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Full-Text Articles in Physical Sciences and Mathematics
Seawater-Induced Mobilization Of Trace Metals From Mackinawite-Rich Estuarine Sediments, Vanessa Wong, Scott Johnston, Edward Burton, Richard Bush, Leigh Sullivan, Peter Slavich
Seawater-Induced Mobilization Of Trace Metals From Mackinawite-Rich Estuarine Sediments, Vanessa Wong, Scott Johnston, Edward Burton, Richard Bush, Leigh Sullivan, Peter Slavich
Associate Professor Edward D Burton
Benthic sediments in coastal acid sulfate soil (CASS) drains can contain high concentrations (∼1–5%) of acid volatile sulfide (AVS) as nano-particulate mackinawite. These sediments can sequester substantial quantities of trace metals. Because of their low elevation and the connectivity of drains to estuarine channels, these benthic sediments are vulnerable to rapid increases in ionic strength from seawater incursion by floodgate opening, floodgate failure, storm surge and seasonal migration of the estuarine salt wedge. This study examines the effect of increasing seawater concentration on trace metal mobilization from mackinawite-rich drain sediments (210–550 μmol g−1 AVS) collected along an estuarine salinity …
Copper Behaviour In A Podosol. Ii: Sorption Reversibility, Geochemical Partitioning And Column Leaching, Edward Burton, Ian Phillips, Darryl Hawker, Dane Lamb
Copper Behaviour In A Podosol. Ii: Sorption Reversibility, Geochemical Partitioning And Column Leaching, Edward Burton, Ian Phillips, Darryl Hawker, Dane Lamb
Associate Professor Edward D Burton
The sorption–desorption and leaching behaviour of Cu in a Podosol from south-east Queensland, Australia, was examined. Copper sorption was described by a linear distribution coefficient at low sorption levels (KDCa→0) of 481 L/kg and a sorption capacity (CS,Max) of 382 mg/kg. Selective removal of soil organic matter reduced these values by approximately 95%, indicating that Cu was sorbed predominantly to soil organic matter. The KDCa→0 and CS,Max values from Cu desorption experiments were 934 L/kg and 516 mg/kg, respectively, which indicates that sorption was not fully reversible. This irreversibility was related to …
Copper Behaviour In A Podosol. I: Ph-Dependent Sorption-Desorption, Sorption Isotherm Analysis And Aqueous Speciation Modelling, Edward Burton, Ian Phillips, Darryl Hawker, Dane Lamb
Copper Behaviour In A Podosol. I: Ph-Dependent Sorption-Desorption, Sorption Isotherm Analysis And Aqueous Speciation Modelling, Edward Burton, Ian Phillips, Darryl Hawker, Dane Lamb
Associate Professor Edward D Burton
The effects of pH and Cu loading on the solid/solution partitioning of Cu in a Podosol from south-east Queensland, Australia was examined. Sorption–desorption of Cu exhibited maximum linear distribution coefficients (KD) at approximately pH 5. Observed decrease in KD values at pH >5 was attributed to increased solubility of native dissolved organic carbon (DOC) at higher pH and subsequent formation of non-sorbing Cu–DOC complexes. Speciation modelling with the MINTEQA2 code indicated that >90% of aqueous Cu was present as Cu–DOC complexes at pH >5.5. The effect of Cu loading was examined with sorption isotherm analysis at pH …