thaw (FT) predictions. Freeze thaw cycles particularly in high-latitude regions have a crucial role in many applications such as agriculture, biogeochemical transitions, hydrology and ecosystem studies. The …

Understanding The Relationship Between Urban Areas And The Boundary Layer Using Remote Sensing Methods, Gabriel A. Rios

Dissertations and Theses

The atmospheric boundary layer is crucial to the exchange in energy between the Earth's surface and the atmosphere. Within this layer, the majority of human activities are carried out, which makes understanding the boundary layer especially important for many of our interests. A key component of this energy exchange is found at the surface, was surface properties are the interface through which momentum, heat, moisture, and other fluxes are transferred between media. Not only does the surface act as an interface, but as an actor that influences the exchange efficiency and rates. This concept is the crux of atmospheric boundary …

Nonlinear Light - Matter Interactions Of Ultrafast High Intensity Laser Pulses, Henry Meyer

Dissertations and Theses

This thesis focuses on the key nonlinear optical effects that arise from the interactions of intense ultrafast laser pulses with various states of matter. These interactions involve electronic and molecular states and yield new information on the underlying fundamental processes that govern the molecular world. Modern day lasers offer ultrashort pulses, high intensities, and complex polarizations and wavefronts. These extreme conditions have profound effect on the optical properties and behaviors of electronic and molecular states within a material. The changes in these mechanisms effect generation of nonlinear optics, such supercontinuum (SC), stimulated Raman (SRS), self-focusing and filamentation, conical emission (CE), …

Towards Simulation Of Complex Ocean Flows: Analysis And Algorithm For Computation Of Coupled Partial Differential Equations, Wenbin Dong

Dissertations and Theses

The hybrid CFD models which usually consist of 2 sub-models, develop our capability to simulate many emerging problems with multiphysics and multiscale flows, especially for the coastal ocean flows interacted with local phenomena of interest. For most cases, the sub-models are connected with direct interpolation which is easy and workable. It becomes urgently needed to investigate the inner mechanism of such model integration as this simple method does not work well if the two sub-models are different in governing equations, numerical methods, and computational grids. Also, it can not treat complex flow structures as well as the balance in mass …