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Full-Text Articles in Physical Sciences and Mathematics
Equation Of State Of Sodium Chloride, Daniel L. Decker
Equation Of State Of Sodium Chloride, Daniel L. Decker
Faculty Publications
Because of many requests, I wish to publish the following numerical table of results for the equation of state of NaCl as calculated in an earlier paper1 along with a few comments on various proposed equations for NaCl. Table I gives the pressure in kilobars at the corresponding values of t.a/ao and temperature in the appropriate row and column. The parameter t.a/ao is the fractional compression of the lattice parameter where the standard value ao is the appropriate lattice parameter at zero pressure and 25°C. The increments between the values given in the table were chosen such that one can …
Model Of Electron Correlation In Solids, Everett G. Larson, Walter R. Thorson
Model Of Electron Correlation In Solids, Everett G. Larson, Walter R. Thorson
Faculty Publications
The usual Hartree-Fock model (energy-band theory) does not always give an adequate description of electronic structure in a solid, because it ignores the effects of electron correlation. It was shown first by Wigner that such a situation always develops in an electron ''gas'' at sufficiently low density; a solid structure described by ''resonance'' of Heitler-London pair bonds between electrons localized on neighboring atoms is then a good model of the system.The transition from a Bloch-type state to such a highly correlated state as a function of electron density (lattice parameter) is a problem of considerable interest for the theory of …
Pressure Calibration To 100 Kbar Based On The Compression Of Nacl, R. N. Jeffrey, J. Dean Barnett, H. B. Vanfleet, H. Tracy Hall
Pressure Calibration To 100 Kbar Based On The Compression Of Nacl, R. N. Jeffrey, J. Dean Barnett, H. B. Vanfleet, H. Tracy Hall
Faculty Publications
An independent determination has been made of the transformation pressures assigned to the high-pressure transformations in Ba and Bi which are generally used for calibration points. The metals were imbedded in NaCl, and the transitions were detected by the resistance change of the metal while the NaCl lattice parameter was simultaneously measured by x-ray diffraction. The NaCl compression values determined at the fixed points were related to pressure by reference to the semiempirical compression curve of Decker. The Ba I-II and Bi III-V transformations at room temperature were assigned thermodynamic equilibrium values of 53.3 ±1.2 kbar and 73.8 ±1.3 kbar, …
X-Ray Diffraction Studies On Tin To 100 Kilobars, J. Dean Barnett, Vern E. Bean, H. Tracy Hall
X-Ray Diffraction Studies On Tin To 100 Kilobars, J. Dean Barnett, Vern E. Bean, H. Tracy Hall
Faculty Publications
The high-pressure equilibrium phase diagram of tin is investigated, and the crystal structure of Sn II at 98 kbar and 25degrees C is shown to be body-centered tetragonal with a=3.70 Angstroms, c=3.37 Angstroms, c/a=0.91, and with two atoms per unit cell. The linear compressibility of white tin is given at 25degrees C up to the high-pressure transformation at 92 kbar, and the latent heat of the transformation is measured as 225 cal/g-atom.