Physical Sciences and Mathematics Commons^™

Predicting The Reactions Of Cs2, Ocs, And Co2 With Group Iv And Group Vi Transition Metal Oxides, Marissa Shea Blair, Zachary Ryan Lee Phd, David A. Dixon Phd

Posters-at-the-Capitol

Building on a recent serious of high level electronic structure studies of Lewis acid gas reactions with metal oxide sorbents, DFT (B3LYP and ωB97X-D) and CCSD(T) methods are being used to predict the Lewis acid-base addition (physisorption) and formation of metal oxide carbonate/thiocarbonate formation (chemisorption) reactions of CS2, OCS, and CO2 of CS2, OCS, and CO2 with Group IV (MO2)n and Group VI (MO3)n (n = 1 - 3) nanoclusters. For the Group IV oxides, chemisorption to form terminal carbonates and thiocarbonates is predicted to be the most favored, with thiocarbonate ligand binding energies slightly more exothermic than their carbonate …

Swelling Studies Of Poly(Ionic Liquids) In Different Solvents And Salt Solutions, Pierson Perdue, Ali Alshaikh, Creighton Baltier, Jason E. Bara, Sourav Chatterjee

Scholars Week

Poly(ionic liquid)s (PILs) represented a special class of polymers, which comprised of a polymeric backbone and ionic liquids (ILs) species in each monomeric repeating units. PILs has properties that combined the properties of ionic liquids (ILs) (i.e., high conductivity, better thermal and chemical stability, and tailor-made functionality) with the intrinsic properties of polymer (i.e., mechanical stability). This synergistic property makes PILs a good candidate for various applications such as stable-ion conductors, membranes for gas separations and sorbents. In the past, it was shown that PILs are capable of swelling when dissolved in different ILs but there are few literature reported …

Synthesis And Characterization Of Semi-Interpenetrating And Double Networks Of Sulfonimide- And Imidazolium-Containing Poly(Ionic Liquids), Jeremiah Coughlon, Seth Taylor, Jason Bara, Kevin Miller, Sourav Chatterjee

Scholars Week

In recent years, there has been increased research interest in creating electrically conductive polymer membranes with materials that are widely available and environmentally safe. Herein, we report how polymeric membranes comprised of unique combinations of ionenes and poly(ionic liquids), including a recently developed sulfonimide- and imidazolium-containing methacryloxy-based monomer, were produced via UV photopolymerization. These membranes were specifically tailored to exhibit both ionic conductivity and an affinity for carbon dioxide, which are both crucial characteristics in such applications as electron transport in lithium-ion batteries and gas sorbency in separation techniques. Monomers, such as the aforementioned methacryloxy-based ionic liquid (IL) and C4VIm, …

Soil Properties Associated With Land Management Practices In Western Kentucky, Ava Isaacs, Gracey Moffitt

Scholars Week

Soil Properties Associated with Land Management Practices in Western Kentucky

1. A. Isaacs, G. Moffitt, W. Sides, and Corey Hale

Mentor: Dr. I.P. Handayani

Hutson School of Agriculture, Murray State University, Kentucky, USA

Abstract

One of the most important factors regarding soil and plant health is nutrient availability and fertility. Of these two factors that were mentioned available potassium is a key component. With that being said we decided that it would be beneficial to see how potassium can be traced within the soil in various locations after fertilizer is applied. There were two parts to this experiment. Part one was …

Physiochemical Properties Of Urethane-Containing Ionic Liquids And Ionenes From A Non-Isocyanate Synthetic Approach, George Timmermann

Scholars Week

Ionic polymers that are designed to contain ionic liquids (ILs) in their backbones have been shown to exhibit a high degree of variability through changing the type of ionic character and the location of the ionic region within the molecule. This large amount of variability in both the structure and characteristics of ILs allows researchers to design task-specific ionic polymers and ILs for a variety of applications including gas separation membranes and solid polymer electrolytes. The synthesis of a specific class of ILs and ionenes through the incorporation of urethane groups with imidazolium rings by reacting carbonyl diimidazole with various …

Strategies For Identifying Important Residues In The Trna Modification Protein Trm732, Alex K. Mullins, Natalie N. Creech, Holly Funk, Michael Guy

Posters-at-the-Capitol

Post-transcriptional tRNA modifications are required for efficient protein translation. In yeast, the Trm7 methyltransferase forms a complex with Trm732 to modify tRNA at position 32. In humans, lack of the human homolog for Trm7, FTSJ1, causes intellectual disability. Little is known about the function of Trm732, although we have shown that one conserved motif in Trm732 is important for tRNA modification. We have identified other residues important for function using two strategies. First, we compared Trm732 proteins of different organisms using protein alignments to determine conserved regions to mutate for testing. We have generated four new Trm732 variants and have …

Mathematical Model Of Devil Facial Tumor Disease (Dftd) Spread In Tasmanian Devils, Abigail Collins

Scholars Week

Applications of disease models can lead to insight on spread of diseases, population movements, and wildlife health safety. This exploration of mathematical models sought to determine the spread of wildlife disease, specifically devil facial tumor disease (DFTD). Tasmanian devil populations have been negatively affected by DFTD. The basic SIR disease model was modified to better fit the spread of DFTD, along with a network model to inspect the rate of infectivity. It was found that the population of Tasmanian devils will continue to decrease in size and multiple populations are connected to each other. Models of wildlife disease have the …

Mapping Of Non-Native Invasive Plant Species Using Remote Sensing And Gis: Assessment Of Human Impact On Kudzu (Pueraria Montana) Spread, Harshitkumar Godhasara

Scholars Week

Remote sensing methods provide tools to identify and map non-native plants. Biophysical characteristics of plants can be utilized to recognize and distinguish non-native invasive plants from other native plant species. Kudzu is an invasive plant, which causes economic loss and decreases biodiversity. Moreover, kudzu doubles emission of nitric oxide and increases ozone pollution. The impact of human activities on the spread of noxious plant species like kudzu can be assessed utilizing remote sensing and geographic information systems (GIS) tools. Kudzu spread in the USA was mapped using in situ data including the actual coordinates of kudzu sites. Geographic distribution of …

Galaxy And Mass Assembly: A Comparison Between Galaxy-Galaxy Lens Searches In Kids/Gama, Shawn Knabel, Benne Holwerda

Posters-at-the-Capitol

Strong gravitational lenses are cases where a distant background galaxy is located directly behind a massive foreground galaxy, whose gravity causes the light from the background galaxy to bend around the foreground galaxy. In addition to being visually stunning, these rare events are useful laboratories for furthering our understanding of gravity and cosmology and to determine properties, such as the mass and dark matter content, of the lensing galaxies themselves. The trouble is finding enough of these strong gravitational lenses for further study. The immensity of the catalogs being collected by state-of-the-art telescopes requires equally innovative methods for interpreting that …

The Effects Of Erosion Structures On Triplett Creek From The Fall Of 2016, 2017, And 2018, Haylee Winters

Posters-at-the-Capitol

Triplett Creek is a tributary of the Licking River. It runs through Morehead, KY, where we are conducting our research.

The creek was modified in the 1970s but construction was halted before the project was complete. Unfortunately, the result was an increase in overflow and subsequent riverbank erosion. The city installed sediment trap rocks in hopes of slowing down the water and decreasing erosion. We are using drones and photogrammetric software to map the area and compare images of the river to determine erosion rates. The new images will be compared to ones taken in previous years to visualize the …

Characteristics Of Soils Under Common Management Practices On Farms In Western Kentucky, River Dowell

Scholars Week

Characteristics of Soils under Common Management Practices

on Farms in Western Kentucky

River O. Dowell and Iin P. Handayani, Murray State University, Kentucky

ABSTRACT

Properly understanding the importance of soil properties and how they continuously change is a key to achieving sustainability in agriculture. This study was conducted to observe the changes of soil properties regarding common tillage systems in Kentucky. Undisturbed and disturbed soil samples were collected from Butler County, KY at depths of 0-7.5 cm and 7.5-15 cm from four sites representing the different management practices of conventional tillage, no-till, pasture, and woodlands. The samples were analyzed for …

Elevated Calcium Levels In Kentucky Lake: A Possible Emerging Problem With An Invasive Species, Adam T. Martin

Posters-at-the-Capitol

Zebra mussels (Dreissena polymorpha) are an exotic and invasive mollusk that have spread extensively through various rivers and lakes in the United States. These mussels are notorious for their “biofouling” capabilities costing billions of dollars in their removal from industrial, public, and power plant water supply lines. While having been present in the Tennessee River drainage with occasional small reproducing populations since the early 1990s, zebra mussels were never abundant or widespread. In 2017, high densities were found on structures and solid substrates throughout the lower portion of Kentucky Lake. Calcium is one of the essential elements that contributes …

Consumption Profiles Of Illicit And Neuropsychiatric Drugs In Urban And Rural Communities In Kentucky Using Sewage Epidemiology, Tara Croft, Katelyn Foppe, Rhiannon Huffines, Bikram Subedi

Posters-at-the-Capitol

The drug overdose deaths in the USA increased by ~20% from 2015 to 2016 to the total >63,600 drug overdose deaths in 2016. Kentucky is among the highest rate of drug overdose death states in the USA. The current estimates of the prevalence of substance abuse are based on the self-reported surveys, overdose/toxicological reports, and drug-related crime statistics. Survey-based conventional approaches are not only cost and time-intensive but also underestimate the actual consumption of drugs. As “wastewater never lie,” the drug residues in raw wastewater collected from the centralized wastewater treatment plants were utilized to determine the consumption rate of …

Catalytic Deoxygenation Of Model And Realistic Feeds To Fuel-Like Hydrocarbons Over Supported Nickel-Copper Catalysts, Deyshon Ward, Kazi Javed

Posters-at-the-Capitol

The goal was to make a renewable fuel by using catalysts to remove oxygen molecules from fats. This is a current issue that society faces today because nonrenewable fossil fuels hurt the environment more than they help it. There are two components that make up a heterogeneous catalyst, a support and a reduced metal active phase. The active metal phases Nickel, Palladium, Platinum have been studied in the past on an alumina and carbon supports. We were investigating other supports using Nickel as the active phase component to determine the effect the support has on the catalyst removing oxygen of …

An In Vitro Study On Skin Protection Across The Uv Spectra, Cheyenne Boone

Posters-at-the-Capitol

Skin cancer is the number one cancer in the United States. Lack of awareness of how harmful UV radiation is could be the cause of the over two million cases reported since 2012. It appears that there is not a lot information on the active ingredients used in sunscreens. Some of the compounds have been linked to birth defects, hormone disruptions, and the bleaching of coral reefs. Samples of commonly used sunscreens (both sprays and creams), cosmetic foundation, essential oils, lotions, and three pure organic actives were tested at specific concentrations and ran through a UV spectrometer. The results have …

Shape Modeling And Boulder Mapping Of Asteroid 1992 Uy4, Nicholas Duong

Posters-at-the-Capitol

The structure and history of near-Earth asteroids are important to
study because they collide with Earth, sometimes with significant consequences for
climate and the survival of many species, including our own. If NASA is ever to deflect an asteroid on a collision course, it is crucial to know as much as possible about its size, composition, structure and boulder distribution. The boulder
distribution in turn helps to map the asteroid's gravitational field.

1992 UY4 is a near-Earth asteroid discovered in 1992. In August 2005, UY4 made a
``close" (for space) pass of Earth, about 15x farther than the Moon. It …

Tunable Copper Complexes For Sustainable Photocatalysis, David Kline

Posters-at-the-Capitol

Photoredox catalysis has direct applications in sustainable chemistry and thus an immense impact on our environment. With the ability to harness energy directly from the sun to catalyze useful chemical reactions, photocatalysts can help to eliminate the need for harsh reaction conditions and reduce generation of hazardous chemical waste. Photocatalysts based on Earth-abundant metals such as copper have recently emerged as sustainable alternatives to rare-earth metals including iridium and ruthenium, which are no longer required for many photocatalyzed chemical transformations.

Using Fundamental Chemistry To Make Functional Materials For Solar Energy Conversion Applications, Kylie N. Heupel, Haley M. Sizemore, Judith L. Jenkins

Posters-at-the-Capitol

Population growth and rapidly increasing energy consumption necessitate innovative materials for energy conversion and storage. Gains in solar electricity and battery technologies are evidenced by the availability of commercial products. However viable solar fuel platforms—where the energy in sunlight is used to form storable fuels such as hydrogen gas—have not yet been realized, motivating the work presented here. In order to produce hydrogen gas from sunlight and water, a photocatalyst is required. The ideal photocatalyst for hydrogen gas generation absorbs solar photons (sunlight), producing high-energy electrons necessary for the reduction of hydrogen ions in water. The host nanocrystal studied here, …