Physical Sciences and Mathematics Commons^™

Programming Language Trends : An Empirical Study, Yaofei Chen

Dissertations

Predicting the evolution of software engineering technology trends is a dubious proposition. The recent evolution of software technology is a prime example; it is fast paced and affected by many factors, which are themselves driven by a wide range of sources. This dissertation is part of a long term project intended to analyze software engineering technology trends and how they evolve. Basically, the following questions will be answered: How to watch, predict, adapt to, and affect software engineering trends?

In this dissertation, one field of software engineering, programming languages, will be discussed. After reviewing the history of a group of …

Selective Removal Of Nox From Catalytic Cracking Regenerator Effluent Using Wet Scrubbing With Aqueous Sodium Chlorite Solutions, Pin Gu

Dissertations

In most refineries, the flue gas from the regenerator in the fluid catalytic cracking (FCC) unit represents a key source of NOx, SOx, particulate, and CO emissions. Wet scrubbing systems have been used with great success to control particulate and SOx emissions from typical FCC regenerator flue gas. Development of relatively inexpensive and safe additives that can be used in existing scrubbing systems to oxidize and absorb NOx is important in order to increase the industrial options to meet the provisions of the Clean Air Act and recently proposed EPA rules. This paper explores the feasibility of removing NOx from …

Measurement Of The Nonlinear Refractive Index (N2) And Stimulated Raman Scattering In Optical Fibers As A Function Of Germania Content, Using The Photorefractive Beam Coupling Technique, Ferdinand Anayo Oguama

Dissertations

One of the greatest challenges in optical communication is the understanding and control of optical fiber nonlinearities. While these nonlinearites limit the power handling capacity of optical fibers and can cause noise, signal distortion and cross talk in optically amplified transmission systems, they have been equally harnessed for the development of new generations of optical amplifiers and tunable laser sources. The two prominent parameters that characterize the nonlinear properties of an optical fiber are the nonlinear refractive index n₂ and the Raman gain coefficient g_R. These parameters are related to the third order nonlinear susceptibility [x^{(3) …}

Thermochemistry And Kinetics In Pyrolysis And Oxidation Reaction Of Oxygenate Chlorocarbons, Neopentane, And Ortho-Xylene, Hongyan Sun

Dissertations

Thermochemical properties of chlorinated alcohols, chlorinated hydroperoxides and corresponding alkoxy, hydroxy alkyl radicals, peroxy and hydroperoxy alkyl radicals are determined by ab initlo and density functional calculations for modeling and optimization of complex chemical processes for combustion or incineration of chlorinated hydrocarbons. The entropy and heat capacities from vibrational, translational, and external rotational contributions are calculated by statistical mechanics, and the hindered rotational contributions to S^°₂₉₈ and C_p(T)'s are calculated by using direct integration over energy levels of the internal rotational potentials. The values of ΔH_f^°₂₉₈ are determined using isodesmic reactions …

Design And Evaluation Of A List Gathering Tool In A Web-Based Collaborative Environment, Yuanqiong Wang

Dissertations

This research focuses on how to build a "list" structure to combine individual items of information into some sort of structure that converts the individual items of information into a structure of knowledge relative to the problem. Software was designed to provide relationships among and comparisons of the contributions in a "list" structure, so that individual members of a group process will be able to understand the contributions of information made by the group as a whole.

A List Gathering Tool was designed and implemented, which is one component in a Web-based Social Decision Support System (SDSS) Toolkit. Then, a …

Design And Evaluation Of A Voting Tool In A Collaborative Environment, Zheng Li

Dissertations

This dissertation researchdesigned, implemented, and evaluated a Web-based Dynamic Voting Toolfor small group decision-making in a collaborative environment.

In this dissertation, theliterature on voting tools in current GDSS research is presented. Variousvoting theories and methods are analyzed, and the advantages and weaknessesare compared, so as to gain a better understanding of how to apply thesedifferent voting methods to diverse decision-making situations. A briefoverview of scaling theories is also given, with an emphasis on Thurstone'sLaw.

The basic features of someweb-based voting tool implementations are reviewed along with a discussionof the pros and cons of Intemet voting. A discussion of Human DynamicVoting …

Understanding The Origins Of Metastability In Thin Film Growth; Tantalum And The Early Group Vb-Vib Metals, Neme Okechukwu Nnolim

Dissertations

Tantalum (Ta) is a metal that is highly prized for its applications in a variety of industries, including the microelectronics industry, where it is largely used in thin film modifications in order to achieve various electronic, magnetic and structural capabilities in solid-state devices. Ta frequently forms metastable phases, including the well-known ß-phase, during the preparation of thin Ta films by standard film deposition methods such as sputtering and electro-deposition. In order to gain insight into Ta metastable phase formation, the Bain transformation mechanism is studied for Ta and the neighboring body centered cubic (bcc) transition metals in Groups 5 and …

An Experimental Study On Network Intrusion Detection Systems, Peng Fu

Theses

A signature database is the key component of an elaborate intrusion detection system. The efficiency of signature generation for an intrusion detection system is a crucial requirement because of the rapid appearance of new attacks on the World Wide Web. However, in the commercial applications, signature generation is still a manual process, which requires professional skills and heavy human effort. Knowledge Discovery and Data Mining methods may be a solution to this problem. Data Mining and Machine Learning algorithms can be applied to the network traffic databases, in order to automatically generate signatures.

The purpose of this thesis and the …

Synthesis And Application Of Novel Chiral Ionic Liquids Derived From Alpha-Pinene, Yun Wang

Theses

Two new chiral ionic liquids of oxazolinium cations derived from a-pinene: 9,9-Dimethyl-4-propenyl-5-propyl-3 -oxa-5-azonia-tricyclo [6.1.1.0 ^2,6] dec-4-ene tetrafluoro borate ([ChIPOZ] [BF₄]) and 9,9-Dimethyl-4-propenyl-5-propyl-3-oxa-5-azonia-tricyclo [6.1.1.0 ^2,6] dec-4-ene hexafluoro phosphate ([ChIPOZ][PF₆]). Both these chiral ionic liquids have been applied in enantiomeric copper-catalyzed 1,4-addition reactions with diethyl zinc. The enantiomeric excess for product using [ChIPOZ][BF₄] is above 70% and for [ChIPOZ][PF₆] is above 30%. Chiral ionic liquids worked as phase transfer catalysts In this reaction.

α-Pinene was used as the "chiral pool" in the synthesis of amino alcohol through a two-step reaction, followed by …

Face Recognition Using Principal Component Analysis, Timothy Kevin Larkin

Theses

Current methods of face recognition use linear methods to extract features. This causes potentially valuable nonlinear features to be lost. Using a kernel to extract nonlinear features should lead to better feature extraction and, therefore, lower error rates. Kernel Principal Component Analysis (KPCA) will be used as the method for nonlinear feature extraction. KPCA will be compared with well known linear methods such as correlation, Eigenfaces, and Fisherfaces.

Image Morphological Processing, Vijayalakshmi Gaddipati

Dissertations

Mathematical Morphology with applications in image processing and analysis has been becoming increasingly important in today's technology. Mathematical Morphological operations, which are based on set theory, can extract object features by suitably shaped structuring elements. Mathematical Morphological filters are combinations of morphological operations that transform an image into a quantitative description of its geometrical structure based on structuring elements. Important applications of morphological operations are shape description, shape recognition, nonlinear filtering, industrial parts inspection, and medical image processing.

In this dissertation, basic morphological operations, properties and fuzzy morphology are reviewed. Existing techniques for solving corner and edge detection are presented. …

Fully Nonlinear Interfacial Waves In A Bounded Two-Fluid System, Lyudmyla Leonidivna Barannyk

Dissertations

We study the nonlinear flow which results when two immiscible inviscid incompressible fluids of different densities and separated by an interface which is free to move and which supports surface tension, are caused to flow in a straight infinite channel. Gravity is taken into consideration and the velocities of each phase can be different, thus giving rise to the Kelvin-Helmholtz instability. Our objective is to study the competing effects of the Kelvin-Helmholtz instability coupled with a stably or unstably stratified fluid system (Rayleigh-Taylor instability) when surface tension is present to regularize the dynamics. Our approach involves the derivation of two-and …

Optimization For Source Localization And Geoacoustic Inversion In Underwater Acoustics, Urmi Ghosh-Dastidar

Dissertations

Matched-field inversion techniques are widely used for source localization and geoacoustic parameter estimation. These inversion methods correlate the received data with modeled data and find the model parameters which provide the maximum correlation. However, when a large number of unknown parameters is involved, many modeled data need to be generated and correlated with the observed data and thus, matched-field inversion can be computationally intensive. An optimization process applied to matched-field inversion is often required to accelerate the inversion process.

In this work, tabu is applied to matched-field inversion for source localization and environmental parameter estimation. Tabu is a global optimization …

High Pressure Effects On Electron Transport And Structure Of Colossal Magnetoresistive Materials, Congwu Cui

Dissertations

Pressure effects on the electronic, magnetic properties and structure of several typical colossal magnetoresistive manganites, La_0.60Y_0.07Ca_0.33MnO₃, Pr_1-xCa_xMn0₃ (X = 0.25, 0.30, 0.35), Nd_1-xSr_xMnO₃ (x = 0.45, 0.50), were explored through high pressure resistivity and structure measurements. It was shown that pressure up to ~7 GPa induces more complicated charge, spin and lattice state changes than in the low pressure range explored previously. In La_0.60Y_0.07Ca_0.33MnO₃, pressure induces a local atomic structure transformation at a critical …

Pharmacophore Derivation Using Discotech And Comparison Of Semi-Emperical, Ab Initio And Density Functional Comfa Studies For Sigma 1 And Sigma 2 Receptor-Ligands, Dawoon Jung

Dissertations

This study describes the development of pharmacophore and CoMFA models for sigma receptor ligands. CoMFA studies were performed for 48 bioactive sigma 1 receptorligands using [H³ ](+) pentazocine as the radioligand, for 30 PCP derivatives for sigma 1 receptor-ligands using [³H](+)SK-F 10047 as the radioligand and for 24 bioactive sigma 2 receptor-ligands using the radioligand [H³](+)DTG in the presence of pentazocine. Distance Comparisons (DISCOtech) was used as the starting point for CoMFA studies. The conformers, derived by DISCOtech were optimized using AMi, or HF/3-21G* in Gaussian 98. The optimized geometries were aligned with the pharmacophore, …

Nonlinear Optical Properties Of Novel Nanostructured Ion Implanted Laser Ablated Silicon Using Femtosecond Pulse Excitation, Elaine Nicole Lalanne

Dissertations

The study of the nonlinear optical properties of novel nanostructured ion implanted and laser ablation of Silicon is motivated by the need for materials that exhibit large values of the real part of the third order nonlinear susceptibility (χ⁽³⁾_Re). This property is essential for light controlled phase or refractive index modulation at low power, where the optical properties are used for optical switching devices. Previous nanosecond (ns) measurements indicated values of-2.8 x 10 ^-5; esu ( γ = 532 nm) for χ⁽³⁾_Re.

The characterization of nonlinear optical properties of the samples was studied …

Image Enhancement Techniques Applied To Solar Feature Detection, Artur J. Kowalski

Dissertations

This dissertation presents the development of automatic image enhancement techniques for solar feature detection. The new method allows for detection and tracking of the evolution of filaments in solar images. Series of H-alpha full-disk images are taken in regular time intervals to observe the changes of the solar disk features. In each picture, the solar chromosphere filaments are identified for further evolution examination. The initial preprocessing step involves local thresholding to convert grayscale images into black-and-white pictures with chromosphere granularity enhanced. An alternative preprocessing method, based on image normalization and global thresholding is presented. The next step employs morphological closing …

Application Of Adaptive Optics To The Spectroscopic Investigation Of Small-Scale Solar Structures, Klaus Hartkorn

Dissertations

We study bright points, umbral dots and the G-band using a two-dimensional spectrometer and an Adaptive Optics system, which allows us to record high-resolution dopplergrams and residual intensity images. We find evidence that bright points are smaller than 120 km in diameter. Bright points are situated exclusively in regions of enhanced G-band brightness and do not show a change in their shape or a displacement in their position of more than 120 km horizontally over a height range from 0 km to 320 km above photospheric level T = 1. We do not find velocity differences of more than 100 …

Fresh Kills Dumped : A Policy Assessment For The Management Of New York City's Residential Solid Waste In The Twenty-First Century, Aaron William Comrov

Theses

New York City ceased disposing of its daily residential solid waste output within its municipal borders in March 2001 when the Department of Sanitation completed its phase-down of the Fresh Kills landfill on Staten Island. The closure of this facility has, for the first time in history, stripped New York City of its waste management selfsufficiency, created a situation in which municipal officials are reliant on private firms and other governmental jurisdictions for disposal services, and contributed to deteriorating fiscal, environmental, political, economic, social and practical conditions.

Consequent and concurrent to this predicament, a multitude of alternative policies have been …

An Application In Bioinformatics : A Comparison Of Affymetrix And Compugen Human Genome Microarrays, Milind Misra

Theses

The human genome microarrays from Compugen® and Affymetrix® were compared in the context of the emerging field of computational biology. The two premier database servers for genomic sequence data, the National Center for Biotechnology Information and the European Bioinformatics Institute, were described in detail. The various databases and data mining tools available through these data servers were also discussed. Microarrays were examined from a historical perspective and their main current applications-expression analysis, mutation analysis, and comparative genomic hybridization-were discussed. The two main types of microarrays, cDNA spotted microarrays and high-density spotted microarrays were analyzed by exploring the human genome microarray …

Towards Digital Library Service Integration, Prateek Shrivastava

Theses

Digital Library Service Integration (DLSI) aims to provide a systematic approach in integrating the services and collections of National Science and Digital Library. The National Science and Digital Library collections can share the services among themselves in a totally integrated environinent. Collections as such will require no change to plug into the DLSI architecture. Collections will keep using the services of NSDL in the similar manner as before. These services will in turn pass few parameters to the services of DLSI. With the help of these parameters, wrappers will fetch the details and priority of the users. These wrappers will …

Feedback Algorithm For Switch Location : Analysis Of Complexity And Application To Network Design, Yuriy S. Polyakov

Theses

An accelerated feedback algorithm to solve the single-facility minisum problem is studied with application to designing networks with the star topology. The algorithm, in which the acceleration with respect to the Weiszfeld procedure is achieved by multiplying the current Weiszfeld iterate by an accelerating feedback factor, is shown to converge faster than the accelerating procedures available in the literature. Singularities encountered in the algorithm are discussed in detail. A simple practical exception handling subroutine is developed. Several applications of the algorithm to designing computer networks with the star topology are demonstrated. Applications of the algorithm as a subroutine for multi-switch …

Uber-Claws : Unsupervised Pattern Classification For Multi-Unit Extracellular Neuronal Burst Extraction, Rama Natarajan

Theses

To further an understanding of how a neuronal population generates patterns of rhythmic activity, the temporal dynamics of the group of neurons must be formalized. Essential to this pursuit, is the ability to reliably detect and separate the classes of single-unit neuronal activity from multi-unit extracellular signals recorded in a single channel. This study proposes a unified approach to automatically detect and classify single-unit bursts, and to observe the precise onset and offset of burst activity. Existing approaches to the problem fundamentally depend on the statistics of spike waveform variability, both extrinsic and intrinsic to the neuron. In contrast, the …

The Rationale For Preserving Neighborhood Open Space In Newark, New Jersey's North Ward, Stephen M. Wiessner

Theses

A study was conducted to determine the shifts in open space availability between 1950 and 2003 in four neighborhoods in the North Ward of Newark, New Jersey. Total open space in square feet and open spaces ten thousand square feet and less were quantified to determine the extent of usable open space for the creation of community gardens or vest pocket parks.

The study identified large reductions of open space recently in the two least affluent study areas. The two more affluent study areas have also lost open space recently, but not at the magnitude of the poorer study areas. …

Experimental And Modeling Studies Of Formation Of Products Of Incomplete Combustion And Chlorocarbon Incineration, Roman Brukh

Dissertations

The two-stage combustor facility was used to investigate the process of chlorocarbon incineration and formation of products of incomplete combustion. For this purpose methylene chloride was used as a chlorine-containing compound. The propose of this research was to obtain a better understanding of the incineration process of chlorocarbons, such as methylene chloride, especially regarding its destruction efficiency and formation of products of incomplete combustion. For measuring near-real time very low concentrations of benzene and methylene chloride, on-line microtrap gas chromatography system was used.

The experimental system was validated using a known combustion reaction mechanism from literature. Modeling of combustion process …

Handgrip Pattern Recognition, Zong Chen

Dissertations

There are numerous tragic gun deaths each year. Making handguns safer by personalizing them could prevent most such tragedies. Personalized handguns, also called "smart" guns, are handguns that can only be fired by the authorized user. Handgrip pattern recognition holds great promise in the development of the smart gun.

Two algorithms, static analysis algorithm and dynamic analysis algorithm, were developed to find the patterns of a person about how to grasp a handgun. The static analysis algorithm measured 160 subjects' fingertip placements on the replica gun handle. The cluster analysis and discriminant analysis were applied to these fingertip placements, and …

Closed-Loop Control Of Vortex Shedding By Means Of Lorentz Force, Xiaoyun Sun

Dissertations

When an incompressible fluid flows past a circular cylinder, vortex shedding occurs as soon as the Reynolds number exceeds about 40. Vortex shedding is usually undesirable, as it generates a significant increase in drag, as well an oscillating lift force on the cylinder leading to cross-stream structural vibrations. Flow control to either delay the appearance of vortex shedding or fully suppress it has attracted much attention during the last decade. The focus of this dissertation is to control vortex shedding from a circular cylinder by applying an external electromagnetic field. As in previous works, the latter is generated by electrodes …

Thermochemistry And Kinetics In Pyrolysis And Oxidation Of Oxygenated Chlorocarbons And Chlorinated Aromatics, Li Zhu

Dissertations

Thermochemical. properties, Δf_H°₂₉₈, S°₂₉₈, and Cp°(T) (5<=T/K<=6000), are determined using different ab inifio and density functional theory methods for three chloromethyl radicals, CH₂Cl, CHCl₂, CCl₃, all chlorobenzenes from monochlorobenzene to hexachlorobenzene, and all chlorophenols from ortho-, meta-, para-chlorophenol to pentachlorophenol. The B3LYP/6-31G(d,p) method is used in the structure optimization. The B3LYP/6-31G(3df,2p), QCISD(T)/6-3 I G(d,p), and CB S-Q methods are used in single point calculations of total electronic energies. Harmonic vibration frequencies are scaled for zero point energies and thermal corrections. Isodesmic reaction(s) are utilized at each calculation level to determine Δf_H°₂₉₈ of each species. Contributions to S°₂₉₈ and Cp°(T) from …

A Method For Developing In-Silico Protein Homologs, Susan Mcclatchy

Theses

Computational methods for identifying and screening the most promising drug receptor candidates in the human genome are of great interest to drug discovery researchers. Successful methods will accurately identify and narrow the field of potential drug receptor candidates. This study details one such method.

The method described here begins with the assumption that novel drug receptors have high sequence similarity to established drug receptors. The similarity search program FASTA3 aligns translated sequences of the human genome to known drug receptor sequences and ranks these alignments by measuring their statistical significance. Query results returned by FASTA3 are assembled into "in-silico proteins" …

Reconsidering Restoration, Brian Hoffner

Theses

What does the process of ecological restoration actually produce? For some restoring nature is a point of no contention. By replacing ecosystems that have been damaged by human interference, humans are taking proper responsibility for their actions. However, the environmental ethics community is all but in agreement over humans' obligations to damaged ecosystems. Some in the field claim that it is human's responsibility to perform "wild gardening", through restorations, to "our" environments. While other philosophers insist that these acts produce "faked nature".

This thesis offers a compromise vision of the meaning of restoration. The author uses the concept of Autonomous …