Physical Sciences and Mathematics Commons^™

Determination Of Spatial Strata For Environmental Regulatory Purposes, John Edward Daniels

Dissertations

This dissertation introduces spatial strata modelling, a methodology that combines spatial statistics, cluster analysis, and geographic information system theories to analyze the background level of naturally occurring contaminants of concern (COCs). The objective of spatial strata modelling is to divide a geographic area of interest into mutually exclusive geographic zones (spatial strata): with each stratum representing a different level of COC concentration. An estimate of each stratum's COC concentration level, representing an upper regulatory limit, will also be provided. Data provided by the Michigan Department of Environmental Quality describing the spatial location and arsenic concentrations of 211 Michigan sites (arsenic …

How Secondary School Mathematics Teachers Construct An Understanding Of "Appropriate Use" Of Graphing Calculators In The Context Of Collegial Inquiry, Marcia L. Weller Weinhold

Dissertations

No abstract provided.

Geochemical And Isotopic Characterization Of Shallow Basinal Brines From The Makgadikgadi Pans Complex, Northeastern Botswana: Determination Of The Sources Of Salinity, Loago N. Molwalefhe

Dissertations

Isotopes and chemical tracers have been used to constrain the sources and causes of salinity in shallow groundwater brine from the Makgadikgadi Basin, northeastern Botswana. The brine is massively rich in chloride and sodium, and moderately rich in carbonates, sulphate and potassium, and is distinctively poor in divalent cationic species. Various models that have been advanced to explain the origin of the brines include evaporative enrichment at the surface and density-induced infiltration, dissolution of evaporites, and trapped connate water.

This study presents the compositional variability and behaviors of ·the stable isotopes of carbon (S¹³C) and oxygen (S^{18 …}

Irradiation Induced Order-Dis Order Transformations In Ni-Mo Alloys, Ovidiu F. Toader

Dissertations

No abstract provided.

A Robust Two-Sample Procedure To Estimate A Shift Parameter, Feridun Tasdan

Dissertations

This study estimates the location shift parameter in the two-sample problem. The classical method, Least Square(LS), obtains the shift parameter estimate under the normality assumption. A departure from normality assumption makes the estimate inefficient and unreliable. One alternative to the least square estimate is Hodges-Lehmann (HL) estimate which uses Wilcoxon ranks to estimate the shift parameter. This estimate is robust against contaminations and large outliers. The proposed method in this study combines two samples and uses convolution technique to find a density function for the combined sample. This new density function is later used in the construction of the log …

Programming Language Trends : An Empirical Study, Yaofei Chen

Dissertations

Predicting the evolution of software engineering technology trends is a dubious proposition. The recent evolution of software technology is a prime example; it is fast paced and affected by many factors, which are themselves driven by a wide range of sources. This dissertation is part of a long term project intended to analyze software engineering technology trends and how they evolve. Basically, the following questions will be answered: How to watch, predict, adapt to, and affect software engineering trends?

In this dissertation, one field of software engineering, programming languages, will be discussed. After reviewing the history of a group of …

Selective Removal Of Nox From Catalytic Cracking Regenerator Effluent Using Wet Scrubbing With Aqueous Sodium Chlorite Solutions, Pin Gu

Dissertations

In most refineries, the flue gas from the regenerator in the fluid catalytic cracking (FCC) unit represents a key source of NOx, SOx, particulate, and CO emissions. Wet scrubbing systems have been used with great success to control particulate and SOx emissions from typical FCC regenerator flue gas. Development of relatively inexpensive and safe additives that can be used in existing scrubbing systems to oxidize and absorb NOx is important in order to increase the industrial options to meet the provisions of the Clean Air Act and recently proposed EPA rules. This paper explores the feasibility of removing NOx from …

Measurement Of The Nonlinear Refractive Index (N2) And Stimulated Raman Scattering In Optical Fibers As A Function Of Germania Content, Using The Photorefractive Beam Coupling Technique, Ferdinand Anayo Oguama

Dissertations

One of the greatest challenges in optical communication is the understanding and control of optical fiber nonlinearities. While these nonlinearites limit the power handling capacity of optical fibers and can cause noise, signal distortion and cross talk in optically amplified transmission systems, they have been equally harnessed for the development of new generations of optical amplifiers and tunable laser sources. The two prominent parameters that characterize the nonlinear properties of an optical fiber are the nonlinear refractive index n₂ and the Raman gain coefficient g_R. These parameters are related to the third order nonlinear susceptibility [x^{(3) …}

Thermochemistry And Kinetics In Pyrolysis And Oxidation Reaction Of Oxygenate Chlorocarbons, Neopentane, And Ortho-Xylene, Hongyan Sun

Dissertations

Thermochemical properties of chlorinated alcohols, chlorinated hydroperoxides and corresponding alkoxy, hydroxy alkyl radicals, peroxy and hydroperoxy alkyl radicals are determined by ab initlo and density functional calculations for modeling and optimization of complex chemical processes for combustion or incineration of chlorinated hydrocarbons. The entropy and heat capacities from vibrational, translational, and external rotational contributions are calculated by statistical mechanics, and the hindered rotational contributions to S^°₂₉₈ and C_p(T)'s are calculated by using direct integration over energy levels of the internal rotational potentials. The values of ΔH_f^°₂₉₈ are determined using isodesmic reactions …

Design And Evaluation Of A List Gathering Tool In A Web-Based Collaborative Environment, Yuanqiong Wang

Dissertations

This research focuses on how to build a "list" structure to combine individual items of information into some sort of structure that converts the individual items of information into a structure of knowledge relative to the problem. Software was designed to provide relationships among and comparisons of the contributions in a "list" structure, so that individual members of a group process will be able to understand the contributions of information made by the group as a whole.

A List Gathering Tool was designed and implemented, which is one component in a Web-based Social Decision Support System (SDSS) Toolkit. Then, a …

Design And Evaluation Of A Voting Tool In A Collaborative Environment, Zheng Li

Dissertations

This dissertation researchdesigned, implemented, and evaluated a Web-based Dynamic Voting Toolfor small group decision-making in a collaborative environment.

In this dissertation, theliterature on voting tools in current GDSS research is presented. Variousvoting theories and methods are analyzed, and the advantages and weaknessesare compared, so as to gain a better understanding of how to apply thesedifferent voting methods to diverse decision-making situations. A briefoverview of scaling theories is also given, with an emphasis on Thurstone'sLaw.

The basic features of someweb-based voting tool implementations are reviewed along with a discussionof the pros and cons of Intemet voting. A discussion of Human DynamicVoting …

Understanding The Origins Of Metastability In Thin Film Growth; Tantalum And The Early Group Vb-Vib Metals, Neme Okechukwu Nnolim

Dissertations

Tantalum (Ta) is a metal that is highly prized for its applications in a variety of industries, including the microelectronics industry, where it is largely used in thin film modifications in order to achieve various electronic, magnetic and structural capabilities in solid-state devices. Ta frequently forms metastable phases, including the well-known ß-phase, during the preparation of thin Ta films by standard film deposition methods such as sputtering and electro-deposition. In order to gain insight into Ta metastable phase formation, the Bain transformation mechanism is studied for Ta and the neighboring body centered cubic (bcc) transition metals in Groups 5 and …

Spearman Rank Regression, Jason C. Parcon

Dissertations

The main purpose of this dissertation is to obtain an estimate of the slope parameter in a regression model that is robust to outlying values in both the x - and Y-spaces. The least squares method, though known to be optimal for normal errors, can yield estimates with infinitely large MSE's if the error distribution is thick-tailed. Regular rank-based methods like the Wilcoxon method are known to be robust to outlying values in the Y -space, but it is still grossly affected by outlying values in x -space.

This dissertation derives an estimate of the slope from an estimating …

A Comparison Of Different Schemes For Selecting And Estimating Score Functions Based On Residuals, Ali A. Al-Shomrani

Dissertations

In a linear model when the errors follow a normal distribution, least squares methodology is most powerful. However, when the assumption of normality of the error distribution is not met then there exist methods which are more powerful than least squares methods. Rank-based methods form one such class. These methods depend on the selection of a score function [varphi]( u ). The correct choice of [varphi] leads to an optimal (efficient) analysis, but its selection depends on the error distribution which is not known.

In this thesis, we explore different schemes for score selection. Some of these schemes are functions …

New Graphical Approach On The Analysis Of Experimental Data, Suha Sari

Dissertations

This study presents a new graphical method to identify significant effects in factorial experiments. The proposed methods are obtained for the different cases in which the design can be of full factorial or fractional factorial and the factor levels can be pure or mixed.

We focus on the different decomposition methods, for example orthogonal components system and orthogonal contrast method, to make use of the chisquare plot which requires that the sums of squares are of the same degrees of freedom. Examples and simulations illustrating the different cases of the procedure are presented.

Image Morphological Processing, Vijayalakshmi Gaddipati

Dissertations

Mathematical Morphology with applications in image processing and analysis has been becoming increasingly important in today's technology. Mathematical Morphological operations, which are based on set theory, can extract object features by suitably shaped structuring elements. Mathematical Morphological filters are combinations of morphological operations that transform an image into a quantitative description of its geometrical structure based on structuring elements. Important applications of morphological operations are shape description, shape recognition, nonlinear filtering, industrial parts inspection, and medical image processing.

In this dissertation, basic morphological operations, properties and fuzzy morphology are reviewed. Existing techniques for solving corner and edge detection are presented. …

Fully Nonlinear Interfacial Waves In A Bounded Two-Fluid System, Lyudmyla Leonidivna Barannyk

Dissertations

We study the nonlinear flow which results when two immiscible inviscid incompressible fluids of different densities and separated by an interface which is free to move and which supports surface tension, are caused to flow in a straight infinite channel. Gravity is taken into consideration and the velocities of each phase can be different, thus giving rise to the Kelvin-Helmholtz instability. Our objective is to study the competing effects of the Kelvin-Helmholtz instability coupled with a stably or unstably stratified fluid system (Rayleigh-Taylor instability) when surface tension is present to regularize the dynamics. Our approach involves the derivation of two-and …

Optimization For Source Localization And Geoacoustic Inversion In Underwater Acoustics, Urmi Ghosh-Dastidar

Dissertations

Matched-field inversion techniques are widely used for source localization and geoacoustic parameter estimation. These inversion methods correlate the received data with modeled data and find the model parameters which provide the maximum correlation. However, when a large number of unknown parameters is involved, many modeled data need to be generated and correlated with the observed data and thus, matched-field inversion can be computationally intensive. An optimization process applied to matched-field inversion is often required to accelerate the inversion process.

In this work, tabu is applied to matched-field inversion for source localization and environmental parameter estimation. Tabu is a global optimization …

High Pressure Effects On Electron Transport And Structure Of Colossal Magnetoresistive Materials, Congwu Cui

Dissertations

Pressure effects on the electronic, magnetic properties and structure of several typical colossal magnetoresistive manganites, La_0.60Y_0.07Ca_0.33MnO₃, Pr_1-xCa_xMn0₃ (X = 0.25, 0.30, 0.35), Nd_1-xSr_xMnO₃ (x = 0.45, 0.50), were explored through high pressure resistivity and structure measurements. It was shown that pressure up to ~7 GPa induces more complicated charge, spin and lattice state changes than in the low pressure range explored previously. In La_0.60Y_0.07Ca_0.33MnO₃, pressure induces a local atomic structure transformation at a critical …

Pharmacophore Derivation Using Discotech And Comparison Of Semi-Emperical, Ab Initio And Density Functional Comfa Studies For Sigma 1 And Sigma 2 Receptor-Ligands, Dawoon Jung

Dissertations

This study describes the development of pharmacophore and CoMFA models for sigma receptor ligands. CoMFA studies were performed for 48 bioactive sigma 1 receptorligands using [H³ ](+) pentazocine as the radioligand, for 30 PCP derivatives for sigma 1 receptor-ligands using [³H](+)SK-F 10047 as the radioligand and for 24 bioactive sigma 2 receptor-ligands using the radioligand [H³](+)DTG in the presence of pentazocine. Distance Comparisons (DISCOtech) was used as the starting point for CoMFA studies. The conformers, derived by DISCOtech were optimized using AMi, or HF/3-21G* in Gaussian 98. The optimized geometries were aligned with the pharmacophore, …

Nonlinear Optical Properties Of Novel Nanostructured Ion Implanted Laser Ablated Silicon Using Femtosecond Pulse Excitation, Elaine Nicole Lalanne

Dissertations

The study of the nonlinear optical properties of novel nanostructured ion implanted and laser ablation of Silicon is motivated by the need for materials that exhibit large values of the real part of the third order nonlinear susceptibility (χ⁽³⁾_Re). This property is essential for light controlled phase or refractive index modulation at low power, where the optical properties are used for optical switching devices. Previous nanosecond (ns) measurements indicated values of-2.8 x 10 ^-5; esu ( γ = 532 nm) for χ⁽³⁾_Re.

The characterization of nonlinear optical properties of the samples was studied …

Image Enhancement Techniques Applied To Solar Feature Detection, Artur J. Kowalski

Dissertations

This dissertation presents the development of automatic image enhancement techniques for solar feature detection. The new method allows for detection and tracking of the evolution of filaments in solar images. Series of H-alpha full-disk images are taken in regular time intervals to observe the changes of the solar disk features. In each picture, the solar chromosphere filaments are identified for further evolution examination. The initial preprocessing step involves local thresholding to convert grayscale images into black-and-white pictures with chromosphere granularity enhanced. An alternative preprocessing method, based on image normalization and global thresholding is presented. The next step employs morphological closing …

Application Of Adaptive Optics To The Spectroscopic Investigation Of Small-Scale Solar Structures, Klaus Hartkorn

Dissertations

We study bright points, umbral dots and the G-band using a two-dimensional spectrometer and an Adaptive Optics system, which allows us to record high-resolution dopplergrams and residual intensity images. We find evidence that bright points are smaller than 120 km in diameter. Bright points are situated exclusively in regions of enhanced G-band brightness and do not show a change in their shape or a displacement in their position of more than 120 km horizontally over a height range from 0 km to 320 km above photospheric level T = 1. We do not find velocity differences of more than 100 …

Multiobjective Optimal Control Problems With Endpoint And State Constraints, Kirsty J. Eisenhart

Dissertations

In this thesis we consider nonsmooth multiobjective optimal control problems in terms of a general preference on [Special characters omitted.]. The optimal control problems considered involve differential inclusion, endpoint constraints and state constraints. No convexity assumption is needed on the differential inclusion. Examples of common preferences are given, and the idea of approximating a preference is introduced. Euler-Lagrange necessary conditions and a form of the maximum principle are developed for closed preferences (and those that can be approximated by closed preferences) in terms of the limiting subdifferential. As a consequence, this is the first result in the literature for lexicographical …

The Tragedy Of The Rivers: Building Authority Over The British Water Environment, Kevin B. Vichcales

Dissertations

"The Tragedy of the Rivers: Building Authority over the British Water Environment" examines the problem of rivers as common public resources in modern Britain. Viewed historically, the enduring problem of environmental pollution control in Britain has been the establishment of regulating authority over aspects of nature that are regarded simultaneously as economic resources, public utilities, and public amenities. Legislators, subject to pressure from industrial polluters, political parties, and advocates for environmental quality, sought at different times to locate authority at local, regional, national and extra-national levels. Each effort failed to resolve the issue of authority over the environment, because administrative …

Experimental And Modeling Studies Of Formation Of Products Of Incomplete Combustion And Chlorocarbon Incineration, Roman Brukh

Dissertations

The two-stage combustor facility was used to investigate the process of chlorocarbon incineration and formation of products of incomplete combustion. For this purpose methylene chloride was used as a chlorine-containing compound. The propose of this research was to obtain a better understanding of the incineration process of chlorocarbons, such as methylene chloride, especially regarding its destruction efficiency and formation of products of incomplete combustion. For measuring near-real time very low concentrations of benzene and methylene chloride, on-line microtrap gas chromatography system was used.

The experimental system was validated using a known combustion reaction mechanism from literature. Modeling of combustion process …

Handgrip Pattern Recognition, Zong Chen

Dissertations

There are numerous tragic gun deaths each year. Making handguns safer by personalizing them could prevent most such tragedies. Personalized handguns, also called "smart" guns, are handguns that can only be fired by the authorized user. Handgrip pattern recognition holds great promise in the development of the smart gun.

Two algorithms, static analysis algorithm and dynamic analysis algorithm, were developed to find the patterns of a person about how to grasp a handgun. The static analysis algorithm measured 160 subjects' fingertip placements on the replica gun handle. The cluster analysis and discriminant analysis were applied to these fingertip placements, and …

Closed-Loop Control Of Vortex Shedding By Means Of Lorentz Force, Xiaoyun Sun

Dissertations

When an incompressible fluid flows past a circular cylinder, vortex shedding occurs as soon as the Reynolds number exceeds about 40. Vortex shedding is usually undesirable, as it generates a significant increase in drag, as well an oscillating lift force on the cylinder leading to cross-stream structural vibrations. Flow control to either delay the appearance of vortex shedding or fully suppress it has attracted much attention during the last decade. The focus of this dissertation is to control vortex shedding from a circular cylinder by applying an external electromagnetic field. As in previous works, the latter is generated by electrodes …

Thermochemistry And Kinetics In Pyrolysis And Oxidation Of Oxygenated Chlorocarbons And Chlorinated Aromatics, Li Zhu

Dissertations

Thermochemical. properties, Δf_H°₂₉₈, S°₂₉₈, and Cp°(T) (5<=T/K<=6000), are determined using different ab inifio and density functional theory methods for three chloromethyl radicals, CH₂Cl, CHCl₂, CCl₃, all chlorobenzenes from monochlorobenzene to hexachlorobenzene, and all chlorophenols from ortho-, meta-, para-chlorophenol to pentachlorophenol. The B3LYP/6-31G(d,p) method is used in the structure optimization. The B3LYP/6-31G(3df,2p), QCISD(T)/6-3 I G(d,p), and CB S-Q methods are used in single point calculations of total electronic energies. Harmonic vibration frequencies are scaled for zero point energies and thermal corrections. Isodesmic reaction(s) are utilized at each calculation level to determine Δf_H°₂₉₈ of each species. Contributions to S°₂₉₈ and Cp°(T) from …