Physical Sciences and Mathematics Commons^™

The Soundscape Of The Grove: The Acoustic Environment Of A Visual Landmark, Bryce Barrett

Honors Theses

The objective of this project was to evaluate the soundscape throughout the Grove and the Circle (two popular outdoor spaces on the University of Mississippi campus) by determining the sound levels and people’s perceptions of sounds. The term soundscape is defined by a person’s perception of an acoustic environment in context. The human perceptions of sounds were gathered during soundwalks, which are walking tours of a given environment where participants provide opinions on their acoustic surroundings. Five soundwalk sessions were conducted with a total of 10 participants with varying environmental conditions. Statistically significant variations in perceptions and sound levels …

Investigating The Effects Of Suspended Algal Content, Dissolved Oxygen, And Temperature On A High-Frequency Acoustic Attenuation System In A Controlled Laboratory Environment, Noah Watson

Honors Theses

The Single Frequency Acoustic Attenuation System (SFAAS) has been developed at the National Center for Physical Acoustics (NCPA). This system uses acoustic methods to monitor fine suspended sediment concentration in streams. Site-specific calibrations are necessary for this system, and previous research has indicated that algal concentration or dissolved oxygen concentration of water may affect collected data. Temperature, dissolved oxygen concentration, and fluorescence, used as a proxy for algal concentration, were monitored during this system’s use, and calibrations were derived to account for the effect of each of these variables on acoustic measurements. It has been shown that temperature has a …

Timber And Tornadoes: A Journalistic View Of Mississippi's Escalating Climate Challenge, Alice Ann Hollingsworth, Alice Ann Hollingsworth

Honors Theses

Timber and Tornadoes: A Journalistic View of Mississippi’s Escalating Climate Challenges is a project which explores the impact of climate change on the state of Mississippi and its industries. Specific areas of interest were the recent onslaught of wind disasters including tornadic activity and hurricanes as well as the impact of weather events on the timber and forestry industries in the state. This project involved interviews of industry professionals as well as academic experts. In addition, interview questions and necessary supplemental context were developed using significant background research. Emphasizing the potential challenges that climate change will present for the state …

Climate Change In Mississippi: A Journalistic Exploration Of Education And Activism, Kala Nance

Honors Theses

Climate Change in Mississippi: A Journalistic Exploration of Education and Activism takes an investigative, journalistic approach toward climate change in Mississippi. Specifically, how education and awareness have a direct impact on Mississippi industries, people and legislation. The project explored the level of acknowledgement of climate change across the state, and how certain individuals used advocacy to encourage education about climate change to raise awareness of the severity of the situation. This project includes interviews with university professors and researchers, non-profit organizations, educational groups and working individuals in some of Mississippi’s largest areas of employment. Additionally, this project draws on research …

Manipulative, Dark, And Unethical Design Practices In Ui & Ux Design, Ryan Edward Brown

Honors Theses

This thesis examines the pervasive and detrimental effects of manipulative user interface and user experience design (UI/UX) practices on individuals and society. Focusing on three critical areas – accessibility, dark patterns, and polarization – the study employs a mixed-methods approach, combining findings from a comprehensive literature review, an analysis of specific design patterns and methods, and a survey of user experiences.
The literature review covers topics such as the importance of accessibility in design education, the prevalence of dark patterns in mobile and desktop sites, the role of personalization algorithms in shaping user experiences, and the formation of echo chambers …

A Comparison Of Assessment Experiences Between Standards-Based Practices And Traditional Practices Within Secondary Mathematics Classrooms, Emily Mayes

Honors Theses

The purpose of this research was to compare assessment experiences and find ways to improve those experiences for students in two mathematics classrooms: one classroom that employs Standards-Based Grading and one classroom that uses traditional grading practices. The research examines students’ perceptions regarding their level of preparation, their anxiety levels surrounding assessment, the validity of assessments, and using assessments and grading practices to give accurate indications of student progress in their learning, given the students’ perceptions. Students in both settings voluntarily and anonymously participated in completing pre- and post-assessment free-response surveys which asked questions about students’ assessment experiences. This research …

Theoretical Spectroscopic Predictions Of Electronically Excited States, Noah R. Garrett

Honors Theses

The quest for faster computation of anharmonic vibrational frequencies of both ground and excited electronic states has led to combining coupled cluster theory harmonic force constants with density functional theory (DFT) cubic and quartic force constants for defining a quartic force field (QFF) utilized in conjunction with vibrational perturbation theory at second order (VPT2). This work shows that explicitly correlated coupled cluster theory at the singles, doubles, and perturbative triples level [CCSD(T)-F12] provides accurate anharmonic vibrational frequencies and rotational constants when conjoined with any of B3LYP, CAM-B3LYP, BHandHLYP, PBE0, and ωB97XD for roughly one-quarter of the computational time of the …

Synthesis And Analysis Of A Novel Magnetic Surfactant, Donovan Turpin

Honors Theses

Researchers in the University of Mississippi Chemical Engineering Department have suggested that chelation of a large magnetic transition metal, namely dysprosium, into the large polar head group of a surfactant could result in a magnetic surfactant. This project was aimed at synthesizing a surfactant with a large enough head group and negative charge (specifically EDTA) to support this ion and demonstrating that the chelation process was successful. If so, the molecule would ideally be capable of forming micelles which could extract oily substances from water using a strong magnet—possibly applicable to environmental crises like oil spills.

NMR analysis has suggested, …

Methods For Computing Rovibrational Spectral Data With Applications To Inorganic Oxides And Hydrocarbons, Alexandria Watrous

Honors Theses

Computational chemistry focuses on finding solutions to the time-independent Schrödinger equation for systems of interest to study their molecular properties such as rovibrational spectral data. Any molecule containing more than one electron cannot be solved explicitly but coupled cluster theory offers one of the best approximations. One such application of this method is to molecules of astrochemical interest to support observation and experimental data. Chapters 2, 3, and 4 look at the performance of new couple cluster theory methods including composite and hybrid methods for ground and excited state rovibrational data. Chapters 5 - 9 use the previously mentioned methods …

Privacy Within Autonomous Vehicle Cameras, Joshua Montgomery

Honors Theses

In recent years, cameras have become ubiquitous in daily life, constantly surveilling, and taking in information. This leads to a potential security risk of the invasion in one’s privacy without their knowledge or any ability to prevent the privacy threat. While cameras alone are an issue, they are often only in locations where a user has some expectation of a loss of privacy, such as public locations with security systems. However, systems that rely on cameras to operate correctly, including autonomous vehicles, are becoming a more prominently used technology while often appearing in places where an average person has some …

Photophysical And Photochemical Processes In Small Molecules And Materials For Solar Energy Conversion, Ethan Lambert

Honors Theses

The work covered in this thesis all falls under the theme of photophysical processes after light and matter interact. Those of primary interest are Raman scattering induced vibrations and excited state dynamics probed by transient absorption spectroscopy. Small molecules are studied with Raman spectroscopy and computational chemistry. These studies unearth the shifts in vibrational frequency as a function of charge transfer or receipt and how a quantitative assay of natural orbital populations and delocalization can offer both the nature and magnitude of this charge transfer. Further, a method is presented that builds upon previous work within the academic family tree; …

Photocatalyzed Hydrogen Evolution Using Nickel-Bound Metallothionein Protein, Windfield Swetman

Honors Theses

The continued burning of fossil fuels is not only a cause of increasing deterioration of the environment but also a financially unsustainable source of energy. Advances in energy production must be investigated to avoid the long-term effects of this current main source of energy. One of the avenues being explored is the use of metalloenzymes to catalyze hydrogen evolution via water splitting that occurs during the reductive half of artificial photosynthesis. Metalloenzyme catalysts with a single Ni(Cys)₄ active site have been previously studied, and this study explores the possibility of increasing hydrogen production by using metalloenzyme catalysts with multiple …

A Study Of Data/Monte Carlo Agreement In Charmed Baryon Decays At Belle Ii, Kaitlyn Thurmond

Honors Theses

The Belle II experiment at the SuperKEKB electron-positron accelerator facility in Tsukuba, Japan has a primary goal of searching for new physics beyond the Standard Model of particle physics. Extremely precise measurements of particle decays will be compared with Standard Model predictions in order to expose the presence of new particles and interactions. These measurements are prepared using simulated samples to avoid potential biases when studying the data. The Belle II collaboration produces two types of simulated samples for this purpose. One is produced with consistent calibration payloads and another with payloads calibrated as a function of data taking. This …

Investigating Reactivity Of Artificial Copper Peptides With Small Molecules, Allyson Bryant

Honors Theses

The design of artificial enzymes has been a topic of significant interest in the field of biochemistry, as they can provide new opportunities for catalytic processes and drug development. De novo protein design has emerged as a promising approach to create such enzymes, and the study of metalloproteins, particularly copper-binding peptides, has become a focus of this research. This thesis investigates the reactivity of a mutated copper-binding peptide, I5A-3SCC, with oxygen and its implications in the development of artificial enzymes.

The parent peptide, 3SCC, was mutated by replacing Isoleucine residues with smaller Alanine side chains, which was hypothesized to enhance …

Aging An Ancient Maya Population From Actuncan, Belize Using Dental X-Rays, Kaitlyn Nicole Cash

Honors Theses

My goal is to determine an accurate age at death estimation of an ancient Maya population from the archaeological site of Actuncan, Belize. This was done by measuring the lengths of the coronal pulp cavities in the individuals’ teeth. I used X-Ray images to measure the coronal pulp cavities of the teeth and estimated age using multiple regression formulae for premolars, molars, and incisors to make age estimations. The formulae came from two studies, Ikeda et al. (1985) and Drusini (2008), that form the basis of my research. Ikeda et al. (1985) was the first to use this aging method, …

Structural Integrity And Stability Of Dna In Ionic Liquid And Near-Infrared Indolizine Squaraine Dye, Ember Yeji Suh

Honors Theses

Luminol, the most common presumptive test for blood at a crime scene, has multiple issues, such as false positive results with chemical agents, no luminescence due to “active oxygen” cleaning agents on bloodstains, and inability to penetrate textile materials. A combination of indolizine squaraine dye and ionic liquid (IL), or Dye Enhanced Textile Emission for Crime Tracking (DETECT), have shown potential to address these issues. The purpose of this study was to assess the binding mechanism of CG (1:1) and SO₃SQ dye to HSA and how the mechanism can explain the W214 fluorescence quenching effect and to determine …

A Camera Trap Study Of Scavenger Species On The University Of Mississippi Campus, Lise Larsen

Honors Theses

This is a camera trap study to understand what kind of mammalian scavenger community we have on the University of Mississippi campus and where they are most prominent. Three motion-triggered cameras were used to survey ten buildings on campus over ten weeks. A low number of individuals were caught on camera during this study. There were limitations on this study such as a low number of cameras and a short span of time. More research needs to be done to understand the scavenger community on this campus.

Identifying Key Activity Indicators In Rats' Neuronal Data Using Lasso Regularized Logistic Regression, Avery Woods

Honors Theses

This thesis aims to identify timestamps of rats’ neuronal activity that best determine behavior using a machine learning model. Neuronal data is a complex and high-dimensional dataset, and identifying the most informative features is crucial for understanding the underlying neuronal processes. The Lasso regularization technique is employed to select the most relevant features of the data to the model’s prediction. The results of this study provide insights into the key activity indicators that are associated with specific behaviors or cognitive processes in rats, as well as the effect that stress can have on neuronal activity and behavior. Ultimately, it was …

An Analysis Of Detection Asymmetry Using Baryon Decays In Belle Ii, Matthew Mestayer

Honors Theses

The purpose of this study was to determine the detection asymmetry of the Belle II detector using decays of two common baryons, Λ⁰ → ��π^- and Σ⁺ → ��π⁰. A Monte Carlo simulation of both decays was used to determine the validity of signal isolation criteria. These criteria were then applied to the Belle II data, allowing for a comparison of the detection asymmetry in the data relative to the simulation. The results show a moderate detection asymmetry when using the Λ⁰ → ��π^- decay, particularly for forward-going baryons. For the Σ^{+ …}

Exploration Of Feature Selection Techniques In Machine Learning Models On Hptlc Images For Rule Extraction, Bozidar-Brannan Kovachev

Honors Theses

Research related to Biology often utilizes machine learning models that are ultimately uninterpretable by the researcher. It would be helpful if researchers could leverage the same computing power but instead gain specific insight into decision-making to gain a deeper understanding of their domain knowledge. This paper seeks to select features and derive rules from a machine learning classification problem in biochemistry. The specific point of interest is five species of Glycyrrhiza, or Licorice, and the ability to classify them using High-Performance Thin Layer Chromatography (HPTLC) images. These images were taken using HPTLC methods under varying conditions to provide eight …

Imperfect Immunity And The Stability Of A Modified Kermack-Mckendrick Model, Kaylee Sims

Honors Theses

The classic Kermack-McKendrick model of mathematical epidemiology suggests that a population is only in equilibrium when there is no disease present. In the modern era, we have several cyclic infectious diseases that show no signs of eradication, despite global health measures. In this thesis, we introduce a coefficient of waning immunity in order to produce a modified Kermack-McKendrick model and analyze whether the model yields system stability with a certain amount of infection present. Ultimately, the model is incongruent with real-world case data, with its most glaring failure being exponential dampening of the height of each disease case peak due …

An Application Of The Pagerank Algorithm To Ncaa Football Team Rankings, Morgan Majors

Honors Theses

We investigate the use of Google’s PageRank algorithm to rank sports teams. The PageRank algorithm is used in web searches to return a list of the websites that are of most interest to the user. The structure of the NCAA FBS football schedule is used to construct a network with a similar structure to the world wide web. Parallels are drawn between pages that are linked in the world wide web with the results of a contest between two sports teams. The teams under consideration here are the members of the 2021 Football Bowl Subdivision. We achieve a total ordering …

Critically Observing The Challenges And Changes: An Analysis On Covid-19’S Impact With An Emphasis On Students In Higher Education, Landon Perkins

Honors Theses

This project involves comparing different visualizations related to COVID-19 and higher education in order to determine key impacts of the COVID-19 pandemic on students in higher education, as well as higher education as a whole. The main metrics used to determine the impact were mental health indicators for anxiety or depressive disorders, enrollment numbers by control type (public, private non-profit, or private for-profit) and state for 2020 and 2021, and state mandate lift dates for a variety of mandates implemented across the United States. These metrics were analyzed both individually and against each other to determine if they had any …

Improving Adjacency List Storage Methods For Polypeptide Similarity Analysis, Arianna Swensen

Honors Theses

Protein design is a complex biomolecular and computational problem. Working on increasingly large protein folding problems requires an improvement in current analysis methods available. This work first discusses various methods of protein design, including de novo protein design, which is the primary focus of this thesis. Then, a new approach utilizing a B+ tree to effectively store and query a graph of keys and vertices is proposed in order to store the number of times two polypeptides are considered to be similar. This approach is found to have a reduction in time complexity from current mapping methods and thus provides …

A Study Of Cannabigerolic Acid And Its Derivatives Via Raman Spectroscopy And Density Functional Theory, Trevor Wolfe

Honors Theses

The cannabinoids are a class of molecules endogenous to the cannabis plant. Their scientific relevance has increased in recent years due to the mercurial legal status of marijuana across the United States. Some of the most known are cannabidiol (CBD), δ9-tetrahydrocannabinol (δ9-THC), and δ8-THC due in large part to their widespread use, especially in states where marijuana and related products are legal. However, cannabigerolic acid (CBGA) is arguably the most important cannabinoid; it is enzymatically converted into other acidic cannabinoids, which subsequently undergo non-enzymatic processes (isomerization, thermal decarboxylation, oxidation, etc.) to synthesize further cannabinoids. Although there is a wealth of …

A Performance Analysis Of The Belle Ii Detector, John Stacy

Honors Theses

The Belle II experiment has recently (2018) started data taking at the SuperKEKB electron-positron collider in Tsukuba, Japan. Detector performance studies are necessary to understand early data and prepare for more complex analyses. This study of the proton detection efficiency of the Belle II detector compares real and simulated data to find discrepancies with the intention to provide useful information for detector and calibration experts to better gauge detector performance. It also attempts to improve the characterization of proton identification efficiency at low momenta, which performs poorly under the current fitting model. This helps analysts exploring final states that include …

Lifetime Measurement Of The Xi_C^+ Using Belle Ii Monte Carlo, Paul Gebeline

Honors Theses

This analysis uses simulated data from the Belle II experiment to measure the lifetime of the Xi_c^+ baryon. Three different decay modes are investigated to explore the feasibility and accuracy of such measurements at Belle II. The Xi_c^+ lifetime is measured using one of these modes after reducing backgrounds from sources other than the decay of interest. The final result is 464 +/- 15 fs, which is consistent with the expected result of 442 fs within uncertainty. This result shows that Belle II can make competitive measurements of particle properties and decays.

Synthetic Investigations In Chemical Probe Development Part 1: Design And Synthesis Of Novel Triton X-405 Adenosine Conjugates; Part 2: Synthesis Of 2,8-Dihydroxychrysene, Rachel Irene Hammond

Honors Theses

Although not drugs themselves, chemical probes are a necessary tool in biomedical research for the interrogation of biological systems. In the present synthetic investigation, two chemical probes were developed – a Triton X-405 adenosine conjugate (TX-405A) and 2,8-dihydroxychrysene. The designed TX-405A conjugate was generated in four steps through tosylation and amination of TX-405 such that EDC-coupling of TX-amine with 2’,3’-Isopropylidene adenosine-5’-carboxylic acid afforded TX-405A following acetonide deprotection. The development of TX-405A represents the first report of the synthesis and utilization of a detergent-linked dosimeter. The synthesis of 2,8-dihydroxychrysene provided an in-depth exploration on the unique reactivity of chrysene. The desired …

Ab Initio Study Of The Rotation Of The C≡C Group In Benzvalyne, Advait Praveen

Honors Theses

For benzvalyne, we have characterized the minima and transition states of the molecule using the B3LYP, MP2, and M06-2X methods and aug-cc-pVTZ basis set. This was done by calculating the energy of the molecule while rotating the alkyne bond contained within it. After the initial rotation, optimized parameters for the molecule are found. Following this, imaginary frequencies were attempted to be found at the local maximum produced by the graph of the Energy v. rotation angle. Should the negative frequencies be found, the energy of the molecule will be characterized by the CCSD (T) method and aug-cc-pVQZ basis sets. This …

Lc-Ms Identification Of Serum Proteins Adsorbed Onto Ionic Liquid-Coated Nanoparticles, Anh M. Hoang

Honors Theses

Nanocarriers are promising candidates for drug delivery due to their size and tunable surface characteristics. However, when they are intravenously injected, few particles make it to their designated location. This is because upon entering the bloodstream, the serum in the blood, which is rich with a diversity of proteins, adsorbs onto the particles’ surfaces forming a protein corona. Many of the attached proteins trigger the mobile immune system and are removed by macrophages, and many particles are then filtered out by the liver and kidneys. Ionic Liquids (ILs), which consist of asymmetric, bulky components that are liquid