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Full-Text Articles in Physical Sciences and Mathematics
Immobilization Of Copper Nanoparticles Onto Various Supports Applications In Catalysis, Anh Hoang Tu Nguyen Sorenson
Immobilization Of Copper Nanoparticles Onto Various Supports Applications In Catalysis, Anh Hoang Tu Nguyen Sorenson
Theses and Dissertations
Copper-based materials are one of the most promising catalysts for performing transformations of important organic compounds in both academic and industrial operations. However, it is challenging to consistently synthesize highly active and stable copper species as heterogeneous catalysts due to their relatively high surface energy. As a result, agglomeration usually occurs, which limits the catalytic activities of the copper species. The work presented in this dissertation shows different synthetic strategies for obtaining active and stable copper-based materials by modifying chemical/physical properties of copper nanoparticles (NPs). Emphasis is placed on discussing specific catalytic systems, including carbon-supported catalysts (monometallic and bimetallic copper-based …
Metallization Of Dna And Dna Origami Using A Pd Seeding Method, Yanli Geng
Metallization Of Dna And Dna Origami Using A Pd Seeding Method, Yanli Geng
Theses and Dissertations
In this dissertation, I developed a Pd seeding method in association with electroless plating, to successfully metallize both lambda DNA and DNA origami templates on different surfaces. On mica surfaces, this method offered a fast, simple process, and the ability to obtain a relatively high yield of metallized DNA nanostructures. When using lambda DNA as the templates, I studied the effect of Pd(II) activation time on the seed height and density, and an optimal activation time between 10 and 30 min was obtained. Based on the Pd seeds formed on DNA, as well as a Pd electroless plating solution, continuous …
Extreme Ultraviolet Polarimetry With Laser-Generated High-Order Harmonics: Characterization Of Uranium, Nicole Brimhall
Extreme Ultraviolet Polarimetry With Laser-Generated High-Order Harmonics: Characterization Of Uranium, Nicole Brimhall
Theses and Dissertations
We developed an extreme ultraviolet (EUV) polarimeter, which employs laser-generated high-order harmonics as the light source. This relatively high-flux, directional EUV source has available wavelengths between 10 nm and 47 nm with easily rotatable linear polarization. The polarimeter has allowed us to characterize the optical constants of materials that may be useful for EUV optics. The instrument has a versatile positioning system and a spectral resolution of about 180, and we have demonstrated that reflectance as low as 0.1% can be measured repeatably at EUV wavelengths. We investigate the high harmonic source used for polarimetry measurements by documenting the spatial …
Biological Oxidation Of Copper Sulfide Minerals, Delmar Boyd Davis
Biological Oxidation Of Copper Sulfide Minerals, Delmar Boyd Davis
Theses and Dissertations
This work represents a study of the biological oxidation of copper sulfide minerals. The principal objective of the study was to determine the extent of bacterial oxidation on copper containing sulfide minerals. It was also desired to determine if the bacteria could oxidize copper sulfides in the absence of iron. A better understanding of the nitrogen requirements of the organisms was desired. Minerals used in this study were Bingham Canyon Float Concentrate, chalcopyrite, covellite, calcocite, bornite, tetrahedrite, and reagent grade copper sulfide. The bacteria used were obtained from the mine waters of Bingham Canyon, Utah. To study the problem the …