Physical Sciences and Mathematics Commons^™

A Semantics-Based Approach To Machine Perception, Cory Andrew Henson

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Machine perception can be formalized using semantic web technologies in order to derive abstractions from sensor data using background knowledge on the Web, and efficiently executed on resource-constrained devices. Advances in sensing technology hold the promise to revolutionize our ability to observe and understand the world around us. Yet the gap between observation and understanding is vast. As sensors are becoming more advanced and cost-effective, the result is an avalanche of data of high volume, velocity, and of varied type, leading to the problem of too much data and not enough knowledge (i.e., insights leading to actions). Current estimates predict …

Electromagnetic Characterization Of Af455 With Dna-Ctma In Solvent Blends, Jessica Marie Hendricks

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This work studies the electromagnetic properties of AF455, a two photon dye, DNA bound with cetyltrimethyl ammonium (CTMA), in liquid solvent blends for use in thin film optical filters. The liquid properties of the materials are believed to be transferred to the films. The solvent blends used are ratios of toluene (T) and dimethyl sulfoxide (DMSO). The complex permittivity and permeability of the samples are measured using the short open coaxial line technique in the frequency range of 1.0 x 107 Hz to 2.0 x 109 Hz. In this frequency range, AF455 does not act as a two photon absorber. …

Synthesis And Electrodeposition Of Mixed Metal Trinuclear Clusters Of Molybdenum And Chromium In Ionic Liquid Onto A Platinum Electrode, Lynn Renee Frock

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Electrochemical properties of [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 and [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3] in 1-ethyl-3-methylimidazolium bis(pentafluoroethanesulfonyl)-imide ionic liquid was investigated. Cyclic voltammograms using a Platinum electrode indicated deposition had occurred for the [Mo3O2(O2CCH3)6(H2O)(CF3SO2H)2 metal cluster but had not for the polynuclear complex [Cr2Mo(u2-CH3COO)6(u3-O)(H2O)3][CF3SO3]. Constant potential electrolysis of -1.23 V using a platinum foil electrode was performed. Scanning electron microscopy in combination with energy dispersion spectroscopy confirmed that deposition had occurred.

Mining Diversified Decision Trees Across Multiple Datasets To Capture Similarities And Alignable Differences, Qian Han

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This dissertation studies the problem of mining shared and alignable difference knowledge structures across multiple datasets/applications. Shared and alignable difference knowledge structures are important for identifying analogies between application domains and for forming new hypothesis in challenging research applications, and for assessing the degree and types of knowledge-level similarities and differences between application domains for use in learning transfer. Generally speaking, shared knowledge structures characterize underlying datasets and highlight conceptual-level structural similarities among the datasets. This dissertation studies the mining of shared decision trees, which are a special type of shared knowledge structures. We first consider building one shared decision …

The Synthesis Of Haplomyrtin Utilizing The Triisopropylsilyl Protecting Group, William S. Barrow

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The synthesis of the arylnaphthalene lignan haplomyrtin using vanillin as a starting material is synthesized via: 1) a bromination of vanillin, 4-hydroxy-5-methoxybenzaldehyde, to produce 6-bromovanillin 2) a hydroxyl protection step of 6-bromovanillin with triisopropylsilylchloride to produce 2-bromo-4-triisopropylsilyoxy-5-methoxybenzaldehyde 3) an aldehyde protection step through a cyclic acetal formation using ethylene glycol to produce 2-(2-bromo-4-triisopropylsilyloxy-5-methoxyphenyl)-1,3-dioxolane 4) a lithium for halogen exchange of the doubly protected 6-bromovanillin leads to neucleophilic coupling with piperonal producing 1,3-benzodioxol-5-yl-[5-triisopropylsilyloxy-2-(1,3-dioxolane-2-yl)-4-methoxyphenyl]methanol and 5) an acid catalyzed intramolecular cycloaddition /Diels Alder adduct with dimethyl acetylenedicarboxylate producing dimethyl 1-(1,3-benzodioxol-5-yl)-4-hydroxy-6-methoxy-7-triisopropylsilyloxynaphthalene-2,3-dicarboxylate.

A Geophysical Investigation To Locate Missing Graves Utilizing Ground Penetrating Radar, Electromagnetic, And Magnetic Methods, Jared Wyatt Shank

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Old cemeteries often have graves that are unmarked because gravestones are missing or degraded and the graves are in areas for which maps or other historical documents are incomplete. This is the case for one cemetery in southwestern Ohio, known as Stevenson Cemetery, which contains graves of Revolutionary War and War of 1812 veterans. The immediate goal of this study is to locate unmarked graves in this cemetery using geophysical techniques. The broader goal is to evaluate three geophysical techniques to determine the effectiveness of each.

The three geophysical techniques evaluated in this study are magnetics, electro-magnetics, and ground-penetrating radar. …

Hydroquinone-Based Poly(Arylene Ether)S With Pendent Benzothiazole Or Benzoxazole And 3-Sulfonated Phenyl Sulfonyl Groups For Use As Proton Exchange Membranes, Huong Hoang

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A series of hydroquinone-based poly(arylene ether) copolymers, with truly pendent sulfonated phenyl sulfonyl groups and either benzothiazole or benzoxazole groups was synthesized for use as proton exchange membranes (PEM). Two homopolymers series, benzothiazole and benzoxazole based, were prepared via meta activated nucleophilic aromatic substitution polycondensation reactions. Two copolymer series of N-heterocyclic and sulfonated phenyl sulfonyl groups were synthesized via a similar method. The ratio of 3,5-difluoro-3'-sulfonated diphenylsulfone to 2-[3,5-bis-(4-hydroxyphenoxy)]benzothiazole or 2-[3,5-bis-(4-hydroxyphenoxy)]benzoxaole was varied to afford ion-exchange capacities ranging from 0.60 to 1.39 meq and 0.62 to 1.42 meq, respectively. Polymers were characterized by gel permeation chromatography (GPC), ¹³C NMR …

Anomalies In Sensor Network Deployments: Analysis, Modeling, And Detection, Giovani Rimon Abuaitah

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A sensor network serves as a vital source for collecting raw sensory data. Sensor data are later processed, analyzed, visualized, and reasoned over with the help of several decision making tools. A decision making process can be disastrously misled by a small portion of anomalous sensor readings. Therefore, there has been a vast demand for mechanisms that identify and then eliminate such anomalies in order to ensure the quality, integrity, and/or trustworthiness of the raw sensory data before they can even be interpreted.

Prior to identifying anomalies, it is essential to understand the various anomalous behaviors prevalent in a sensor …

The Enhancement Of Peroxide-Cured Fluoroelastomer Rubber To Metal Bonding, Richard Hunter Cooke Iii

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A "combi-cured&" fluoroelastomer (FKM) rubber formulation was designed to yield 100% cohesive rubber failure when cured to cold-rolled steel with derivatives of polymeric silane adhesives. Three different categories of adhesives were tested: Unsaturated Polymeric Silane with Phosphonium Salt (UPSP-D), Unsaturated Polymeric Silane (UPS-L), and Saturated Polymeric Silane (SPS-L). Adhesion Inserts molded using ASTM Method D429 Method C all consistently yielded 100% cohesive rubber failure and showed adhesion strength in the range of 700 to 800 psi after being pulled at 2" per minute until break. After obtaining consistent 100% rubber failure, a design of experiment (DOE) was implemented to determine …

Design And Fabrication Of An Eddy Current Brake Dynamometer For Efficiency Determination Of Electric Wheelchair Motors, Wesley Brin

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Electric wheelchairs have a considerable impact on improving the quality of life for the millions of disabled persons around the world. These modern pieces of technology offer freedom and mobility for disabled persons to interact with the world outside of their homes. The goal of this project is to assist in advancements of conventional electric wheelchairs. This includes replacing the heavy, bulky, and inefficient lead acid batteries and worm gear drive systems with lithium-ion batteries and wheel hub motors in order to decrease weight and size, and increase efficiency. This master thesis research is focused on designing, fabricating, and testing …

Cooperative Interactive Distributed Guidance On Mobile Devices, Gregory Burnett

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Mobiles device are quickly becoming an indispensable part of our society. Equipped with numerous communication capabilities, they are increasingly being examined as potential tools for civilian and military usage to aide in distributed remote collaboration for dynamic decision making and physical task completion. With an ever growing mobile workforce, the need for remote assistance in aiding field workers who are confronted with situations outside their expertise certainly increases. Enhanced capabilities in using mobile devices could significantly improve numerous components of a task's completion (i.e. accuracy, timing, etc.). This dissertation considers the design of mobile implementation of technology and communication capabilities …

Capturing And Modeling A Three-Dimensional Stationary Noise Source Directivity Pattern With A Dynamic Array In The Near Field, Randy Mieskoski

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The author has studied several legacy landmark methodologies to develop an original measurement technique. Spherical harmonics modeling practices were leveraged to accurately represent a source directivity pattern. In this thesis a lightweight microphone measurement array that was manually maneuvered around a static noise source was employed. The measurement technique consisted of inserting a head-tracker sensor onto the microphone array to allow the location of the captured acoustic Sound Pressure Level (SPL) to be investigated. By leveraging the historical methodologies the acoustic SPL and location data collected with this technique were processes to represent a directivity pattern of the compressor source …

Post-Emplacement Leaching Behaviors Of Nano Zero Valent Iron Modified With Carboxymethylcellulose Under Simulated Aquifer Conditions, Leslie Lavinia Williams

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Nanoscale particles of zero valent iron stabilized with carboxymethylcellulose (CMC-nZVI) have been shown to degrade chlorinated hydrocarbons efficiently in bench-scale investigations. The remediation of contaminated sites by subsurface injection of stabilized nZVI in a slurry form has been investigated at pilot scale and field scale with conflicting results concerning transport of stabilized nZVI and its long-term stability for in situ degradation of chlorinated hydrocarbons. Changes in the hydraulic conductivity in porous media have also been reported following injection of stabilized nZVI slurry in both large tank experiments and in field studies. This study investigated the leaching behavior of CMC-nZVI post-emplacement …

Adaptive Semantic Annotation Of Entity And Concept Mentions In Text, Pablo N. Mendes

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The recent years have seen an increase in interest for knowledge repositories that are useful across applications, in contrast to the creation of ad hoc or application-specific databases.

These knowledge repositories figure as a central provider of unambiguous identifiers and semantic relationships between entities. As such, these shared entity descriptions serve as a common vocabulary to exchange and organize information in different formats and for different purposes. Therefore, there has been remarkable interest in systems that are able to automatically tag textual documents with identifiers from shared knowledge repositories so that the content in those documents is described in a …

Synthesis And Characterization Of Graphene Oxide/Sulfur Nanocomposite For Lithium-Ion Batteries, Aaron Joseph Blake

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The growing need for clean and efficient energy storage systems has recently peaked due to concerns of climate change and increased global energy consumption. However, efficiently integrating renewable resources such as solar and wind energy into society will require a complex electrical energy storage (EES) system capable of storing and expending significant amounts of energy. A battery based on the lithium/sulfur couple can yield a theoretical specific energy of 2600Wh/kg, which is about five times higher than that offered by present Li-ion batteries, and hence, is a promising and attractive technology. Despite recent developments in addressing various issues inherent to …

The Solvent-Free Synthesis Of And N-Methyl-N-Alkylpiperidinium Salts And Their Anion Exchange Reactions With Dilithium Phthalocyanine, Michael Joseph Krol Jr.

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A nucleophilic substitution reaction of N-methylpiperidine with bromopropane, bromobutane, bromopentane, bromohexane and bromoheptane was carried out in a Q-Tube with excess alkyl halide and yielded N-methyl-N-propylpiperidinium bromide, N-methyl-N-butylpiperidinium bromide, N-methyl-N-pentylpiperidinium bromide, N-methyl-N-hexylpiperidinium bromide and N-methyl-N-heptylpiperidinium bromide in yields from 85 to 92 %. The salts, which were solids at room temperature, were soluble in dichloromethane and were characterized by 1H and 13C NMR, elemental analysis and DSC. Two of the piperidinium bromides, N-methyl-N-propylpiperidinium bromide, N-methyl-N-butylpiperidinium bromide were used in an anion exchange reaction with dilithium phthlocyanine to yield N-methyl-N-propylpiperidinium lithium phthalocyanine and N-methyl-N-butylpiperidinium lithium phthalocyanine, respectively in 78 to 85% …

The Synthesis And Characterization Of 1,3-Bisphenylsulfonylacetone, 2,5-Dicarboethoxy-3,4-Di(4-Methylphenyl)Cyclopentadienone Dimer, And Dp-Ppv Polymers And Oligomers, Mark Robert Duffy

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An SN2 reaction between 1,3-dichloroacetone and benzenesulfinic acid sodium salt was carried out to produce 1,3-bis(phenylsulfonyl)acetone. A crystal structure for 1,3-bis(phenylsulfonyl)acetone was obtained. The SN2 reaction was followed by a condensation reaction with benzil but this did not yield a condensation product. A photo-active compound, 2,5-dicarboethoxy-3,4-di(4-methylphenyl)cyclopentadienone, was synthesized and was shown to undergo a unique, solid-state dimerization. Several reactions involving the ester functions were carried out but these did not yield the expected products, instead, structural rearrangements seemed to predominate. An asymmetric cyclopentadienone, 2-carbomethoxy-5-methyl-3,4-diphenylcyclopentadienone, was synthesized and it was reacted with norbornadiene to produce methyl 4-methyl-2,3-diphenylbenzoate. The benzoate was reduced …

Quantitative Analysis Of The Polarity Reversal Pattern Of The Earth's Magnetic Field And Self-Reversing Dynamo Models, Patrick Shane Craig

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The geologic record documents that the Earth's magnetic field has reversed 284 times over the past 160 Myr. This study uses two methods to analyze the scaling properties of the pattern of geomagnetic reversals and to analyze the scaling properties of reversals output by two mathematical self-reversing dynamo models, the Rikitake (1958) two-disk dynamo and the magnetohydrodynamic (MHD) model of Driscoll and Olson (2011). The first analysis method plots the duration versus cumulative probability for geomagnetic polarity intervals ranging between 0.01 and 35 Myr. The Kolmogorov-Smirnov statistic is used to determine the optimal minimum value of xmin at which power …

Palaeoecological Analysis Of The Decline In Stromatolite Abundance During The Ordovician Period, Noran Mhm El-Sherif

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A stromatolite is a laminated benthic microbial deposit. Its uniqueness arises from being present since the Precambrian to the present. Stromatolites recorded a peak time during the Mesoproterozoic, subsequently they witnessed abrupt rises and falls in abundance with the steepest decline in the Ordovician period, from which it never recovered from. There is no consensus yet regarding the reasons behind the decline of stromatolites. Thus the decline of these microbial deposits remains an enigma. Additionally, a literature gap exists regarding the reasons that specifically led to the Ordovician decline. Accordingly, the focus of this literature-based MSc. thesis is to find …

Dual-Stimuli Responsive Poly(Ethylenimine)S With A Tunable Lcst For Gene Delivery, Mary Abraham

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Hyperbranched poly(ethylenimine)s (HPEI) were modified with hydrophobic isobutyryl amide groups (HPEI-IBAm_0.60) to cause an LCST. These modified polymers were then further substituted with hydrophobic alkyl chains (HPEI-IBAm_0.60-R_0.40), a mixture of alkyl chains and hydroxyethyl groups (HPEI-IBAm_0.60-EtOH_0.20-R_0.20), and a mixture of alkyl chains and low molecular weight PEG (HPEI-IBAm_0.60-PEG_0.20-R_0.20) to determine the effect of different functional groups on solubility behavior. At pH 7.4, all but three LCSTs were below body temperature (37 °C), while at pH 5, all but three LCSTs were above …

Iodo Containing Sulfone And Sulfonamide Based Poly(Arylene Ether)S, Fadwa G. Constandinidis

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In an ongoing project involving the synthesis of functionalized poly(arylene ether)s that carry pendent phenyl sulfonyl groups, the introduction of an iodo group was desired. The effects of fluorine position on the electrophilic iodination of the 2,4-, 2,6-, and 2,5- and 3,5-isomers of difluorodiphenylsulfone, DFDPS were studied. The relative reactivity, toward EAS, was probed via ¹³C NMR spectroscopy and verified experimentally by iodination with N-iodosuccinimide. The product mixtures and corresponding structures indicated that intermediate stability did not always correlate to reactivity. Model studies were also conducted on DFDPS isomers that successfully carry in iodo groups in a pendent …

Enhanced Resolution Of The Paleoenvironmental And Diagenetic Features Of The Silurian Brassfield Formation, Lisa Marie Oakley

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The Brassfield Formation is an early Silurian (Aeronian, Llandoverian) unit of limestone and dolostone with excellent preservation of early reef communities and a diverse invertebrate fauna. A well-preserved outcrop occurs in southwestern Ohio at the Oakes Quarry Park in Fairborn; it contains abundant corals and stromatoporoids that are co-dominant in reef and reef-affected settings. This research provided an enhanced perspective of the Brassfield Formation to better reconstruct its paleoenvironment and better understand its diagenetic features. The depositional and diagenetic features of the Brassfield are described and interpreted using histologic methods and light microscopy. Selected thin sections were treated with carbonate …

Natural Language Document And Event Association Using Stochastic Petri Net Modeling, Michael Thomas Mills

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The purpose of this research is to design and implement a new methodology that captures the natural language understanding of events from English natural language text and model it using Stochastic Petri Nets. To establish a baseline of recent natural language processing (NLP) and understanding (NLU) research, two surveys are presented. One is a general survey in NLP and NLU methodologies for processing multi-documents. It summarizes and presents methodologies in terms of their features, capabilities, and maturity. The second survey focuses on graph-based methods for NL text processing and understanding and analyzes them in terms of their functional descriptions, capabilities …

Computational Modeling Of Graphene Oxide Exfoliation And Lithium Storage Characteristics, Reza Mortezaee

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Graphene oxide is a two dimensional material obtained by adsorption of oxygen or oxygen-containing groups on graphene. Stacked layers of graphene oxide constitute graphite oxide. These materials have various applications such as a source material for graphene production, transport support for electron microscopy, flexible organic photovoltaic cells and use in Li-ion batteries. Generation of exfoliated graphene oxide from a graphite oxide precursor is achieved relatively easily in solution as compared to graphene exfoliation. In this study we investigate the details of the graphene oxide exfoliation procedure in solution by calculating the Gibb's free energies and reaction rates. We consider two …

The Synthesis Of Benzyloxy Substituted Dp-Ppvs, Ryan Oostendorp

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The alkyne 1-(benzyloxy)-4-(propargyloxy)benzene was reacted with 2,5-di(carboethoxy)3,4-diphenylcyclopentadienone to yield diethyl 5-((4-(benzyloxy)phenoxy)methyl)-2,3-diphenylterephthalate. The terephthalate was reduced with lithium aluminum hydride to produce 5-((4-(benzyloxy)phenoxy)methyl)-1,4-di(hydroxymethyl)-2,3-diphenylbenzene. The diol was reacted with thionyl chloride to yield the monomer 5-((4-(benzyloxy)phenoxy)methyl)-1,4-di(chloromethyl)-2,3-diphenylbenzene that has a pendent protected phenol function. The new compounds were characterized by melting point, IR, 1H NMR, 13C NMR spectroscopy and elemental analysis. Polymerization of the dichloro monomer via a Gilch polymerization yielded poly[(2,3-diphenyl-(5-((4-(benzyloxy)phenoxy)methyl)-1,4-phenylene) vinylene]. The polymer was characterized by IR, 1H NMR spectroscopy, TGA and DSC. The polymer was insoluble in most solvents but partially soluble in chlorinated solvents. The solid polymer fluoresced a …

Semsos : An Architecture For Query, Insertion, And Discovery For Semantic Sensor Networks, Joshua Kenneth Pschorr

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With sensors, storage, and bandwidth becoming ever cheaper, there has been a drive recently to make sensor data accessible on the Web. However, because of the vast number of sensors collecting data about our environment, finding relevant sensors on the Web and then interpreting their observations is a non-trivial challenge. The Open Geospatial Consortium (OGC) defines a web service specification known as the Sensor Observation Service (SOS) that is designed to standardize the way sensors and sensor data are discovered and accessed on the Web. Though this standard goes a long way in providing interoperability between sensor data producers and …

Two Fundamental Building Blocks To Provide Quick Reaction Capabilities For The Department Of Defense, Daniel Alan Uppenkamp

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The Department of Defense (DoD) has a need for long-term development efforts in conjunction with short-term development efforts. Ideally, Quick Reaction Capabilities (QRC) would be able to make use of the same processes that are used for Acquisition Programs (AP) with a few modifications to accommodate the accelerated schedule. Unfortunately, APs have a more fundamental problem with both the development process and the development framework. In August of 2007, the agile development process and modular, open source framework discussed in this thesis were two key factors that enabled the Air Force Research Laboratory (AFRL) to successfully deploy AngelFire in support …

Effect Of Sample History On Dissolution Rates Of Gypsum {010} Surfaces, Dennis Stefan Renier Lennaerts

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Mineral dissolution plays a significant role in geochemical processes such as carbon sequestration and isotope geochemistry. While factors such as temperature, pressure, and solution chemistry have been widely studied, the effects of sample history and surface morphology on dissolution rates have been studied to a lesser extent. This research focuses on the dissolution of cleaved, polished, and reacted samples of the atomically flat natural {010} cleavage plane of gypsum (CaSO4·2H2O) to further investigate upon the effect of sample history. Gypsum was chosen as the mineral of interest because of its planar crystal surface and relatively fast dissolution rate. Chemical dissolution …

Abiotic Reduction Of Nitrite And Nitrate By Nanoscale Chemogenic Magnetite: Pathways For Significant Greenhouse Gas Production, Adam Charles Burdsall

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The biogeochemical cycling of nitrogen in terrestrial systems is a major source of nitrous oxide (N₂O), which is among key greenhouse gases (GHG). While biotic processes are commonly accepted as the major drivers of N₂O production, the role of abiotic processes is less understood, and their importance may be underestimated. This study investigates abiotic reactions in the formation and breakdown of N trace gases, including nitric oxide (NO) and nitrous oxide (N₂O) by naturally occurring nanoscale magnetite in soil as denitrification (reduction of nitrite) intermediates. Nitrogen biogeochemical cycling has been studied extensively with respect …

A Latent Dirichlet Allocation/N-Gram Composite Language Model, Raymond Daniel Kulhanek

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I present a composite language model in which an n-gram language model is integrated with the Latent Dirichlet Allocation topic clustering model. I also describe a parallel architecture that allows this model to be trained over large corpora and present experimental results that show how the composite model compares to a standard n-gram model over corpora of varying size.