Physical Sciences and Mathematics Commons^™

Swelling Studies Of Poly(Ionic Liquids) In Different Solvents And Salt Solutions, Pierson Perdue, Ali Alshaikh, Creighton Baltier, Jason E. Bara, Sourav Chatterjee

Scholars Week

Poly(ionic liquid)s (PILs) represented a special class of polymers, which comprised of a polymeric backbone and ionic liquids (ILs) species in each monomeric repeating units. PILs has properties that combined the properties of ionic liquids (ILs) (i.e., high conductivity, better thermal and chemical stability, and tailor-made functionality) with the intrinsic properties of polymer (i.e., mechanical stability). This synergistic property makes PILs a good candidate for various applications such as stable-ion conductors, membranes for gas separations and sorbents. In the past, it was shown that PILs are capable of swelling when dissolved in different ILs but there are few literature reported …

Synthesis And Characterization Of Semi-Interpenetrating And Double Networks Of Sulfonimide- And Imidazolium-Containing Poly(Ionic Liquids), Jeremiah Coughlon, Seth Taylor, Jason Bara, Kevin Miller, Sourav Chatterjee

Scholars Week

In recent years, there has been increased research interest in creating electrically conductive polymer membranes with materials that are widely available and environmentally safe. Herein, we report how polymeric membranes comprised of unique combinations of ionenes and poly(ionic liquids), including a recently developed sulfonimide- and imidazolium-containing methacryloxy-based monomer, were produced via UV photopolymerization. These membranes were specifically tailored to exhibit both ionic conductivity and an affinity for carbon dioxide, which are both crucial characteristics in such applications as electron transport in lithium-ion batteries and gas sorbency in separation techniques. Monomers, such as the aforementioned methacryloxy-based ionic liquid (IL) and C4VIm, …

Soil Properties Associated With Land Management Practices In Western Kentucky, Ava Isaacs, Gracey Moffitt

Scholars Week

Soil Properties Associated with Land Management Practices in Western Kentucky

1. A. Isaacs, G. Moffitt, W. Sides, and Corey Hale

Mentor: Dr. I.P. Handayani

Hutson School of Agriculture, Murray State University, Kentucky, USA

Abstract

One of the most important factors regarding soil and plant health is nutrient availability and fertility. Of these two factors that were mentioned available potassium is a key component. With that being said we decided that it would be beneficial to see how potassium can be traced within the soil in various locations after fertilizer is applied. There were two parts to this experiment. Part one was …

Physiochemical Properties Of Urethane-Containing Ionic Liquids And Ionenes From A Non-Isocyanate Synthetic Approach, George Timmermann

Scholars Week

Ionic polymers that are designed to contain ionic liquids (ILs) in their backbones have been shown to exhibit a high degree of variability through changing the type of ionic character and the location of the ionic region within the molecule. This large amount of variability in both the structure and characteristics of ILs allows researchers to design task-specific ionic polymers and ILs for a variety of applications including gas separation membranes and solid polymer electrolytes. The synthesis of a specific class of ILs and ionenes through the incorporation of urethane groups with imidazolium rings by reacting carbonyl diimidazole with various …

Mathematical Model Of Devil Facial Tumor Disease (Dftd) Spread In Tasmanian Devils, Abigail Collins

Scholars Week

Applications of disease models can lead to insight on spread of diseases, population movements, and wildlife health safety. This exploration of mathematical models sought to determine the spread of wildlife disease, specifically devil facial tumor disease (DFTD). Tasmanian devil populations have been negatively affected by DFTD. The basic SIR disease model was modified to better fit the spread of DFTD, along with a network model to inspect the rate of infectivity. It was found that the population of Tasmanian devils will continue to decrease in size and multiple populations are connected to each other. Models of wildlife disease have the …

Mapping Of Non-Native Invasive Plant Species Using Remote Sensing And Gis: Assessment Of Human Impact On Kudzu (Pueraria Montana) Spread, Harshitkumar Godhasara

Scholars Week

Remote sensing methods provide tools to identify and map non-native plants. Biophysical characteristics of plants can be utilized to recognize and distinguish non-native invasive plants from other native plant species. Kudzu is an invasive plant, which causes economic loss and decreases biodiversity. Moreover, kudzu doubles emission of nitric oxide and increases ozone pollution. The impact of human activities on the spread of noxious plant species like kudzu can be assessed utilizing remote sensing and geographic information systems (GIS) tools. Kudzu spread in the USA was mapped using in situ data including the actual coordinates of kudzu sites. Geographic distribution of …

Modeling Distances Between Various Attractions And Nearest City Parks Using Exponential Distribution, Ashley Hall

Scholars Week

We examine the park data in Twin Cities Metropolitan Area (TCMA) to understand the distances between various attractions (water features, transit stops, bike paths, sport fields, etc.) and nearest city parks. We verify our research hypothesis that these distance variables are exponentially distributed using histograms and chi-squared goodness-of-fit test. Our findings suggest that most of the distance variables are indeed exponentially distributed except the one that measures the distance between the metropolitan area and the nearest city parks. Based on that, we further hypothesize that the locations of the various attractions relative to the nearest city parks follow the spatial …

Polycarbodiimides And Polyguanidines : Their Reactivity And Applications In Covalent Adaptable Networks, Alberto Melchor Bañales

Scholars Week

We have recently discovered a new chemical transformation in which N,N’,N’’ tri-substituted guanidines undergo a thermal exchange reaction. Kinetic investigations indicate that the transformation is first order with respect to the guanidine, indicating a dissociative mechanism in which a carbodiimide and amine are formed as intermediates. This new reaction has been applied to polymer systems. Polycarbodiimides were shown to undergo postpolymerization modification with amines to form polyguanidines at room temperature under an hour. Polyguanidines undergo the newly found chemical transformation to form different substituted polyguanidines. This exchange reaction will be applied to the preparation of a covalent adaptable network by …

Spectral Analysis Of Stratigraphy At Eberswalde Crater, Mars, Cory Hughes

Scholars Week

We will analyze spectral characteristics of stratigraphy in the catchment and deposit at Eberswalde Crater, Mars. This crater is a frequent contender for the preferred destination of future Mars rover and human science missions in the search for evidence of life on the Red Planet.

Characteristics Of Soils Under Common Management Practices On Farms In Western Kentucky, River Dowell

Scholars Week

Characteristics of Soils under Common Management Practices

on Farms in Western Kentucky

River O. Dowell and Iin P. Handayani, Murray State University, Kentucky

ABSTRACT

Properly understanding the importance of soil properties and how they continuously change is a key to achieving sustainability in agriculture. This study was conducted to observe the changes of soil properties regarding common tillage systems in Kentucky. Undisturbed and disturbed soil samples were collected from Butler County, KY at depths of 0-7.5 cm and 7.5-15 cm from four sites representing the different management practices of conventional tillage, no-till, pasture, and woodlands. The samples were analyzed for …