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Full-Text Articles in Physical Sciences and Mathematics
Aerogels For Energy Storage Applications: From Shape Memory Materials To Thermites And Explosives, Suraj Donthula
Aerogels For Energy Storage Applications: From Shape Memory Materials To Thermites And Explosives, Suraj Donthula
Doctoral Dissertations
"Aerogels are three dimensional highly porous solid objects that provide density reduction compared to dense objects. Those materials can have applications in different classes of energy storage and the two types that are focused in this dissertation are mechanical energy and thermal energy storage. Shape memory materials can store and recover elastic deformation energy when triggered by an external stimulus such as temperature. To incorporate those properties, shape memory polymeric aerogels (SMPA) were synthesized from a rigid isocyanurate containing triisocyanate (N3300 A) and four short oligomeric derivatives of ethylene glycol: H(OCH2CH2)nOH (1 ≤ n …
Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr
Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr
Doctoral Dissertations
"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH4 and NaAlH4 indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …