Physical Sciences and Mathematics Commons^™

Microplastic Accumulation In Terrestrial Gastropods And Soils, Gregory B. Bonilla

Masters Theses

Microplastics (MPs) have become an emerging threat to ecosystems across the world. Transport, impacts, and fates are grossly understudied, especially in terrestrial environments. Current research on MP bioaccumulation has focused mainly on aquatic organisms with little study of terrestrial organisms, including snails where data are nearly nonexistent. To address this, we collected and examined land snails and their surrounding soil for MP content in shell and tissue. From September 11, 2020, to October 25, 2021, cover boards were placed (n=30) along relatively undisturbed sites in hardwood, forested areas, and tall grasses in a Wildlife Management Area (WMA) in Oak Ridge …

Synthesis And Characterization Of 2,6-Diisopropylphenoxy Tetrapyrazinoporphyrazines As Potential Molecular Qubits, Benjamin Marx

Masters Theses

This thesis reports the synthesis of metal-free and metal-containing phthalocyanine derivatives using methods typical for that class of functional dyes. A mixture of the target compounds prepared here, one paramagnetic and one diamagnetic tetrapyrazinoporphyrazine, will be tested for their potential use in spintronics – the application of spin-active species in molecular electronics. Phthalocyanines and their derivatives are well-known for their ease of preparation and tunability; they have been utilized as sensitizers for photodynamic therapy of cancer and solar cells, as well as in catalysis and chemical sensing. Tetrapyrazinoporphyrazine complexes are compared with the parent phthalocyanine as their chemistry is similar …

Elegance Or Alchemy? An International Cross-Case Analysis Of Faculty And Graduate Student Perceptions Of Mathematical Proofs, Brooke Nicole Denney

Masters Theses

Artist Marcel Duchamp once said, ``The painter is a medium who doesn’t realize what he is doing. No translation can express the mystery of sensibility, a word, still unreliable, which is nonetheless the basis of painting or poetry, like a kind of alchemy" (Moffitt, 2012). Just as there is a puzzling aspect of creating art or writing poetry, the aesthetic quality of mathematical proofs is a mysterious and ill-defined concept. Like many other subjective terms, it can be difficult to reach a consensus on what elegance means in a mathematical context. In this thesis, I try to better understand faculty …

Manganese Geochemistry And Plant Availability In Response To Agricultural Practices, Ashleigh R. Montgomery

Masters Theses

Manganese (Mn) is an essential micronutrient for all organisms. In soils, Mn forms determine availability to plants. Most Mn research has been conducted in forest ecosystems and Mn cycling in agricultural systems is understudied. Therefore, the objective of the experiment is to understand the effect of different agricultural management strategies on Mn cycling and plant availability. First, a greenhouse experiment was conducted to determine the effect of different application rates of two Mn fertilizers (MnSO₄ and MnEDTA) on soil geochemical properties and growth of corn (Zea mays) and soybean (Glycine max). The fertilizers were applied to …

The Characterization Of Dynamic Soil Properties And Their Relation To Soil Organic Carbon In East Tennessee Soils, Shannon Marissa Newell

Masters Theses

Quantifying how dynamic soil properties (DSPs) are affected by different management regimes is essential for understanding how these vital resources can be better managed. The Dewey soil series is a critical soil series in East Tennessee. For this study, the University of Tennessee, Knoxville (UTK) worked alongside the National Cooperative Soil Survey (NCSS) in an effort to better understand the dynamics of the Dewey soil series through a wide range of DSP data. To accomplish this, Dewey soil was collected from five sites which are considered representative of five management regimes: well-managed cropland (WMC), poorly-managed cropland (PMC), well-managed pasture (WMP), …

Comparative Geochemical Analysis Of Recent Volcanic Flows On Barva Volcano, Costa Rica, Julie Coulombe

Masters Theses

ABSTRACT

Barva Volcano is a dormant stratovolcano in the Cordillera Central region of Costa Rica, rising above the capital city of San Jose with a population of 347,000. Barva’s recent inactivity and extensive forestation have resulted in fewer investigations of its composition, petrogenesis, and eruptive history. The objective of this research is to analyze the geochemical data from several of the most recent lava flows, evaluate variability between eruptive units, and ascertain physical conditions within the Barva magma storage region. The data collected in this study helps constrain the geochemistry of units seen in the quarry and provides information regarding …

Kinematic And Vorticity Analysis Of The Slide Lake And Homestake Shear Zones, Central Colorado, Carsen T. Adams

Masters Theses

Kinematic and quantitative vorticity analysis of the Homestake shear zone (HSZ) and the Slide Lake shear zone (SLSZ) in central Colorado provide further insight into crustal processes that controlled deformation within the Colorado Mineral Belt (CMB) shear zone system throughout the Proterozoic. Evaluating vorticity, that is, the relative contributions of pure to simple shear in sheared rocks, is crucial to understanding lithospheric tectonic evolution and allows for kinematic modeling of shear zone development at a variety of scales. Moreover, novel vorticity analyses involve determining the orientation of the vorticity vector and vorticity normal surface which can give insight into shear …

Analysis Of Turbulent Flow Behavior In Helicopter Rotor Hub Wakes, Forrest Mobley

Masters Theses

The rotor hub is one of the most important features of all helicopters, as it provides the pilot a means for controlling the vehicle by changing the characteristics of the main and tail rotors. The hub also provides a structural foundation for the rotors and allows for the rotor blades to respond to aerodynamic forces while maintaining controllability and stability. Due to the inherent geometry and high rate of rotation, the rotor hub in its current form acts a large bluff body and is the primary source of parasite drag on the helicopter, despite its relatively small size. The rotor …

Challenges In Approaching The Detection Limits For Hillslope Erosion Using Terrestrial Laser Scanning, Gene Nathan Bailey Iii

Masters Theses

Accurately quantifying soil loss due to water erosion is a critical step in managing soils. Terrestrial LiDAR (Light Detection and Ranging) presents a potential alternative to traditional soil loss measurement by estimating soil erosion and deposition through detecting surface changes. Terrestrial LiDAR can also provide spatial distribution information without disturbing the observed surface. While erosion estimation through terrestrial LiDAR detects large magnitude erosion well, the finer temporal/spatial scale erosion experienced on the hillslope in sheet and rill erosion has remained a challenge to detect. This research addresses two of the challenges in using terrestrial LiDAR on fine scales in two …

Meta-Heuristic Optimization Techniques For The Production Of Medical Isotopes Through Special Target Design, Cameron Ian Salyer

Masters Theses

Medical isotopes are used for a variety of different diagnostic and therapeutic purposes Ruth (2008). Due to recent newly discovered applications, their production has become rapidly more scarce than ever before Charlton (2019). Therefore, more efficient and less time consuming methods are of interest for not only the industry’s demand, but for the individuals who require radio-isotope procedures. Currently, the primary source of most medical isotopes used today are provided by reactor and cyclotron irradiation techniques, followed by supplemental radio-chemical separations Ruth (2008). Up until this point, target designs have been optimized by experience, back of the envelope calculations, and …

Public Perceptions Of Salamanders In Great Smoky Mountains National Park, Savannah Blackman

Masters Theses

Amphibians receive little attention when it comes to public appreciation or support for their conservation. Despite their ecological importance, salamanders are often little known and overlooked by the general public. To better conserve their rapidly declining populations, it is important to understand and consider public knowledge and attitudes toward salamanders and certain behaviors that negatively affect them—like rock stacking in streams and rivers. The Great Smoky Mountains National Park is referred to as the “Salamander Capital of the World!” as it is home to more than 30 different species of salamander. One issue facing salamander populations within the park is …

Texture And Composition Of An Arid-Climate Weathering Profile And The Link Between Bedrock And Derived Sediment Composition, Kristan Leigh Watkins

Masters Theses

Multiple compositional aspects of Holocene, terrigenous-clastic sediment differ from its source, the underlying Cretaceous Stepladder granodiorite (Mojave Desert, California). Different processes can cause sediments to change in composition from source, including chemical weathering, hydrodynamic sorting during transport, and diagenesis. Sorting and physical processes have previously suggested. To assess the relative contributions of these processes to understand provenance reconstruction, the textures and compositions of an exposed Holocene saprolite weathering profile, grus, and granodiorite bedrock were studied. Fracture density in the weathering profile decreased from ~10% at the top to ~2% at the bottom of the profile in contact with the bedrock. …

Transverse Energy Analysis In Small Collision Systems, Alexander L. Aukerman

Masters Theses

Heavy Ion Collisions performed in the LHC at Cern are capable of generating a new phase of nuclear matter known as the Quark Gluon Plasma. In addition to running heavy ion collisions, the detectors dedicated to studying the QGP perform collisions utilizing smaller collision systems for the sake of comparing key measurements associated with the creation of a QGP. The transverse energy of the particles generated from the collision is one such key measurement. For the sake of comparison an analysis is performed on the transverse energy measurements taken from proton-proton collisions.

Evaluation Of Microbiometer As A Tool To Estimate Soil Health In A West Tennessee Cotton Crop, Daniel T. Sain

Masters Theses

Healthy soils are critical for optimized yields and sustainability in agriculture. Soil health testing can provide valuable information on how management practices are affecting soil health. In west Tennessee, existing soil health tests were unable to discern between significant differences in management practices. A new soil health test called microBIOMETER® has been developed by Prolific Earth Sciences® (Montgomery, NY). MicroBIOMETER® utilizes a new methodology for estimating microbial biomass and uses that estimate as a soil health score. This test has not been validated for use in west Tennessee. This research was focused on the validation of microBIOMETER® in a continuous …

Understanding Hydrogen Variations In Silicate Glasses As A Result Of Degassing: Fire-Fountaining On The Moon And Earth, Erin M. Recchuiti

Masters Theses

Volatiles, particularly hydrogen, play a key role in volcanic eruptions, especially explosive eruptions like fire-fountaining [e.g., Saal et al. 2002; Dixon 1997; Arndt & von Engelhardt 1987; Yoder 1976]. Discerning volatile abundance and behavior during ascent and eruption can aid in understanding the source melt and primary volatile content of planetary interiors. Volcanic glasses are samples closest to the primary melt, as they quench quickly enough to limit fractionation or crystallization. This is paramount for volatile studies, especially pertaining to water as its constituents are oxygen and hydrogen. Hydrogen is the most volatile element and one of the first to …

Assessment Of Soil Health Under Native Warm-Season Grasses And Different Grazing Management, Kara Leigh Grosso

Masters Theses

This research uses analysis of soil quality indicators (SQIs) to compare vegetation species and grazing management over the 2021 grazing season. The soil health effect of the native warm-season grasses (NWSG) big bluestem (BB) (Andropogon gerardii) mixed with indian grass (IG) (Sorghastrum nutans) (BBIG), and switchgrass (SG) (Panicum virgatum), inter-seeded with a 12 species biodiversity mix was investigated in a 5 pressure grazing system (no graze (NG), no rest (NR), early, middle, and late rest (ER, MR, LR)). Additionally, there is a need for inexpensive tools for land owners to assess soil quality, and a validation study …

Enigma - Ongoing Development Towards Novel Beta-Decay Spectroscopy Station At Isolde, Philipp Wagenknecht

Masters Theses

Beta decay and collinear laser spectroscopy are proven efficient tools to study nuclear structure far from stability. Two areas of significance are investigations into nuclear deformation and shape coexistence, as well as delayed neutron emissions used in nuclear energy applications. This contribution presents the ongoing development towards a novel beta-decay spectroscopy station for the VITO experiment at CERN’s radioactive ion beam facility ISOLDE. The setup will utilize both collinear laser spectroscopy and beta-decay spectroscopy to measure the energy and spin-parities of the ground and excited states of radioactive beams. Initial designs of the support structure, magnetic field, and detector array …

Path Planning And Flight Control Of Drones For Autonomous Pollination, Chapel R. Rice

Masters Theses

The decline of natural pollinators necessitates the development of novel pollination technologies. In this thesis, a drone-enabled autonomous pollination system (APS) that consists of five primary modules: environment sensing, flower perception, path planning, flight control, and pollination mechanisms is proposed. These modules are highly dependent upon each other, with each module relying on inputs from the other modules. This thesis focuses on approaches to the path planning and flight control modules. Flower perception is briefly demonstrated developing a map of flowers using results from previous work. With that map of flowers, APS path planning is defined as a variant of …