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Full-Text Articles in Physical Sciences and Mathematics
Super-Aptamer Bio-Imprinted Hydrogels : An Investigation Into The Optimization And Characterization Of Cross-Linked Polymeric Materials Displaying Macromolecular Amplified Responses, Nicholas Alexander Gariano
Super-Aptamer Bio-Imprinted Hydrogels : An Investigation Into The Optimization And Characterization Of Cross-Linked Polymeric Materials Displaying Macromolecular Amplified Responses, Nicholas Alexander Gariano
LSU Doctoral Dissertations
It is becoming more important to detect ultra-low concentrations of analytes for biomedical, environmental, and national security applications. Equally important is that new methods should be easy to use, inexpensive, portable, and if possible allow detection using the naked eye. Detection of low concentrations of analytes generally cannot be achieved directly, but requires signal amplification by catalysts, macromolecules, metal surfaces or supramolecular aggregates. The rapidly progressing field of macromolecular signal amplification has been advanced using conjugated polymers, chirality in polymers, solvating polymers and polymerization/depolymerization strategies. The use of molecularly imprinted polymers is ideal for creation of novel sensors to meet …
Preparation And Characterization Of Cellulose Nanoparticles And Their Application In Biopolymeric Nanocomposites, Jingquan Han
Preparation And Characterization Of Cellulose Nanoparticles And Their Application In Biopolymeric Nanocomposites, Jingquan Han
LSU Doctoral Dissertations
Regenerated cellulose nanoparticles (RCNs) including both elongated fiber and spherical structures were prepared from microcrystalline cellulose (MCC) and cotton using 1-butyl-3-methylimidazolium chloride followed by high-pressure homogenization. The RCN has a two-step pyrolysis, different from raw MCC and cotton that had a one-step process. The crystalline structure of RCNs was cellulose II in contrast to the cellulose I form of the starting materials. Also, the RCNs have decreased crystallinity and crystallite size. The elongated RCNs produced from cotton and MCC had average lengths of 123 ± 34 and 112 ± 42 nm, and mean widths of 12 ± 5 and 12 …