Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

California Polytechnic State University, San Luis Obispo

Polymer Chemistry

Surface Energy

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Adhesion And Durability Of Coatings On Polypropylene Exterior Sidings, Logan Riekio Stark Dec 2011

Adhesion And Durability Of Coatings On Polypropylene Exterior Sidings, Logan Riekio Stark

Master's Theses

Plastics have become a universal material for use in a myriad of commercial and consumer products. One such product, exterior siding, is the focus of this project. Although siding products were originally made from wood, vinyl siding, which offered superior performance, was introduced in the 1950’s. More recently, polypropylene (PP) siding has been introduced; PP provides a stronger product, which allows for deeper patterns and better edge detailing. PP siding, compared to traditional wood siding, doesn’t warp, crack, or degrade as easily with extended exposure to the elements, and is cheaper to maintain. However, even plastic siding must be coated. …


The Preparation Of Functional Surfaces, Philip Thomas Dirlam Jun 2011

The Preparation Of Functional Surfaces, Philip Thomas Dirlam

Master's Theses

Diels-Alder chemistry was utilized to manipulate the surface energy of glass substrates in reversible manner. Glass slides and capillaries were functionalized with hydrophobic dieneophiles resulting in a non-wetting surface. A retro Diels-Alder reaction facilitated by the thermal treatment of the surface’s function to cleave the hydrophobic dieneophile and resulted in the fabrication of a hydrophilic surface. Contact angle (CA) measurements were used as preliminary measurements for monitoring the changes in surface energy exhibited during the initial hydrophobic state (CA - 70±3°), after attachment of the dieneophile creating a hydrophobic state (CA - 101±9°) followed by reestablishment of the hydrophilic state …