Physical Sciences and Mathematics Commons^™

Effect Of Polymer Design And Coating Formulation On The Water Uptake And Sensitivity Of Acrylic Water-Borne Films, William Z. Thompson

Master's Theses

Water-borne latex coatings represent a safer, more user-friendly, and environmentally responsible alternative to solvent-borne coatings, and are growing in popularity each year. However, these coatings often exhibit unfavorable performance when exposed to water for extended periods of time. This prolonged exposure often results in water uptake, which may give rise to other detrimental effects such as a decrease in modulus, blushing or water-whitening, reduced serviceable life, and softening of the film. In this study, various polymer composition latex design spaces are studied to develop an understanding of how water uptake can be modulated and minimized using common synthetic approaches. Factors …

Development And Implementation Of Dispersion Phase Diagrams (Dpds) For Four Different Hydrophobically Modified Ethoxylated Urethane (Heur) Based Acrylic Paint Systems, Tyler J. Bell

Master's Theses

Latex polymers serve as binders in a wide range of architectural paints and coatings. A latex is an aqueous colloidal dispersion of polymer particles that when dried above the polymer’s film formation temperature coalesces into a dry polymer film (Dragnevski, Routh, Murray, & Donald, 2010). The other main components of paint include associative thickeners, surfactants, pigments and fillers with the thickener being the primary area of focus for this study.

The relatively simple system of latex, associative thickener and surfactant has been studied extensively. These studies have shown the mechanism of thickening for the associative thickener, and surfactant effects on …