Physical Sciences and Mathematics Commons^™

Synthesis And Studies Of A Carbon-13 Labelled Chemical Carcinogen, Robert E. Royer

Chemistry and Chemical Biology ETDs

Derivatives of 6-methylbenzo[a]pyrene enriched to 90% carbon-13 at the methyl carbon were synthesized. Reactions of the carcinogen, 6-chloromethylbenzo[a]pyrene, with nucleophiles under solvolytic conditions were studied kinetically and, using labelled 6-chloromethylbenzo[a]pyrene, the reaction products were studied by CMR. The purpose was to characterize the selectivity of the benzo[a]pyrenyl- 6-methyl carbonium ion in its reactions with some simple nucleophiles and with nucleosides and other nucleic acid components.

Although the solvolysis of 6-chloromethylbenzo[a]pyrene in aqueous/organic solution is first order, information about the course of the reaction can be obtained, under certain circumstances, from rate constants. Thus, if the rate of solvolysis is slowed …

Photochemical Studies Of Hydroxo-Bridged Complexes Of Chromium (Iii), Ronald Raymond Ruminski

Chemistry and Chemical Biology ETDs

The acid solution and solid state photolysis in both visible and ultraviolet regions of the spectrum for µ-hydro­xo-bis[pentaamminechromium(III)] chloride, and the solution photolysis in the visible and 1 traviolet region of the spectrum for µ-hydroxo-bis[pentaarnrninechr rnium(III)] perchlorate, have been studied. The ultraviolet irradiation of µ-hydroxo-bis[pentaamminechromium(III)] chloride in HCl and CHlO₄ produces a redox photoproduct identified as HCrO₄^-, although the rate of production of HCrO₄^- in HClO₄ is slower than in HCl. Photochemical cleavage of the hydroxo-bridge occurs in the ultraviolet photolysis of µ -hydroxo-bis[pentaanuninechromium(III)] chloride and is 1.9 times faster than the corresponding …

The Effects Of Various Pyrolysis Conditions On The Release Of Products From Green River Oil Shale, Georgia Thomas Fritz

Chemistry and Chemical Biology ETDs

The fusion of oil shales with eutectic mixtures of inorganic salts was studied with the objective of finding a chemical means of releasing the organic material either at a lower temperature or with a lower empirical activation energy (E_a). Experimental techniques by which the pyrolysis of oil shale was studied were thermogravimetry (TG), evolved gas detection (EGD), and pyrolysis/thin-layer chromatography (TLC). The following fused salts were investigated (ratios in mo1%): LiCO₃/Na₂co₃/K2CO3, 43.5/31.5/25.0; KSCN/NaSCN, 73.75/26.25; KSCN/­NaSCN, 70/30; Na₂SO₄/K₂SO₄/ZnSO₄, 29.1/30.2/40.7; NaCl/Na₂CO_{3 …}

Measurement Of The H- Photodetachment Cross Section In The Continuum Region From 1.5 To 10.5 Ev, Mohammad Hassan Sharifian-Attar

Physics & Astronomy ETDs

We have measured the H photodetachment cross section in the photon energy range from 1.5 to 10.5 eV, using a colliding beam method. The H beam with an energy of 800 MeV, at Los Alamos Linear Accelerator, was intersected by a nitrogen laser beam with a photon energy of 3 .678 eV in the lab frame. We changed the energy of the pho"ton in the H rest frame, through the Doppler effect, by varying the angle between the laser and the H beams. The magnitude of the Doppler shift was enough to cover the entire range from 1.5 to 10.5 …

Texture, Fabric And Composition Of Fine-Grained Terrigenous Sediments From The Graneros Member Of The Mancos Shale, San Juan Basin, New Mexico, Anthony J. Skeryanc

Earth and Planetary Sciences ETDs

Petrography, scanning electron microscopy (SEM), porosity and permeability, radiography, x-ray diffraction (clay mineralogy), whole rock wet chemistry and organic analysis are used to examine the texture, fabric and composition of fine-grained terrigenous sediments from the Graneros Member of the Mancos Shale, San Juan Basin, New Mexico. Grain content is highly variable and determines the configuration of the fabric during compaction. A scale of the degree of parallel orientation is compared to grain content and reveals a decrease in parallelism with an increase in grain content. Grain content also affects permeability, thus controlling he degree of authigenic mineralization. Although clay composition …

Mineralogy, Petrology, And Geochemistry Of Some Lavas From Kohala Volcano, Hawaii, Steven Sherman Sibray

Earth and Planetary Sciences ETDs

Twelve samples from Kohala volcano, Hawaii were selected for chemical analyses and electron microprobe study. Seven of the samples are from the Pololu volcanic series. Three of these samples are tholeiitic basalts, two are oceanites, and two are alkali olivine basalts transitional to hawaiite. The five samples from the Hawi volcanic series include one hawaiite, two mugearites, and two benmoreites. Electron microprobe study of the minerals in the basaltic matrix of the two oceanites reveal that one of the oceanites was derived from a tholeiitic magma while the other was derived from an alkalic magma. The alkalic oceanite matrix is …

Mineralogy, Petrology, And Geochemistry Of Some Lavas From Kohala Volcano, Hawaii, Steven Sherman Sibray

Earth and Planetary Sciences ETDs

Twelve samples from Kohala volcano, Hawaii, were selected for chemical analyses and electron microprobe study. Seven of the samples are from the Polulu volcanic series. Three of the samples are tholeiitic basalts, two are oceanites, and two are alkali olivine basalts transitional to hawaiite. The five samples from the Hawi volcanic series include one hawaiite, two mugearites, and two benmoreites. Electron microprobe study of the minerals in the basaltic matrix of the two oceanites reveal that one of the oceanites was derived from a tholeiitic magma while the other was derived from an alkalic magma. The alkalic oceanite matrix is …

Comparisons Between Oriented Film And Solution Tertiary Structure Of Various Nucleic Acids, Douglas R. C. Priore

Chemistry and Chemical Biology ETDs

It was desired to help establish whether or not the tertiary structure of a biomolecule is the same in a cry­stal (or an oriented film) as it is in solution. Generally it is accepted that the structures in these diverse environ­ments are similar, if not identical. By comparing the extinction coefficients obtained from oriented film data to those obtained from solution data it was hoped that this question might further be resolved. To this end an electric dichroism instrument built in our lab was used to measure the dichroic signal so as to calculate, with the help of the ultraviolet …

On The Electrical Evaluation Of Three Southern New Mexico Geothermal Areas, Christian Smith

Earth and Planetary Sciences ETDs

Three electrical resistivity exploration programs have been made at areas of known but unassessed geothermal resources in the Rio Grande rift and Basin and Range province of southern New Mexico: Radium Springs Known Geothermal Resource Area (KGRA), Las Alturas Estates, and Lightning Dock KGRA. The experiments are the framework for a thorough reconnaissance electrical evaluation of these geothermal resource areas. A preliminary experiment was made at Rio Rancho Estates, near Albuquerque, in order to evaluate the applicability and resolution of electrical methods in an area of known subsurface geology within the Rio Grande rift. The interpreted depth to electrical basement, …

Heights Of Formation For Certain Solar Spectral Lines, Erik J. Schwendeman

Physics & Astronomy ETDs

Heights of formation are calculated for several of the solar spectral lines studied by the National Aeronautics and Space Administration - Goddard Space Flight Center (NASA-GSFC) New Mexico Solar Station at Sacramento Peak Observatory. These lines are Ca II H, K, 8498 Å and 8542 Å, MgI b₁, NaI D₁ and D₂ and Sil 4103 Å. I calculate the heights of formation for each of these lines along with upper and lower confidence limits representing the height region where 90% of the total intensity of the line is formed in the solar photosphere and chromosphere. The …

Numerical Methods For Multipoint Boundary Value Problems, Mahoud Abdul-Ghani Sarhan

Mathematics & Statistics ETDs

Existence and uniqueness theory for ordinary differential systems subject to linear constraints is presented in some detail. Finite difference schemes, shooting methods, orthonormalization procedures and projection methods are studied. Orthonormalization procedures are shown to be ineffective for the general linear problem. Projection methods for linear differential systems with fairly general multipoint boundary conditions are thoroughly developed. Two particular examples of such methods are given: Galerkin and collocation. The various numerical methods considered are evaluated and compared. Several examples are discussed and numerical results are displayed .

Petrology And Geochemistry Of Shonkinite, Syenodiorite, And Nepheline Monzonite Of The Island Of Kauai, Hawaii, Henry Gassaway Brown Iv

Earth and Planetary Sciences ETDs

Boulders of shonkinite, syenodiorite, and nepheline monzoni te occur on Kauai, Hawaii. Boulders of shonkinite and syenodiorite outcrop 1 mile north of Kalaheo and nepheline monzonite boulders have been found in Wailooa Canyon along Koaie and Waialae streams. Detailed petrographic and bulk-rock and mineral geochemical study of samples collected from each locality suggest crystallization in supercooled nephelinic magmas. Shonkinite probably formed after a moderate degree of supercooling, syenodiorite after a high degree of supercooling, and nepheline monzonite after minimal supercooling. Shonkinite, syenodiorite, and nepheline monzonite probably crystallized in hypabyssal magma chambers beneath vents for Koloa Volcanic Group lavas.

Shonkinite formed …

Plasma Sheath Analysis By Computer Simulation, Leo J. Rahal

Physics & Astronomy ETDs

The time development of a fully ionized, dense two-component plasma is investigated through the use of a one-dimensional particle simulation code. The plasma is initially composed of two distinct regions. One region is a uniform plasma in which electrons and ions are at the sane temperature and have no electric fields due to charge separ­ation. The other region contains a charge separation of electrons and ions resulting in an electric field. There also exists an electron current which produces a confining magnetic field. This is the sheath region between the neutral plasma and the confining magnetic field. The simulation occurs …

Infrared Observations Of Hii Regions And Comet West, Paul A. Heckert

Physics & Astronomy ETDs

In Chapter 1, I outline the methods of making ground-based infrared observations. I concentrate on the observational procedures rather than the instrumental design. Near-infrared observations of S 156A, _S 158A, S 159A, S 162A₁, S 228, and G 45. 5 + 0 .1 (#2) made with a beam size of ̴1 are used to estimate the total near infrared flux. After correcting for the line of sight extinction the near infrared luminosities are greater than the Lyman-α luminosities inferred from radio observations. A strong double peaked infrared source was discovered near the region of G 25.3-0.1. The infrared …

Chromium(Iii) Tartrates, Gerald Lynn Robbins

Chemistry and Chemical Biology ETDs

The binuclear tartrate-bridged complexes [Cr ₂ (tartH) ₂ (L)₂ ] and Na [ Cr₂ (tart) (tartH) (L)₂]("tart" = C₄H₂O₆^4-, "tartH" = C₄H₃O₆^3- and "L"= 1,10-phenanthroline or 2,2'-bipyridyl) have been synthesized where each complex contains either two optically active or two meso bridging ligands. A discussion of the number of isomers and symmetries of these complexes is presented, as well as a complete description of the syntheses of the complexes and their sodium salts.

Alkali Basalt-Trachyte Suite And Volcanism, Northern Part Of The Mount Taylor Volcanic Field, New Mexico, L. S. Crumpler

Earth and Planetary Sciences ETDs

This report is the result of detailed mapping of a part of the northern Mount Taylor volcanic field of west-central New Mexico. More than 100 volcanic vents were mapped, including 8 maars, 5 pit craters, and 15 distinct trachyte flow domes. Three successive periods of volcanism were identified: (1) Tapia stage (pre-Mount Taylor, 3.26^± .20 m.y.): an alkali basalt-trachyte suite, identified here for the first time on the North American continent; includes basanitoid, hawaiite, mugearite, benmorite and trachyte. Of these, the trachyte is the most voluminous (about 3 km³), the basanitoid and hawaiite (''early basalt") the least …

Environmental Perception In Bandelier National Monument, New Mexico, Howard Graham Crow Ii

Geography ETDs

The focus of this study was on visitor satisfac­tion in a natural area, as opposed to alternative use such as preservation of the area, with little or no visitor access. Visitor satisfaction can be approached through studies in environmental perception. Such studies integrate work in psychology, philosophy, and geography. This author sought to determine whether or not more precise information about the perceptual basis for visitor satisfaction in a natural area could be obtained through survey research. Bandelier National Monument served as a useful laboratory for carrying out this research.

Data collection was by a survey technique. A detailed questionnaire …

Geologic Factors Influencing Speleogenesis In The Capitan Reef Complex, New Mexico And Texas, David Henry Jagnow

Earth and Planetary Sciences ETDs

The purpose of this thesis is to determine the geologic factors that have influenced speleogenesis (origin of caves) in the Capitan reef complex (Permian) exposed along the northeast prong of the Guadalupe Mountains of New Mexico and Texas. This study of 52 caves included mapping caves, joints, and cross sections, determining stratigraphic position, generating joint rose diagrams, and photographing the geologic and hydrologic controls on speleogenesis.

Most Guadalupe caves are strongly controlled by vertical joints that parallel or are nearly perpendicular to the reef escarpment. East of Rattlesnake Canyon, caves generally develop along joint swarms that parallel the reef escarpment; …