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Full-Text Articles in Physical Sciences and Mathematics
Crystal Engineering Of Functional Metal-Organic Material Platforms For Gas Storage And Separation Applications, Sameh Khamis Elsaidi
Crystal Engineering Of Functional Metal-Organic Material Platforms For Gas Storage And Separation Applications, Sameh Khamis Elsaidi
USF Tampa Graduate Theses and Dissertations
Metal-organic materials (MOMs) represent a unique class of porous materials that captured a great scientific interest in various fields such as chemical engineering, physics and materials science. They are typically assembled from metal ions or metal clusters connected by multifunctional organic ligands. They represent a wide range of families of materials that varied from 0D to 3D networks: the discrete (0D) structures exemplified by metal-organic polyhedra (MOPs), cubes and nanoballs while the polymeric 1D, 2D and 3D structures exemplified by coordination polymers (CPs). Indeed, the porous 3D structures include metal-organic frameworks (MOFs), porous coordination polymers (PCPs) and porous coordination networks …
Synthesis, Characterization And Mechanistic Studies Of Biomolecules@Mesomofs, Yao Chen
Synthesis, Characterization And Mechanistic Studies Of Biomolecules@Mesomofs, Yao Chen
USF Tampa Graduate Theses and Dissertations
Encapsulation of biomolecules is of great interest to research advances related to biology, physiology, immunology, and biochemistry, as well as industrial and biomedical applications such as drug delivery, biocatalysis, biofuel, food and cosmetics. Encapsulation provides functional characteristics that are not fulfilled by free biomolecules and stabilizes the fragile biomolecules. In terms of biocatalysis, solid support can often enhance the stability of enzymes, as well as facilitate separation and recovery for reuse while maintaining activity and selectivity. Various kinds of materials have been used for encapsulation of biomolecules, among which, porous materials are an important group. Metal-organic frameworks (MOFs) have attracted …
Template-Directed Synthesis And Post-Synthetic Modification Of Porphyrin-Encapsulating Metal-Organic Materials, Zhenjie Zhang
Template-Directed Synthesis And Post-Synthetic Modification Of Porphyrin-Encapsulating Metal-Organic Materials, Zhenjie Zhang
USF Tampa Graduate Theses and Dissertations
Metal-organic materials (MOMs) represent an emerging class of materials comprised of molecular building blocks (MBBs) linked by organic linker ligands. MOMs recently attract great attention because of their ability to exhibit permanent porosity, thereby enabling study of properties in the context of gas storage, gas separation, solid supports for sensors, catalysis and so on. Although MOMs have been studied for over 60 years, the porous nature of MOMs was not systematically and widely explored until the early 1990's. This may be one of the reasons why template-directed synthesis of MOMs remains relatively underexplored, especially when compared to other classes of …