Physical Sciences and Mathematics Commons^™

A Reliability-Based Routing Protocol For Vehicular Ad-Hoc Networks, James Bernsen

University of Kentucky Master's Theses

Vehicular Ad hoc NETworks (VANETs), an emerging technology, would allow vehicles to form a self-organized network without the aid of a permanent infrastructure. As a prerequisite to communication in VANETs, an efficient route between communicating nodes in the network must be established, and the routing protocol must adapt to the rapidly changing topology of vehicles in motion. This is one of the goals of VANET routing protocols. In this thesis, we present an efficient routing protocol for VANETs, called the Reliable Inter-VEhicular Routing (RIVER) protocol. RIVER utilizes an undirected graph that represents the surrounding street layout where the vertices of …

New Photovoltaic Acceptors: Synthesis And Characterization Of Functionalized C-Fused Anthradithiophene Quinones, Kerri Shelton

University of Kentucky Master's Theses

Stable organic semiconductors are critical to produce inexpensive, efficient and flexible thin film organic solar cells. A current chemical focus is the synthesis of stable, electron-accepting materials to be utilized as an acceptor layer in photovoltaics.¹ The Anthony group has shown that the functionalization of pentacene with suitable electron withdrawing groups provides a catalog of suitable acceptors for this purpose.² These pentacenes can be further modified to pack in a unique 1-dimensional "sandwich herringbone" crystal packing, leading to improved device current.³ To improve the stability of acene acceptors, we have taken two hetero-atom themed approaches. First, we …

Development Of Novel Electrophilic Ruthenium(Ii) And Iridium(Iii) Complexes And Their Applications As Homogeneous Catalysts, Ryan R. Ketcham

University of Kentucky Master's Theses

Our aim was to develop the synthetic potential and reaction chemistry of Ir³⁺ and Ru²⁺ electrophiles by preparing well-characterized complexes whose properties are controllable by modification of the ancillary ligand environment Specifically, we prepared a series of ruthenium complexes to serve as selective hydrogenation and hydrogenolysis catalysts of furan derivatives. We also expanded the synthesis of electrophilic Ir³⁺ di-thiolate complexes. These types of compounds could eventually serve as catalysts precursors for the addition of weak nucleophiles to alkynes and nitriles.

Conceptualizing And Improving Red Wine Grape Cultivars Grown In Kentucky, Matthew Simson

University of Kentucky Master's Theses

Wine sensory attributes are associated with quality of wines. Cabernet Franc did not possess good coloration of its wine. Therefore, in the 2009 and 2010 growing seasons, studies including the sampling of four red wine grape cultivars from the end of flowering throughout the rest of the season and applying treatments to Cabernet Franc grapevines at veraison were commenced to address suitability and color enhancement, respectively. The study examining Cabernet Franc, Cabernet Sauvignon, Chambourcin, and Norton looked at sampling their grapes at two-week intervals from times post-flowering to understand the demands of each cultivar during key stages of berry development, …

Investigation Of The Toxicity And Efflux Of Polychlorinated Biphenyls And Hydroxylated Polychlorinated Biphenyls In Escherichia Coli, Shen Geng

University of Kentucky Master's Theses

Polychlorinated biphenyls (PCBs) are persistent organic pollutants. Due to their properties, PCBs accumulate in the food-chain and post a threat to the health of human beings and wildlife. Hydroxylated PCBs (OH-PCBs) are oxidative metabolites of PCBs and are more hydrophilic than their parent PCBs. One of the best approaches to break down these contaminants is through bioremediation, which is an environmental friendly process that uses microorganisms to restore natural environment.

Towards this goal, we have investigated the toxicity and accumulation of PCBs and OH-PCBs in a Gram-negative bacterium, Escherichia coli. We have also determined the role played by a …

Cluster-Based Term Weighting And Document Ranking Models, Keerthiram Murugesan

University of Kentucky Master's Theses

A term weighting scheme measures the importance of a term in a collection. A document ranking model uses these term weights to find the rank or score of a document in a collection. We present a series of cluster-based term weighting and document ranking models based on the TF-IDF and Okapi BM25 models. These term weighting and document ranking models update the inter-cluster and intra-cluster frequency components based on the generated clusters. These inter-cluster and intra-cluster frequency components are used for weighting the importance of a term in addition to the term and document frequency components. In this thesis, we …

Fate Of Stable Isotope Label During Predation Of 15N-Tagged Wild-Type Escherichia Coli By Protozoa, Ashley M. Barton

University of Kentucky Master's Theses

Currently, bacterial movement in karst aquifers is not well understood. Use of stable isotopes to label non-pathogenic Escherichia coli as a particulate groundwater tracer in karst systems has been examined in previous studies. Loss of the stable isotope signal is anticipated in traces greater than 500 m in length. Potential loss of ¹⁵N due to predation by protozoa was examined. Filter-sterilized water from Royal Spring in Georgetown, Kentucky, was inoculated with a mixture of either Tetrahymena pyriformis or Colpoda steinii and ¹⁵N-enriched E. coli and stored in the dark at 14°C. Samples were analyzed for their nitrogen isotope …

Determining Interstellar Reddening: A New Approach Using Spectroscopy And Photometry, Syed A. Uddin

University of Kentucky Master's Theses

The mystery of Canis Major overdensity is addressed. We discuss concurrent methods and their limitations on the determination of interstellar reddening. We establish a new way to determine line of sight interstellear reddening by observing stellar spectral lines and UBV colors. We observe and analyze spectra of 22 stars in different open clusters. We find that Hydrogen Balmer line at 4861 angstrom can predict the stellar atmospheric parameters and intrinsic colors with reasonable accuracy. Comparing with observed colors we derive the reddening of the stars. We compare our results with standard database WEBDA and find that within 90% probability limit …

A Classification Of Lower Paleozoic Carbonate-Bearing Rocks For Geotechnical Applications, Bethany L. Overfield

University of Kentucky Master's Theses

An empirically-based classification of lower Paleozoic carbonate-bearing rocks was created for field-based geotechnical applications. Geotechnical parameters were subsequently correlated to that classification. Seven hundred seventy-seven samples were used as the basis for the classification. Thirteen categories based on visual and tactile properties and a hydrochloric acid test were created. Samples were from central, north-central, and south-central Kentucky and represented the majority of Ordovician exposures in the state, and some Mississippian exposures. Few Silurian and Devonian units were included in the sample set. Geotechnical parameters, including density as well as elastic constants (shear and compression wave velocities, Poisson’s ratio, Young’s modulus, …

Physical Conditions In A Galactic Star Forming Region W22, Akshaya Rane

University of Kentucky Master's Theses

This document describes study of an active star forming region in our galaxy (the Milky Way) known as W22. Physical conditions in these regions can help us in understanding star formation processes in the universe and hence the structure and evolution of the universe. Zeeman effect measurements in 18 cm OH absorption line were carried out in order to estimate the line of sight magnetic field strength in the molecular cloud associated with this star forming region. Other physical parameters such as hydrogen column density, optical depth, critical magnetic field were also determined from these measurements. The region was mapped …

Stability Of Spore-Based Sensing Systems, Abhishek Sangal

University of Kentucky Master's Theses

The full exploitation of bacterial whole-cell biosensing systems in field applications requires the survival of bacterial cells and long term-preservation of their sensing ability during transportation and on-site storage of such analytical systems. Specifically, there is a need for rapid, simple and inexpensive biosensing systems for monitoring human health and the environment in remote areas which often suffer from harsh atmospheric conditions and inadequate commercial distribution and storage facilities. Our laboratory has previously reported the successful use of bacterial spores as vehicles for the long-term preservation and storage of whole-cell biosensing systems at room temperature.

In the present research, we …

Tectonic Controls On Lower Devonian Sandstone Distribution, Alabama, Michael P. Solis

University of Kentucky Master's Theses

The Devonian Frog Mountain Formation thickens abruptly eastward across the Eastern Coosa thrust fault from <12 m on the west to>70 m on the east. The thin Frog Mountain on the west unconformably overlies the Cambrian-Ordovician Knox Group. The thin Frog Mountain (mostly shale) is overlain by the Mississippian Maury Shale (~1 m thick) and Fort Payne Chert (~50 m thick). The thick Frog Mountain on the east rests on the Middle Ordovician Athens Shale, a black shale >150 m thick. The Athens overlies the Knox Group. The thick Frog Mountain is nearly all sandstone and is overlain by Fort Payne Chert which is only …

Functionalization Of Multi-Walled Carbon Nanotubes And The Interactions Of Multi-Walled Carbon Nanotubes In Epoxy Composites, Christopher Fitzwater

University of Kentucky Master's Theses

Multi-walled carbon nanotubes (MWNTs) are a relatively new allotrope of carbon that have potentially useful properties that may improve polymer composites. The work of this thesis explores the interactions between MWNTs and functionalized MWNTs within epoxy matrix and the properties of the MWNT/epoxy composite. These interactions were characterized with an emphasis on finding how well the MWNT/epoxy composite flows and how conductive it is after curing.

Origin Of Blue Ridge Basement Rocks, Dellwood Quad, Western Nc: New Evidence From U-Pb Zircon Geochronology And Whole Rock Geochemistry, Donald Franklin Loughry Jr.

University of Kentucky Master's Theses

Terrane discrimination in polycyclic continental basement rocks is challenging due to high-grade metamorphism and intense deformation. Based on early USGS mapping the Blue Ridge basement in the Dellwood quadrangle of the eastern Great Smoky Mountains was proposed to consist of augen orthogneisses of Laurentian (Grenvillian) affinity interfolded with migmatitic hornblende and biotite paragneisses (“Carolina Gneiss”) and amphibolites of uncertain affinity. However, detailed study reveals that the hornblende gneiss of Hadley and Goldsmith (1963) is a heterogeneous map unit consisting of (1)metaplutonic rocks; (2) variably foliated and folded felsic orthogneisses; (3) strongly migmatitic, folded Hbl+Bt-bearing gneisses; (4) foliated and lineated garnet …

Synthesis, Characterization And Development Of Catalysts For Co2 Capture, Anitha Suhas Wishrojwar

University of Kentucky Master's Theses

Fossil fuel and advanced industrialization techniques contribute to global warming through emissions of greenhouse gases such as CO₂. In order to mitigate climate change, there is a desperate need to reduce CO₂ emissions from different sources. CO₂ capture and sequestration (CCS) play an important role in these reductions.

Naturally occurring enzymes, e.g., carbonic anhydrase (CA), can catalyze these reactions in living systems. Much effort has been focused on complexes of zinc with ligands such as teta, cyclen and tripodal ligands including BIMA and Trispyrazolylborates. These complexes have many interesting CO₂ capture properties, but maintain toxic …

Effects Of Livestock Antibiotics On Nitrification, Denitrification, And Microbial Community Compositon In Soils Along A Topographic Gradient, Sagarika Banerjee

University of Kentucky Master's Theses

Several types of antibiotics (roxarsone, virginiamycin, and bacitracin) are widely included in poultry feed to improve animal growth yields. Most of the antibiotics are excreted in manure which is subsequently applied to soils. One concern with this practice is that antibiotics may affect several microbially-mediated nutrient cycling reactions in soils that influence crop productivity and water quality. The main objectives of this study were to determine the effects of livestock antibiotics on nitrification, denitrification, and microbial community composition in soils along a topographic gradient. These objectives were addressed in a series of lab experiments by monitoring changes in inorganic N …

Feasibility Of Using 15N-Enriched Escherichia Coli As A Bacterial Tracer In The Cane Run/Royal Spring Basin, Kentucky, John G. Warden

University of Kentucky Master's Theses

A novel tracer method has used ¹⁵N to label Escherichia coli and track the transport of bacteria, a common contaminant, through karst aquifers. Use of this method could provide valuable insight into the movement of bacteria in aquifers, which would help improve remediation methods and strategies. A wild strain of E. coli was isolated from the Cane Run/Royal Spring basin in the Inner Bluegrass region of Kentucky. The strain was serotyped O^-:H^- and virulence testing showed the strain did not have virulence factors of E. coli commonly pathogenic to humans. Five karst microcosms were filled with …

Chromium, Copper, And Arsenic Concentration And Speciation In Soil Adjacent To Chromated Copper Arsenate (Cca) Treated Lumber Along A Topohydrosequence, Donald Roy Schwer Iii

University of Kentucky Master's Theses

Arsenic (As), Chromium (Cr), and Copper (Cu) are ubiquitous in soils as a result of anthropogenic and geogenic processes. The fate of As, Cr, and Cu in the environment is largely governed by their speciation, which is influenced by soil physiochemical properties. This study investigated the influence of soil physiochemical properties and landscape position on As, Cr, and Cu concentration and speciation in soils adjacent to Chromated Copper Arsenate (CCA) treated lumber fence posts. Concentration gradients showed elevated total As and Cu adjacent to the three fence posts, which decreased with increasing distance from the posts. In addition, As and …

A Trusted Storage System For The Cloud, Sushama Karumanchi

University of Kentucky Master's Theses

Data stored in third party storage systems like the cloud might not be secure since confidentiality and integrity of data are not guaranteed. Though cloud computing provides cost-effective storage services, it is a third party service and so, a client cannot trust the cloud service provider to store its data securely within the cloud. Hence, many organizations and users may not be willing to use the cloud services to store their data in the cloud until certain security guarantees are made. In this thesis, a solution to the problem of securely storing the client’s data by maintaining the confidentiality and …

The No. 5 Block In Eastern Kentucky: A Critical Re-Examination Of The Petrology With Special Attention To The Origin Of Inertinite Macerals In The Splint Lithotypes, Allison Ranae Richardson

University of Kentucky Master's Theses

Microbes, including fungi and bacteria, and insects are responsible for the consumption and subsequent degradation of plant materials into humus. These microbes directly and indirectly affect the physical and chemical characteristics of coal macerals. Efforts to understand and determine the origins of inertinite macerals are largely misrepresented in the literature, conforming to a single origin of fire. This study focuses on the variability of physical and inferred chemical differences observed petrographically between the different inertinite macerals and discusses the multiple pathways plant material may take to form and or degrade these macerals.

Petrographic results show that fungal activity plays a …

Latest Quaternary Paleoclimate Reconstruction Utilizing Stable Isotopic And Trace Element Proxies In A Stalagmite From Culverson Creek Cave, West Virginia, Ashley Nicole Gilbert

University of Kentucky Master's Theses

A reconstruction of regional climate variability in southern West Virginia that spans the last glacial/interglacial transition is presented. Paleoclimate interpretations obtained from the 50-cm long stalagmite provide key insights regarding the timing, magnitude, and forcing mechanisms responsible for past climate variability. Stable isotopic (δ¹⁸O and δ¹³C) and trace element (Ba, Sr, Mg) signatures from samples contiguously milled along the growth-axis of a ²³⁰Th-dated stalagmite which grew between approximately 20 and 5 thousand years before present (kyr BP) provide critical constraints for above-cave mean annual temperature, seasonality of moisture mean annual precipitation, and potential vegetation shifts. …

Non-Portland Cement Activation Of Blast Furnace Slag, Anne Elizabeth Oberlink

University of Kentucky Master's Theses

The purpose of this project was to produce a “greener” cement from granulated ground blast furnace slag (GGBS) using non-Portland cement activation. By eventually developing “greener” cement, the ultimate goal of this research project would be to reduce the amount of Portland cement used in concrete, therefore reducing the amount of carbon dioxide emitted into the atmosphere during cement production.

This research studies the behavior of mineral binders that do not contain Portland cement but instead comprise GGBS activated by calcium compounds or fluidized bed combustion (FBC) bottom ash. The information described in this paper was collected from experiments including …

Hydraulic Geometry Relationships And Regional Curves For The Inner And Outer Bluegrass Regions Of Kentucky, Ruth Roseann Brockman

University of Kentucky Master's Theses

Hydraulic geometry relationships and regional curves are used in natural channel design to assist engineers, biologists, and fluvial geomorphologists in the efforts undertaken to ameliorate previous activities that have diminished, impaired or destroyed the structure and function of stream systems. Bankfull channel characteristics were assessed for 14 United States Geological Survey (USGS) gaged sites in the Inner Bluegrass and 15 USGS gaged sites in the Outer Bluegrass Regions of Kentucky. Hydraulic geometry relationships and regional curves were developed for the aforementioned regions.

Analysis of the regression relationships showed that bankfull discharge is a good explanatory variable for bankfull parameters such …

3d Reconstruction Using Multi-View Imaging System, Conglin Huang

University of Kentucky Master's Theses

This thesis presents a new system that reconstructs the 3D representation of dental casts. To maintain the integrity of the 3D representation, a standard model is built to cover the blind spots that the camera cannot reach. The standard model is obtained by scanning a real human mouth model with a laser scanner. Then the model is simplified by an algorithm which is based on iterative contraction of vertex pairs. The simplified standard model uses a local parametrization method to obtain the curvature information. The system uses a digital camera and a square tube mirror in front of the camera …

Use Of Surface Geophysical Techniques To Locate A Karst Conduit In The Cane Run - Royal Spring Basin, Kentucky, Ganesh N. Tripathi

University of Kentucky Master's Theses

Groundwater flow in karst terrains is difficult to map because it can be concentrated through conduits that do not necessarily coincide with the surface features. We applied electrical resistivity (ER) and self-potential (SP) techniques at three sites to locate an inferred trunk conduit feeding a major spring in the Inner Bluegrass region of Kentucky. Royal Spring is the primary water supply for the city of Georgetown; the upper part of its basin coincides with the Cane Run watershed. ER and SP profiles were perpendicular to the inferred trunk conduit orientation. ER profiles (972 m total length) were measured using a …

Bedrock Mapping Of The Winchendon (1:25,000) Quadrangle (Ma-Nh): Evidence For Discontinous Deformation Along The Bronson Hill-Central Maine Boundary Zone, Timothy M. O'Brien

University of Kentucky Master's Theses

Bedrock geology of the Winchendon quadrangle is divided into two zones based on structures and lithology. The eastern zone consists of tightly folded Silurian Rangeley and Paxton metasediments and pegmatites. Planar, NNE-SSW striking, W dipping foliations are characterized by alternating phyllosilicate-rich and leucosome layers. Fold axes of tight to isoclinal upright and recumbent folding are parallel to SSW-NNE shallowly plunging sillimanite, quartz and muscovite lineations. In the western zone Rangeley schists were intruded by Devonian Hardwick and Coys Hill and Fitzwilliam plutons. Planar NNE-SSW striking foliations dip shallowly to steeply west. Fold axes of tight-to-isoclinal asymmetric to recumbent folds plunge …

Structural Geology Of The Transylvania Fault Zone In Bedford County, Pennsylvania, Elizabeth Lauren Dodson

University of Kentucky Master's Theses

Transverse zones cross strike of thrust-belt structures as large-scale alignments of cross-strike structures. The Transylvania fault zone is a set of discontinuous right-lateral transverse faults striking at about 270º across Appalachian thrust-belt structures along 40º N latitude in Pennsylvania. Near Everett, Pennsylvania, the Breezewood fault terminates with the Ashcom thrust fault. The Everett Gap fault terminates westward with the Hartley thrust fault. Farther west, the Bedford fault extends westward to terminate against the Wills Mountain thrust fault. The rocks, deformed during the Alleghanian orogeny, are semi-independently deformed on opposite sides of the transverse fault, indicating fault movement during folding and …

Matrix Geochemistry And Phytophthora Occurrence On Reforested Mine Lands In Appalachia, Kathryn M. Ward

University of Kentucky Master's Theses

At the Bent Mountain surface mine, Pike County, Kentucky, a study has been ongoing since 2005 to assess the influence of various types of loose-graded mine spoils on water quality and forest establishment. Six research plots consist of two replicates of brown weathered sandstone, gray unweathered sandstone, and mixed brown sandstone, gray sandstone, and shale that were emplaced according to Forestry Reclamation Approach criteria. A series of analyses was initiated in 2007 to examine influence of spoil matrix composition on sulfate and carbonate geochemistry of infiltrated waters, as well as to investigate the occurrence of Phytophthora, a group of …

Variation In C/P Ratios In Devonian-Mississippian Marine Shales: Testing The Productivity-Anoxia Feedback Model, Brian T. Scott

University of Kentucky Master's Theses

Carbon/phosphorus ratios for late Devonian-early Mississippian marine black shales along a transect from the Illinois Basin, across the Cumberland Saddle, and into the Appalachian Basin were evaluated to assess the role of productivity in organic carbon accumulation. Phosphorus is a key limiting nutrient for biological productivity in marine environments and may be regenerated preferentially relative to organic carbon, the amount of regeneration possibly being related to bottom-water anoxia. A positive feed-back mechanism (more specifically, productivity-anoxia feedback or PAF) has been proposed between water-column anoxia, high benthic regeneration of phosphorus, and marine productivity. This regeneration of phosphorus under anoxic conditions and …

Integrated Geophysical Imaging Of Subsurface Geologic Conditions Across A Contaminant Plume, Mccracken County, Kentucky, Cora A. Blits

University of Kentucky Master's Theses

Over 7.8 km of seismic reflection data and 2 km of electrical resistivity data were acquired, processed, and interpreted during this multi-method geophysical study. Objectives included the definition of geologic conditions underlying a contaminant plume in McCracken County, western Kentucky, and the determination of the potential for structural control on the rate and direction of plume migration. Both geophysical methods indicate the presence of multiple high-angle normal faults outlining a series of asymmetric grabens ranging in width from 160 m to almost 300 m and striking between N40°E and N45°E. There was agreement between the two methods on fault location …