Physical Sciences and Mathematics Commons^™

Time Series Modeling To Ascertain Age In Fisheries Management, Kathleen Sue Kirch

OES Theses and Dissertations

The ability to assign accurate ages of fish is important to fisheries management. Accurate ageing allows for the most reliable age-based models to be used to support sustainability and maximize economic benefit. Structures used to age include bones, scales, and most commonly ear bones (otoliths). Assigning age relies on validating putative annual marks by evaluating accretional material laid down in patterns in fish otoliths, typically by marginal increment analysis. These patterns often take the shape of a sawtooth wave with an abrupt drop in accretion yearly to form an annual band and are typically validated qualitatively. Researchers have shown keen …

Longitudinal Solid Polarized Target For Clas12 And Study Of Spin Structure Of Nucleons, Pushpa Pandey

Physics Theses & Dissertations

A suite of experiments measuring target-spin observables in electron-nucleon scattering (dubbed Run Group C) was conducted at Jefferson Lab’s Hall B in Newport News, VA with a new polarized nuclear target known as ‘APOLLO’ (Ammonia Polarized Longitudinally). This innovative target is engineered to seamlessly integrate with the advanced 12 GeV CEBAF (Continuous Electron Beam Accelerator Facility) accelerator and the Hall B CLAS12 (12 GeV CEBAF Large Acceptance Spectrometer) detector array. The ‘APOLLO’ target harnesses the power of Dynamic Nuclear Polarization (DNP) to achieve longitudinal polarization of solid ammonia, thereby creating a net polarization in both protons (NH₃) and …

Development Of One And Two Current Transition Amplitudes With Two Body Final States, Keegan H. Sherman

Physics Theses & Dissertations

One of the biggest challenges facing modern day nuclear physics is understanding the structure of states within the hadronic spectrum of Quantum Chromodynamics (QCD). We have shown this spectrum to be quite rich with hundreds of allowed states; however, if we wish to better grasp the dynamics of QCD, then it is necessary that we start investigating the internal structure of these states. This may be done by probing these states with external currents, but this requires a description of the intersection of QCD with the electroweak sector. This work acts as a stepping stone in this direction. Working to …

Broadband Dielectric Spectroscopic Detection Of Volatile Organic Compounds With Zinc Oxide And Metal-Organic Frameworks As Solid-State Sensor Materials, Papa Kojo Amoah

Electrical & Computer Engineering Theses & Dissertations

The industrial revolution drove technological progress but also increased the release of harmful pollutants, posing significant risks to human health and the environment. Volatile organic compounds (VOCs), which have various anthropogenic and natural sources, are particularly concerning due to their impact on public health, especially in urban areas. Addressing these adverse effects requires comprehensive strategies for mitigation as traditional gas sensing techniques have limitations and there is a need for innovative approaches to VOC detection.

VOCs encompass a diverse group of chemicals with high volatility, emitted from various human activities and natural sources. These compounds play a crucial role in …

Dynamic Soil-Structure Response And Failure Of Wood Utility Poles Under Hurricane-Force Wind And Non-Linear Cable Loads, Ramani Ayakannu

Civil & Environmental Engineering Theses & Dissertations

This dissertation presents the outcome of a study of the dynamic soil-structure interaction response of tapered wood utility poles embedded in various foundation soils subject to quasi-static and dynamic wind loads. The study includes the effects of nonlinear soil behavior with varying quantities of moisture and nonlinear cable tension loads on a class H1 wood pole. The natural frequency response of the pole is determined using a finite element formulation. The dynamic response in the presence of wind-induced forcing function is studied using a SAP2000 finite element scheme with wind speeds up to 220 mph. The natural frequency of the …

Spectroscopy Of Atmospheres, Randika Dodangodage

Physics Theses & Dissertations

Spectroscopic methods are used to study planetary and stellar atmospheres. The information obtained from spectroscopic studies provides insight into atmospheric compositions and dynamics, which can be used to model and characterize atmospheres and climates. Laboratory-recorded absorption cross-sections are needed to interpret the recorded spectra of planets and stars. High resolution ethane, neopentane, propene, and n-butane spectra have been recorded, and absorption cross-sections have been provided for different temperatures and total pressures with different broadening gases, including hydrogen, helium, and nitrogen. The Atmospheric Chemistry Experiment (ACE) satellite orbits Earth and records spectra through solar occultation limb observations. HOCl is a chlorine …

Trust And Contexts: A Conceptual Framework For Understanding Coastal Household Preparedness, Ogechukwu M. Agim Nwandu-Vincent

School of Public Service Theses & Dissertations

Despite research findings that show the benefits of being prepared for increasingly tumultuous natural and coastal hazard events, studies on hazard preparedness indicate that low levels of preparedness may occur in vulnerable areas due to the uncertainty around hazard risks, expected hazard onset and impact strength, as well as associated effects. Study findings indicate that trust may impact the uncertainty and complexity faced by people dealing with unfamiliar, infrequent, and complex hazards, as well as contexts such as factors such as age, gender, prior hazard experience, and homeownership.

While studies have looked at the relationship between trust and compliance (desired …

Impact Of Climate Change On Carbon And Nitrogen Balance In Zostera Marina L. (Eelgrass), Malee Jinuntuya

OES Theses and Dissertations

Seagrasses face vulnerability to both global stressors like Ocean Acidification (OA) and climate warming compounded by local stressors such as eutrophication that reduces light availability, leading to a complex dynamic of positive and negative effect on their growth and survival. Increased dissolved aqueous CO₂ (CO_2(aq)) benefits seagrasses by enhancing photosynthetic and growth rates, but it may increase nutrient demand, potentially depleting nutrient supply, especially in oligotrophic environments.

In this study, the long-term impact of CO₂ on Zostera marina L. (eelgrass) were investigated across a gradient of CO_2(aq) concentrations (55 – 2200 µM CO_{2(aq)) …}

Exploring Cation Exchange: Unveiling Its Significance In Biochar And Bioenergetics Applications, Gyanendra Kharel

Chemistry & Biochemistry Theses & Dissertations

Cation exchange, a cornerstone of soil chemistry and nutrient cycling, is a fundamental chemical process that occurs in soils, sediments, membranes, and other solid materials. It involves the interchange of positively charged ions, or cations, between a solid matrix and a surrounding solution. This process is crucial in various natural and engineered systems, leading to a range of applications across different fields.

This dissertation presents an extensive investigation into the applications of cation exchange in the fields of biochar and bioenergetics, encompassing three distinct aims. The first aim concentrates on the surface oxygenation of biochar through ozonization, aiming to achieve …

Application Of The Fokker-Planck Equation For Quantifying Initial Condition Uncertainty Of Reversible Dynamic Systems, Troy S. Newhart

Mechanical & Aerospace Engineering Theses & Dissertations

Characterizing the behavior of dynamic systems requires the inclusion of initial conditions to propagate behavior forward in time. More realistic representations of system behavior quantify uncertainty about the initial conditions to assess sensitivity, reliability, and other stochastic response parameters. In many engineering applications, the uncertain initial conditions may be unknown given a desired response. This research applies the Fokker-Planck equation to reversible dynamic systems of select multi-dimensional nonlinear differential equations as a means for predicting the uncertainty about initial conditions. An alternating directions implicit numerical scheme is used to numerically solve the Fokker-Planck equation for both forward and reversed equations …

Computational Modeling And Analysis Of Facial Expressions And Gaze For Discovery Of Candidate Behavioral Biomarkers For Children And Young Adults With Autism Spectrum Disorder, Megan Anita Witherow

Electrical & Computer Engineering Theses & Dissertations

Facial expression production and perception in autism spectrum disorder (ASD) suggest the potential presence of behavioral biomarkers that may stratify individuals on the spectrum into prognostic or treatment subgroups. High-speed internet and the ease of technology have enabled remote, scalable, affordable, and timely access to medical care, such as measurements of ASDrelated behaviors in familiar environments to complement clinical observation. Machine and deep learning (DL)-based analysis of video tracking (VT) of expression production and eye tracking (ET) of expression perception may aid stratification biomarker discovery for children and young adults with ASD. However, there are open challenges in 1) facial …

Optics Studies For Multipass Energy Recovery At Cebaf: Er@Cebaf, Isurumali Neththikumara

Physics Theses & Dissertations

Energy recovery linacs (ERLs), focus on recycling the kinetic energy of electron beam for the purpose of accelerating a newly injected beam within the same accelerating structure. The rising developments in the super conducting radio frequency technology, ERL technology has achieved several noteworthy milestones over the past few decades. In year 2003, Jefferson Lab has successfully demonstrated a single pass energy recovery at the CEBAF accelerator. Furthermore, they conducted successful experiments with IR-FEL demo and upgrades, as well as the UV FEL driver. This multi-pass, multi-GeV range energy recovery demonstration proposed to be carried out at CEBAF accelerator at Jefferson …

Do Microplastics, Vibrio Bacteria, And Warming Water Temperatures Cause Disease In The Northern Star Coral, Astrangia Poculata?, Heather Leigh Sheffey

OES Theses and Dissertations

As marine plastic pollution increases, it becomes imperative to study the effects of microplastics on marine fauna. Marine plastic debris is a vector for disease to marine invertebrates (Lamb et al., 2018; Rotjan et al., 2019). In this context, studies have shown Astrangia poculata will consume microplastics as they do their normal food (Allen et al, 2017; Rotjan et al., 2019). Further, with temperatures increasing worldwide, there is a concern the virulence of disease-causing bacteria will increase (Vezzulli et al., 2015). In a series of manipulative laboratory experiments, this study quantified changes in respiration rates and visual health of Astrangia …

The Prevalence Of Burnout In Saudi Arabia Dental Hygienists, Nouf Hamad Aldayel

Dental Hygiene Theses & Dissertations

Purpose: The purpose of this pilot study was to assess the prevalence of burnout in Saudi Arabian dental hygienists and identify risk factors associated with burnout. Methods: A descriptive survey design using the Copenhagen Burnout Inventory (CBI) assessed burnout among a convenience sample of n=123 Saudi dental hygienists. The survey was disseminated electronically to 1,000 Saudi Arabian dental hygienists. The CBI measures three subscales: personal, work-related, and client/patient-related burnout on a five-point Likert-type scale. The survey also included six demographic questions, two Likert-type, one “yes/no,” and one openended question, related to burnout. Descriptive statistics, one-way between subject’s ANOVA, independent samples …

Structural Insights Into The Cl-Par-4 Protein: Ionic Requirements, Conformational Transitions, And Interaction With Cisplatin, Krishna Kumar Raut

Chemistry & Biochemistry Theses & Dissertations

Cancer continues to be the leading global cause of death, with challenges in early diagnosis, drug resistance, non-specific drug targeting, and cancer recurrence and metastasis posing formidable obstacles in cancer therapy. In this context, Prostate Apoptosis Response-4 (Par-4), a pro-apoptotic tumor suppressor protein, emerged as a promising therapeutic target due to its ability to selectively induce apoptosis in cancer cells, thereby minimizing the drug-associated adverse effects. However, a comprehensive understanding of the structural features of Par-4, specifically the caspase-cleaved fragment (cl-Par-4), is crucial for therapeutic advancements.

This dissertation investigated the effects of various ions, both monovalent and divalent, on the …

A New Method To Determine The Posterior Distribution Of Coefficient Alpha, John Mart V. Delosreyes

Psychology Theses & Dissertations

There is a focus within the behavioral/social sciences on non-physical, psychological constructs (i.e., constructs). These constructs are indirectly measured using measurement instruments that consist of questions that capture the manifestations of these constructs. The indirect nature of measuring constructs results in a need of ensuring that measurement instruments are reliable. The most popular statistic used to estimate reliability is coefficient alpha as it is easy to compute and has properties that make it desirable to use. Coefficient alpha’s popularity has resulted in a wide breadth of research into its qualities. Notably, research about coefficient alpha’s distribution has led to developments …

Machine Learning Approach To Activity Categorization In Young Adults Using Biomechanical Metrics, Nathan Q. C. Holland

Mechanical & Aerospace Engineering Theses & Dissertations

Inactive adults often have decreased musculoskeletal health and increased risk factors for chronic diseases. However, there is limited data linking biomechanical measurements of generally healthy young adults to their physical activity levels assessed through questionnaires. Commonly used data collection methods in biomechanics for assessing musculoskeletal health include but are not limited to muscle quality (measured as echo intensity when using ultrasound), isokinetic (i.e., dynamic) muscle strength, muscle activations, and functional movement assessments using motion capture systems. These assessments can be time consuming for both data collection and processing. Therefore, understanding if all biomechanical assessments are necessary to classify the activity …

A New View Of Chlorophyll Dynamics In The Southern Mid-Atlantic Bight From A Two-Year High-Resolution Spray Glider Survey, Francesco Lane

OES Theses and Dissertations

The southern Mid-Atlantic Bight (MAB) near Cape Hatteras, NC, USA, is likely a hotspot for the episodic export of carbon-rich shelf waters to the open ocean. Over a 2 year period, from March 2017 to May 2019, Spray gliders repeatedly occupied transects, along the slope and across the shelf, generating high-resolution chlorophyll fluorescence (fChl) data in the southern MAB. This study implements an fChl calibration method utilizing remotely sensing ocean color as a standard. We validate the method’s utility by demonstrating a reduction in post-calibration cross-mission fChl variability and demonstrating close correspondence between the calibrated fChl data and an in …

Faster, Cheaper, And Better Cfd: A Case For Machine Learning To Augment Reynolds-Averaged Navier-Stokes, John Peter Romano Ii

Mechanical & Aerospace Engineering Theses & Dissertations

In recent years, the field of machine learning (ML) has made significant advances, particularly through applying deep learning (DL) algorithms and artificial intelligence (AI). The literature shows several ways that ML may enhance the power of computational fluid dynamics (CFD) to improve its solution accuracy, reduce the needed computational resources and reduce overall simulation cost. ML techniques have also expanded the understanding of underlying flow physics and improved data capture from experimental fluid dynamics.

This dissertation presents an in-depth literature review and discusses ways the field of fluid dynamics has leveraged ML modeling to date. The author selects and describes …

Dental Hygiene Students Reported Physiological Symptoms Associated With Wearing An N95 Respirator Mask, Peyton Shea Butler

Dental Hygiene Theses & Dissertations

Purpose: Physiological symptoms and comfort levels while wearing an N95 respiratory mask has not been examined with dental hygienists. The purpose of this study was to investigate dental hygiene students reported physiological symptoms and comfort perception while wearing an N95 respirator mask during patient care appointments. Methods: After IRB approval (IRB #1987754-2), a 16-item questionnaire was distributed through email to a convenience sample of 65 dental hygiene students. Questions assessed respiratory, dermatologic, cardiac, mask mouth and general physiological symptoms, as well as comfort levels. Additionally, participants were asked to respond to demographic questions and one open ended question inquiring about …

Tracing And Segmentation Of Molecular Patterns In 3-Dimensional Cryo-Et/Em Density Maps Through Algorithmic Image Processing And Deep Learning-Based Techniques, Salim Sazzed

Computer Science Theses & Dissertations

Understanding the structures of biological macromolecules is highly important as they are closely associated with cellular functionalities. Comprehending the precise organization of actin filaments is crucial because they form the dynamic cytoskeleton, which offers structural support to cells and connects the cell’s interior with its surroundings. However, determining the precise organization of actin filaments is challenging due to the poor quality of cryo-electron tomography (cryo-ET) images, which suffer from low signal-to-noise (SNR) ratios and the presence of missing wedge, as well as diverse shape characteristics of actin filaments. To address these formidable challenges, the primary component of this dissertation focuses …

Global Energy Consumption: An Analysis Of Variables That Shape Per Capita Usage, Or How Pump Price, Urbanization, And Fossil Fuels Imports Impact Fossil Fuels Consumption Per Capita Across Oecd Countries, Mila Demchyk Savage

Graduate Program in International Studies Theses & Dissertations

Among reasons explaining the importance of studying fossil fuel consumption are: crude oil is a subject of the international commodities market, thus, any fluctuation related to its' availability or price would impact the rest of the World; natural resources like oil, gas, and coal are limited; the extensive use of fossil fuels harms our surroundings, creating many environmental concerns; every human (on average) has been using more energy since 1971 and the trend is expected to continue. The upward trend is not consistent among individual countries. Therefore, the core question of my research is, `Why do some countries consume less …

Towards Intelligent Runtime Framework For Distributed Heterogeneous Systems, Polykarpos Thomadakis

Computer Science Theses & Dissertations

Scientific applications strive for increased memory and computing performance, requiring massive amounts of data and time to produce results. Applications utilize large-scale, parallel computing platforms with advanced architectures to accommodate their needs. However, developing performance-portable applications for modern, heterogeneous platforms requires lots of effort and expertise in both the application and systems domains. This is more relevant for unstructured applications whose workflow is not statically predictable due to their heavily data-dependent nature. One possible solution for this problem is the introduction of an intelligent Domain-Specific Language (iDSL) that transparently helps to maintain correctness, hides the idiosyncrasies of lowlevel hardware, and …

Tidal Flooding In The Mid-Atlantic Region Of The Us: Water Quality Effects In The Lower Chesapeake Bay, Alfonso Macias Tapia

OES Theses and Dissertations

Many coastal areas around the globe suffer from nutrient pollution and its environmental, social, and economic consequences. Nutrient inputs can come from point (e.g., the end of a pipe) and nonpoint sources, from which the former are better constrained as sampling need only be conducted at a discharge point. Given the temporal and spatially extensive nature of tidal flooding events, they can represent another type of nonpoint source of nutrients to adjacent water bodies heretofore, unexamined and quantified. Most studies examining impacts of tidal flooding have focused on threats to resources on land, such as urban infrastructure and human health …

Inverse Mappers For Qcd Global Analysis, Manal Almaeen

Computer Science Theses & Dissertations

Inverse problems – using measured observations to determine unknown parameters – are well motivated but challenging in many scientific problems. Mapping parameters to observables is a well-posed problem with unique solutions, and therefore can be solved with differential equations or linear algebra solvers. However, the inverse problem requires backward mapping from observable to parameter space, which is often nonunique. Consequently, solving inverse problems is ill-posed and a far more challenging computational problem.

Our motivated application in this dissertation is the inverse problems in nuclear physics that characterize the internal structure of the hadrons. We first present a machine learning framework …

Deep Virtual Pion Pair Production, Dilini Lakshani Bulumulla

Physics Theses & Dissertations

This experiment investigates the deep virtual production of both σ− and ρ− mesons, with a particular focus on the microscopic structure of the σ mesons. While the ρ meson is an ordinary qq¯ pair, the σ meson is composed of not only the typical qq¯ pair, making it a topic of controversy for nearly six decades. Although the existence of the σ− meson is now well established, its microscopic structure remains poorly understood. The primary objective of this thesis is to contribute to the understanding of the σ meson by analyzing its deep virtual production. The main focus of this …

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Evaluating Direct Filtration As An Alternative To Conventional Carbon-Based Advanced Treatment For Indirect Potable Reuse, Savannah M. Flemmer

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District (HRSD) is recharging purified wastewater into the Potomac Aquifer via the Sustainable Water Initiative for Tomorrow (SWIFT) project. Conventional SWIFT treatment applies coagulation, flocculation, sedimentation, ozonation, biofiltration, granular activated carbon (GAC) adsorption, and ultraviolet disinfection to secondary effluent to produce water that meets drinking water standards for managed aquifer recharge. HRSD is considering implementing direct filtration as an alternative to conventional treatment for two additional SWIFT facilities. Direct filtration presents an opportunity for significant cost savings by eliminating sedimentation, shortening flocculation detention time, and reducing coagulant usage. Without upstream removal of solids and organics, however, biofilters …

Nitrogen Cycling In The Lower Chesapeake Bay And Mid- And South Atlantic Bight, Yifan Zhu

OES Theses and Dissertations

Nitrogen (N) is central to marine primary production; its availability often limits the capacity and rates of primary productivity in most of the world’s oceans. Contrastingly, estuaries frequently receive anthropogenic N loading, oftentimes resulting in eutrophication, harmful algal blooms (HABs), and substantially degraded water quality. Nutrient variability in both estuaries and oceanic regimes results from meteorological forcing and physical processes, including wind-induced, tidal, and mesoscale mixing and upwelling. In this dissertation, a comprehensive investigation of N variability and cycling and its links to physical-biogeochemical processes was conducted using time-series monitoring approaches, flux estimations, satellite imaging, biogeochemical measurements, and molecular analyses. …

Reinforcing Digital Trust For Cloud Manufacturing Through Data Provenance Using Ethereum Smart Contracts, Trupti Narayan Rane

Engineering Management & Systems Engineering Theses & Dissertations

Cloud Manufacturing(CMfg) is an advanced manufacturing model that caters to fast-paced agile requirements (Putnik, 2012). For manufacturing complex products that require extensive resources, manufacturers explore advanced manufacturing techniques like CMfg as it becomes infeasible to achieve high standards through complete ownership of manufacturing artifacts (Kuan et al., 2011). CMfg, with other names such as Manufacturing as a Service (MaaS) and Cyber Manufacturing (NSF, 2020), addresses the shortcoming of traditional manufacturing by building a virtual cyber enterprise of geographically distributed entities that manufacture custom products through collaboration.

With manufacturing venturing into cyberspace, Digital Trust issues concerning product quality, data, and intellectual …