Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Earth Sciences (3)
- Engineering (2)
- Geology (2)
- Hydrology (2)
- Biogeochemistry (1)
-
- Chemistry (1)
- Climate (1)
- Environmental Health (1)
- Environmental Sciences (1)
- Geochemistry (1)
- Inorganic Chemistry (1)
- Life Sciences (1)
- Oceanography and Atmospheric Sciences and Meteorology (1)
- Other Environmental Sciences (1)
- Pharmacology, Toxicology and Environmental Health (1)
- Sedimentology (1)
- Soil Science (1)
- Institution
- Publication
- Publication Type
Articles 1 - 7 of 7
Full-Text Articles in Physical Sciences and Mathematics
Topographic Controls On N2o And N2 Efflux In A Temperate Forest, Eric M. Enanga
Topographic Controls On N2o And N2 Efflux In A Temperate Forest, Eric M. Enanga
Electronic Thesis and Dissertation Repository
The release of greenhouse gases into the atmosphere is becoming an increasingly important problem due to the overwhelming evidence of the relationship between rising greenhouse gas concentrations and increased global temperatures. It is important that we gain a better understanding of the processes controlling the release of N2O, a powerful greenhouse gas. Topographic influences on soil temperature, moisture, reduction-oxidation (redox) potential, dissolved organic carbon, and nitrate conditions, which in turn influence N2O release, were investigated in a natural temperate forest ecosystem in Ontario, Canada. Wetland positions were observed to have the conditions most suited for N …
Coordination Nature Of 4-Mercaptoaniline To Sn(Ii) Ion: Formation Of A One Dimensional Coordination Polymer And Its Decomposition To A Mono Nuclear Sn(Iv) Complex, Eon S. Burkett, Tasneem A. Siddiquee
Coordination Nature Of 4-Mercaptoaniline To Sn(Ii) Ion: Formation Of A One Dimensional Coordination Polymer And Its Decomposition To A Mono Nuclear Sn(Iv) Complex, Eon S. Burkett, Tasneem A. Siddiquee
Chemistry Faculty Research
The coordination of the bifunctional ligand 4-mercaptoaniline with aqueo us tin(II) metal ion was studied. A coordination polymer was synthesized when an aqueous solution of SnCl2 was treated with 4-MA. The crystalline material is stable under atmospheric conditions retaining its oxidation state. However, when submerged in a solution saturated with oxygen, the compound oxidizes to a mononuclear tin(IV) complex. Both the compounds were characterized by single crystal X-ray diffraction studies. Although the structure of the tin(IV) complex was previously reported, crystal structure of this compound was redetermined.
Utilizing Indicator Of Reduction In Soils Tubes To Affirm A Serpentinitic Hydric Soil On The California Central Coast, Jason Demoss
Utilizing Indicator Of Reduction In Soils Tubes To Affirm A Serpentinitic Hydric Soil On The California Central Coast, Jason Demoss
Natural Resources Management and Environmental Sciences
Wetlands are vital ecosystems that are crucial in maintaining the life of rare and unique soils, plants, and animals. These ecosystems are key players in water storage, water filtration, carbon storage, and harboring unique species. Since the intervention of human development on the Earth’s surface, almost 50% of the Earth’s original wetlands have either been damaged or destroyed. The identification and assessment of both new and old wetlands is crucial in the survival of these precious ecosystems and their conservation. A 3 month-long study was performed to confirm the hydric status of a soil derived from serpentinitic parent material. The …
Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman
Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman
Masters Theses
Several studies indicate that seasonal applications of road deicers can lead to saline runoff entering surface water and groundwater, which can in turn change the chemistry, density, and physical mixing patterns of urban lakes. An investigation at Asylum Lake, an urban lake located near three major roadways, was conducted to determine the degree of road salt contamination in the lake, to determine if salt loading disrupts seasonal mixing patterns, and to determine the extent of redox stratification present due to eutrophic conditions. Samples were collected monthly from the deepest point in Asylum Lake over a 19-month period and analyzed for …
A Multi-Proxy Approach To Understanding Abrupt Climate Change And Laurentide Ice Sheet Melting History Based On Gulf Of Mexico Sediments, Clare Carlisle Williams
A Multi-Proxy Approach To Understanding Abrupt Climate Change And Laurentide Ice Sheet Melting History Based On Gulf Of Mexico Sediments, Clare Carlisle Williams
USF Tampa Graduate Theses and Dissertations
During the last deglaciation (ca. 24-10 ka thousand years ago (ka)), the North American Laurentide Ice Sheet (LIS) was a major source of meltwater to the Arctic Ocean, North Atlantic Ocean, and the Gulf of Mexico (GOM), and it is hypothesized that meltwater routing played an important role in regulating Late Quaternary millennial-scale climate variability, via its influence on Atlantic Meridional Overturning Circulation (AMOC). For example, the meltwater routing hypothesis predicts that a rerouting of meltwater from the GOM to the North Atlantic and/or Arctic Oceans resulted in a decrease of North Atlantic Deep Water (NADW) formation and subsequent cooling …
Polypyrrole Doped With Redox-Active Poly(2-Methoxyaniline-5-Sulfonic Acid) For Lithium Secondary Batteries, Yang Yang, Caiyun Wang, Syed A. Ashraf, Gordon G. Wallace
Polypyrrole Doped With Redox-Active Poly(2-Methoxyaniline-5-Sulfonic Acid) For Lithium Secondary Batteries, Yang Yang, Caiyun Wang, Syed A. Ashraf, Gordon G. Wallace
Gordon Wallace
Polypyrrole is a promising electrode material for flexible/bendable energy storage devices due to its inherent fast redox switching, mechanical flexibility, easy processability and being environmentally benign. However, its low attainable capacity limits its practical applications. Here, we synthesise a polypyrrole/poly(2-methoxyaniline-5-sulfonic acid) (PPy/PMAS) composite by incorporating redox-active PMAS into a PPy matrix via an electropolymerization method. For comparison, polypyrrole containing the electrochemically inert dopant p-toluenesulfonate (PPy-pTS) was prepared under the same conditions. The resultant PPy/PMAS film shows greatly improved electrochemical properties by harnessing the contribution from PMAS, i.e. higher specific capacity, better rate capability and improved cycling stability when used as …
A New Strategy For Integrating Abundant Oxygen Functional Groups Into Carbon Felt Electrode For Vanadium Redox Flow Batteries, Ki Jae Kim, Seung-Wook Lee, Taeeun Yim, Jae-Geun Kim, Jang Wook Choi, Jung Ho Kim, Min-Sik Park, Young-Jun Kim
A New Strategy For Integrating Abundant Oxygen Functional Groups Into Carbon Felt Electrode For Vanadium Redox Flow Batteries, Ki Jae Kim, Seung-Wook Lee, Taeeun Yim, Jae-Geun Kim, Jang Wook Choi, Jung Ho Kim, Min-Sik Park, Young-Jun Kim
Australian Institute for Innovative Materials - Papers
The effects of surface treatment combining corona discharge and hydrogen peroxide (H2O2) on the electrochemical performance of carbon felt electrodes for vanadium redox flow batteries (VRFBs) have been thoroughly investigated. A high concentration of oxygen functional groups has been successfully introduced onto the surface of the carbon felt electrodes by a specially designed surface treatment, which is mainly responsible for improving the energy efficiency of VRFBs. In addition, the wettability of the carbon felt electrodes also can be significantly improved. The energy efficiency of the VRFB cell employing the surface modified carbon felt electrodes is improved by 7% at high …