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Full-Text Articles in Physical Sciences and Mathematics
Influence Of Season And Time Of Day On Marsh Bird Detections, Tyler Harms, Stephen Dinsmore
Influence Of Season And Time Of Day On Marsh Bird Detections, Tyler Harms, Stephen Dinsmore
Tyler Harms
Call-broadcast surveys are frequently used to elicit responses of secretive marsh birds and produce greater detection rates than passive surveys. However, little is known about how detection rates of birds from these surveys differ by season and time of day. We conducted call-broadcast surveys for eight focal species at 56 wetlands throughout Iowa from 15 May–13 June 2010 (early season) and from 15 June–10 July 2010 (late season). Our focal species were Pied-billed Grebe (Podilymbus podiceps), American Bittern (Botaurus lentiginosus), Least Bittern (Ixobrychus exilis), King Rail (Rallus elegans), Virginia Rail (Rallus …
Isomer-Specific Product Detection Of Cn Radical Reactions With Ethene And Propene By Tunable Vuv Photoionization Mass Spectrometry, Adam Trevitt, Fabien Goulay, Giovanni Meloni, David Osborn, Craig Taatjes, Stephen Leone
Isomer-Specific Product Detection Of Cn Radical Reactions With Ethene And Propene By Tunable Vuv Photoionization Mass Spectrometry, Adam Trevitt, Fabien Goulay, Giovanni Meloni, David Osborn, Craig Taatjes, Stephen Leone
Adam Trevitt
No abstract provided.
Pyrolysis Of Fulvenallene (C7h6) And Fulvenallenyl (C7h5): Theoretical Kinetics And Experimental Product Detection, Adam Trevitt, G Da Silva, M Steinbauer, P Hemberger
Pyrolysis Of Fulvenallene (C7h6) And Fulvenallenyl (C7h5): Theoretical Kinetics And Experimental Product Detection, Adam Trevitt, G Da Silva, M Steinbauer, P Hemberger
Adam Trevitt
Fulvenallene and fulvenallenyl are the respective C7H6 and C7H5 global minima, yet their importance to combustion has only recently emerged. We have studied the pyrolysis of these species theoretically to obtain rate constants and compare our results to pyrolysis mass spectrometry experiments for product identification. Master equation modeling reveals that fulvenallene rapidly dissociates to fulvenallenyl + H, and that fulvenallenyl dissociates to form propargyl plus diacetylene, with lesser amounts of i-C5H3 (CH2CCCCH)/n-C5H3 (CHCCHCCH) plus acetylene. Photoionization mass spectrometry experiments using a pyrolysis source on the fulvenallene precursor phthalide identify products consistent with those proposed theoretically for both fulvenallene and fulvenallenyl …
Reactions Of Small Carbon-Bearing Radicals With Unsaturated Hydrocarbons: Product Detection And Low Temperature Kinetics, Adam Trevitt, Fabien Goulay, Stephen Leone
Reactions Of Small Carbon-Bearing Radicals With Unsaturated Hydrocarbons: Product Detection And Low Temperature Kinetics, Adam Trevitt, Fabien Goulay, Stephen Leone
Adam Trevitt
We report on results from two experimental techniques concerned with the reactions of small carbon based radicals (CN and CH) with unsaturated hydrocarbons. First, low temperature (100-300K) kinetic studies using a pulse Laval nozzle technique probe the reactions of the CN radical with benzene and toluene. The CN + benzene is found to be a fast, barrierless reaction. But in the case of toluene, two reaction pathways are in competition, one of which back dissociates to the reactants. The implications for the atmosphere of Titan are discussed. Product detection studies undertaken at the Advanced Light Source (ALS) using synchrotron coupled …