Physical Sciences and Mathematics Commons^™

Evaporated Aluminum Fluoride As A Barrier Layer To Retard Oxidation Of Aluminum Mirrors, Margaret Miles

Theses and Dissertations

The aluminum oxide growth rate for aluminum protected with 2.4 nm of aluminum fluoride has been determined. We show that a 2.4 nm aluminum fluoride layer does not prevent aluminum from oxidation but does significantly retard the oxide growth – decreasing the oxide layer thickness from 1 nm in less than an hour to 0.9 nm over 116 hours. Additionally, the optical constants for aluminum oxide growing under an aluminum fluoride barrier layer have been determined – showing an increase in absorption at high energies for Al₂O₃ forming at room temperature as compared to highly ordered Al …