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Fundamental Aspect And Behavior Of Saturated Fluorocarbons In Glow Discharge In Absence Of Potential Source Of Hydrogen, Yu Iriyama, H. Yasuda
Fundamental Aspect And Behavior Of Saturated Fluorocarbons In Glow Discharge In Absence Of Potential Source Of Hydrogen, Yu Iriyama, H. Yasuda
Chemistry Faculty Research & Creative Works
The glow discharge of a series of saturated fluorocarbons, CnF2n+2 (n = 1, 2, 4, 6, and 8), was studied with glass substrates which do not contain any hydrogen. It was found that the deposition rate was a function of the F/C ratio of the starting fluorocarbons. That is, fluorocarbons with higher F/C ratio, such as CF4 and C2F6, hardly polymerized, while fluorocarbons with lower F/C ratio, such as C8F18, polymerized as well as C2F4. After plasma exposure, the surface of glass substrate was …