Physical Sciences and Mathematics Commons^™

Semiotic Aggregation In Deep Learning, Bogdan Muşat, Răzvan Andonie

All Faculty Scholarship for the College of the Sciences

Convolutional neural networks utilize a hierarchy of neural network layers. The statistical aspects of information concentration in successive layers can bring an insight into the feature abstraction process. We analyze the saliency maps of these layers from the perspective of semiotics, also known as the study of signs and sign-using behavior. In computational semiotics, this aggregation operation (known as superization) is accompanied by a decrease of spatial entropy: signs are aggregated into supersign. Using spatial entropy, we compute the information content of the saliency maps and study the superization processes which take place between successive layers of the network. In …

Herschel Gould Belt Survey Observations Of Dense Cores In The Cepheus Flare Clouds, James Di Francesco, Jared Keown, Cassandra Fallscheer, Philippe André, Bilal Ladjelate, Vera Könyves, Alexander Men'shchikov, Shaun Stephens-Whale, Quang Nguyen-Luong, Peter Martin, Sarah Sadavoy, Stefano Pezzuto, Eleonora Fiorellino, Milena Benedettini, Nicola Schneider, Sylvain Bontemps, Doris Arzoumanian, Pedro Palmeirim, Jason M. Kirk, Derek Ward-Thompson

All Faculty Scholarship for the College of the Sciences

We present Herschel SPIRE and PACS maps of the Cepheus Flare clouds L1157, L1172, L1228, L1241, and L1251, observed by the Herschel Gould Belt Survey of nearby star-forming molecular clouds. Through modified blackbody fits to the SPIRE and PACS data, we determine typical cloud column densities of (0.5–1.0) × 10²¹ cm⁻² and typical cloud temperatures of 14–15 K. Using the getsources identification algorithm, we extract 832 dense cores from the SPIRE and PACS data at 160–500 μm. From placement in a mass versus size diagram, we consider 303 to be candidate prestellar cores, and 178 of these …

Mass And Number Size Distributions Of Rbc In Snow And Firn Samples From Pine Island Glacier, West Antarctica, Luciano Marquetto, Susan Kaspari, Jefferson Cardia Simões

Geological Sciences Faculty Scholarship

An extended‐range Single Particle Soot Photometer (SP2) coupled to a Marin‐5 nebulizer was used to measure the refractory black carbon (rBC) mass and number size distributions in 1,004 samples from a West Antarctica snow/firn core. The SP2 was calibrated using Aquadag and a Centrifugal Particle Mass Analyzer for BC particles ranging from 0.5 to 800 fg. Our results indicate a significant contribution of rare, large particles of mass‐equivalent diameter (D_BC) > 500 nm to the total rBC mass (36%), while small particles (D_BC < 100 nm) are abundant but contribute <8% to total rBC mass. We observed a primary mass median diameter of 162 ± 40 nm, smaller than reported for snow in other regions of the globe but similar to East Antarctica rBC size distributions. In addition, we observed other modes at 673, 1,040, and >1,810 nm (uncontained mode). We compared two sets of samples from different seasons …

Modular Synthesis And Transition Metal-Free Alkynylation/Alkenylation Of Castagnoli–Cushmanderived N,O- And N,S-Heterocyclic Vinyl Chlorides, Timothy K. Beng, Abdikani Omar Farah, Victoria Shearer

All Faculty Scholarship for the College of the Sciences

A modular and functional group-tolerant protocol for the transition metal-free coupling of novel N,O- and N,S-heterocyclic vinyl chlorides with terminal acetylenes and styrenes has been developed, leading to the epimerization-free synthesis of fully carbofunctionalized dihydro-1,4-oxazines/thiazines. Bicyclic morpholines have also been prepared through the interrogation of newly synthesized cross-conjugated dienes in Diels–Alder reactions. The use of environmentally benign reaction media endows the current strategy with a practical advantage.

Hot But Not Dry: Modest Changes In Water Relations For An Epiphytic Bromeliad In A Tropical Dry Deciduous Forest, Saúl Hernández-Robinson, Eric A. Graham, Olivia Hernández-González, Roberth Us-Santamaría, José Luis Simá, Fernando Arellano-Martín, José Luis Andrade

All Faculty Scholarship for the College of the Sciences

Premise of research. Epiphytic bromeliads endure intense seasonal environmental changes in the canopy of dry tropical deciduous forests. The analysis of the physiological responses of these epiphytes to environmental changes can be useful in assessing their plasticity, vulnerability, and adaptations to such extreme habitats.

Methodology. We measured microenvironmental variables and water relations for plants of the epiphytic bromeliad Tillandsia brachycaulos in three microhabitats within the canopy of a dry tropical forest. We measured individual plants for seasonal and spatial differences in light, leaf temperature, osmotic potential, cell wall elasticity, and relative capacitance as indications of their physiological responses …

Toward Near‐Field Tsunami Forecasting Along The Cascadia Subduction Zone Using Rapid Gnss Source Models, Amy L. Williamson, Diego Melgar, Brendan W. Crowell, Diego Argas, Timothy I. Melbourne, Yong Wei, Kevin Kwong

Geological Sciences Faculty Scholarship

Over the past 15 years and through multiple large and devastating earthquakes, tsunami warning systems have grown considerably in their efficacy in providing timely and accurate forecasts to affected communities. However, one part of tsunami warning that still needs improvement is forecasts catered to local, near‐field communities in the time after an earthquake rupture but before coastal inundation. In this study, we test a rapid, Global Navigation Satellite Systems (GNSS)‐driven earthquake characterization model using a large data set of synthetic megathrust ruptures for its near‐field tsunami forecasting potential. We also provide a framework for tsunami forecasting that focuses on the …

The Post-Wildfire Impact Of Burn Severity And Age On Black Carbon Snow Deposition And Implications For Snow Water Resources, Cascade Range, Washington, Ted M. Uecker, Susan D. Kaspari, Keith N. Musselman, S. Mckenzie Skiles

Geological Sciences Faculty Scholarship

Wildfires in the snow zone affect ablation by removing forest canopy, which enhances surface solar irradiance, and depositing light absorbing particles [LAPs, such as black carbon (BC)] on the snowpack, reducing snow albedo. How variations in BC deposition affects post-wildfire snowmelt timing is poorly known and highly relevant to water resources. We present a field-based analysis of BC variability across five sites of varying burn age and burn severity in the Cascade Range, Washington State, United States. Single particle soot photometer (SP2) analyses of BC snow concentrations were used to assess the impact of BC on snow albedo, and radiative …

Plate Boundary Trench Retreat And Dextral Shear Drive Intracontinental Fault-Slip Histories: Neogene Dextral Faulting Across The Gabbs Valley And Gillis Ranges, Central Walker Lane, Nevada, Jeffrey Lee, Andrew K. R. Hoxey, Andrew Calvert, Peter Dubyoski

All Faculty Scholarship for the College of the Sciences

The spatial-temporal evolution of intracontinental faults and the forces that drive their style, orientation, and timing are central to understanding tectonic processes. Intracontinental NW-striking dextral faults in the Gabbs Valley–Gillis Ranges (hereafter referred to as the GVGR), Nevada, define a structural domain known as the eastern Central Walker Lane located east of the western margin of the North American plate. To consider how changes in boundary type along the western margin of the North American plate influenced both the initiation and continued dextral fault slip to the present day in the GVGR, we combine our new detailed geologic mapping, structural …

Contact In The Unitary Fermi Gas Across The Superfluid Phase Transition, S. Jensen, Christopher N. Gilbreth, Y. Alhassid

All Faculty Scholarship for the College of the Sciences

A quantity known as the contact is a fundamental thermodynamic property of quantum many-body systems with short-range interactions. Determination of the temperature dependence of the contact for the unitary Fermi gas of infinite scattering length has been a major challenge, with different calculations yielding qualitatively different results. Here we use finite-temperature auxiliary-field quantum Monte Carlo (AFMC) methods on the lattice within the canonical ensemble to calculate the temperature dependence of the contact for the homogeneous spin-balanced unitary Fermi gas. We extrapolate to the continuum limit for 40, 66, and 114 particles, eliminating systematic errors due to finite-range effects. We observe …

Changing Mantle Sources And The Effects Of Crustal Passage On The Steens Basalt, Se Oregon: Chemical And Isotopic Constraints, Nicole E. Moore, A. L. Grunder, Wendy A. Bohrson, Richard W. Carlson, I. N. Bindeman

Geological Sciences Faculty Scholarship

Continental flood basalts are more prone to compositional modification from passage through thicker and (or) more felsic crust in comparison to their oceanic counterparts. The Steens Basalt in southeast Oregon (~17 Ma) is among the oldest and most mafic members of the Columbia River Basalt Group and provides a record of the early stages of flood basalt volcanism. We evaluate the balance of mantle sources in time during the onset of Columbia River Basalt Group magmatism and assess the effect of crustal passage using stratigraphically controlled Sr, Nd, Pb, Hf, Os, and O isotopic compositions, as well as whole rock …

Transition Metal-Free Domino Acyl Substitution/Michael Addition Of Alkenyl Grignard Reagents To Lactam Esters: Synthesis Of Lactam-Bearing Homoallylic Ketones, Abdikani Omar Farah, Muhannad Rabah, Timothy K. Beng

All Faculty Scholarship for the College of the Sciences

A solvent-controlled protocol for the direct and transition metal-free addition of alkenyl Grignard reagents to vicinally functionalized sp³-rich morpholinones has been developed, leading to the chemo and regioselective synthesis of lactam-bearing homoallylic ketones. The addition of lithium chloride proved to be essential. In cases where a new stereocenter is generated, the doubly branched homoallylic ketones are obtained in unexpectedly high diastereoselectivities. Efforts to extend the methodology to other heterosubstituted lactams revealed some important reactivity and selectivity differences.

Modeling Multi-Targets Sentiment Classification Via Graph Convolutional Networks And Auxiliary Relation, Ao Feng, Zhengjie Gao, Xinyu Song, Ke Ke, Tianhao Xu, Xuelei Zhang

All Faculty Scholarship for the College of the Sciences

Existing solutions do not work well when multi-targets coexist in a sentence. The reason is that the existing solution is usually to separate multiple targets and process them separately. If the original sentence has N target, the original sentence will be repeated for N times, and only one target will be processed each time. To some extent, this approach degenerates the fine-grained sentiment classification task into the sentencelevel sentiment classification task, and the research method of processing the target separately ignores the internal relation and interaction between the targets. Based on the above considerations, we proposes to use Graph Convolutional …

Noise Characteristics Of Operational Real‐Time High‐Rate Gnss Positions In A Large Aperture Network, Diego Melgar, Brendan W. Crowell, Timothy I. Melbourne, Walter Szeliga, Marcelo Santillan, Craig Scivner

Geological Sciences Faculty Scholarship

Large earthquakes are difficult to model in real‐time with traditional inertial seismic measurements. Several algorithms that leverage high‐rate real‐time Global Navigation Satellite Systems (HR‐GNSS) positions have been proposed, and it has been shown that they can supplement the earthquake monitoring effort. However, analyses of the long‐term noise behavior of high‐rate real‐time GNSS positions, which are important to understand how the data can be used operationally by monitoring agencies, have been limited to just a few sites and to short time spans. Here, we show results from an analysis of the noise characteristics of 1 year of positions at 213 GNSS …

Site-Selective, Catalytic, And Diastereoselective Sp3 C–H Hydroxylation And Alkoxylation Of Vicinally Functionalized Lactams, Timothy K. Beng, Victoria Shearer, Rachel Davey, Ivianne Redman

All Faculty Scholarship for the College of the Sciences

The C–H bond functionalization of sp³ carbon centres presents a significant challenge due to the inert nature of hydrocarbons as well as the need to selectively functionalize one of the numerous aliphatic C–H bonds embodied in organic molecules. Here, we describe catalytic, diastereoselective, and site-selective sp³ C–H hydroxylation/alkoxylation protocols featuring dihydroisoquinolones, γ-, and δ-lactams, which bear vicinal stereocenters. The hydroxylation strategy utilizes oxygen, a waste-free oxidant and affords attractive fragments for potential drug discovery. Fe-catalyzed dehydrative coupling of the resulting tertiary alcohols with simple primary alcohols has led to the construction of highly versatile unsymmetrical dialkyl ethers.

Refractory Black Carbon (Rbc) Variability In A 47-Year West Antarctic Snow And Firn Core, Marquetto Luciano, Susan Kaspari, Jefferson Cardia Simões

All Faculty Scholarship for the College of the Sciences

Black carbon (BC) is an important climate-forcing agent that affects snow albedo. In this work, we present a record of refractory black carbon (rBC) variability, measured from a 20m deep snow and firn core drilled in West Antarctica (79°55’34.600” S, 94°21’13.3”W, 2122m above sea level) during the 2014–2015 austral summer. This is the highest elevation rBC record from West Antarctica. The core was analyzed using the Single Particle Soot Photometer (SP2) coupled to a CETAC Marin-5 nebulizer. Results show a well-defined seasonality with geometric mean concentrations of 0.015 μg L^-1 for the wet season (austral summer–fall) and 0.057 μg …

Weighted Random Search For Cnn Hyperparameter Optimization, Rǎzvan Andonie, Adrian-Cǎtǎlin Florea

All Faculty Scholarship for the College of the Sciences

Nearly all model algorithms used in machine learning use two different sets of parameters: the training parameters and the meta-parameters (hyperparameters). While the training parameters are learned during the training phase, the values of the hyperparameters have to be specified before learning starts. For a given dataset, we would like to find the optimal combination of hyperparameter values, in a reasonable amount of time. This is a challenging task because of its computational complexity. In previous work, we introduced the Weighted Random Search (WRS) method, a combination of Random Search (RS) and probabilistic greedy heuristic. In the current paper, we …

A New Early Occurrence Of Cervidae In North America From The Miocene-Pliocene Ellensburg Formation In Washington, Usa, Meaghan M. Emery-Wetherell, Joseph F. Schilter

All Faculty Scholarship for the College of the Sciences

A new fossil cervid from the Craig’s Hill locality of the Miocene-Pliocene Ellensburg Formation in the State of Washington, USA, may be one of the oldest fossil deer yet found in North America, underlying a date of 4.9 Ma ± 0.1 Ma. This mandible fragment with m2, m3, and associated p2 has a size that does not distinguish it from Bretzia pseudalces, Odocoileus hemionus, or Capreolus constantini, and distinguishes it from Eocoileus gentryorum and Odocoileus lucasi only in having a thinner p2. A strong paraconid on the p2, and ectostylids and cingulids on the m2 and m3 link it most …

Twentieth Century Black Carbon And Dust Deposition On South Cascade Glacier, Washington State, Usa, As Reconstructed From A 158‐M‐Long Ice Core, Susan D. Kaspari, Dan Pittenger, T. M. Jenk, U. Morgenstern, M. Schwikowski, N. Buenning, L. Stott

All Faculty Scholarship for the College of the Sciences

Light absorbing particles (LAPs) include black carbon (BC) and mineral dust and are of interest due to their positive radiative forcing and contribution to albedo reductions and snow and glacier melt. This study documents historic BC and dust deposition as well as their effect on albedo on South Cascade Glacier (SCG) in Washington State (USA) through the analysis of a 158‐m (139.5‐m water equivalent [w.e.]) ice core extracted in 1994 and spanning the period 1840–1991. Peak BC deposition occurred between 1940 and 1960, when median BC concentrations were 16 times higher than background, likely dominated by domestic coal and forest …

Geochronology Of The Middle Eocene Purple Bench Locality (Devil’S Graveyard Formation), Trans-Pecos Texas, Usa, Amy L. Atwater, Kelly D. Thomson, E. Christopher Kirk, Meaghan Emery-Wetherell, Logan Wetherell, Daniel F. Stockli

All Faculty Scholarship for the College of the Sciences

Purple Bench is a middle Eocene fossil locality in the Devil’s Graveyard Formation of the Trans-Pecos region of West Texas. In addition to yielding a range of taxa characteristic of the Uintan North American Land Mammal Age, the Purple Bench locality is noteworthy in documenting a number of endemic species that are known only from the site. Despite the Uintan character of the mammalian fauna, the absolute age of Purple Bench is a matter of debate. This uncertainty stems from the wide interval of time encompassed by current radiometric dates bracketing the Purple Bench locality and from conflicting magnetostratigraphic correlations …

Learning In Feedforward Neural Networks Accelerated By Transfer Entropy, Adrian Moldovan, Angel Caţaron, Rǎzvan Andonie

All Faculty Scholarship for the College of the Sciences

Current neural networks architectures are many times harder to train because of the increasing size and complexity of the used datasets. Our objective is to design more efficient training algorithms utilizing causal relationships inferred from neural networks. The transfer entropy (TE) was initially introduced as an information transfer measure used to quantify the statistical coherence between events (time series). Later, it was related to causality, even if they are not the same. There are only few papers reporting applications of causality or TE in neural networks. Our contribution is an information-theoretical method for analyzing information transfer between the nodes of …

Glacial Earthquakes And Precursory Seismicity Associated With Thwaites Glacier Calving, J. Paul Winberry, Audrey D. Huerta, Sridhar Anandakrishnan, Richhard C. Aster, Andrew A. Nyblade, Douglas A. Wiens

All Faculty Scholarship for the College of the Sciences

We observe two (~M_S 3) long‐period (10–30 s) seismic events that originate from the terminus of Thwaites Glacier, Antarctica. Serendipitous acquisition of satellite images confirm that the seismic events were glacial earthquakes generated during the capsizing of icebergs. The glacial earthquakes were preceded by 6 days of discrete high‐frequency seismic events that can be observed at distances exceeding 250 km. The high‐frequency seismicity displays an increasing rate of occurrence, culminating in several hours of sustained tremor coeval with the long‐period events. A series of satellite images collected during this precursory time period show that the high‐frequency events and …