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Full-Text Articles in Physical Sciences and Mathematics
Enrichment And Heterogeneity Of Trace Elements At The Redox-Interface Of Fe-Rich Intertidal Sediments, Annabelle Keene, Scott Johnston, Richard Bush, Edward Burton, Leigh Sullivan, Matthew Dundoon, Angus Mcelnea, C Smith, Col Ahern, Bernard Powell
Enrichment And Heterogeneity Of Trace Elements At The Redox-Interface Of Fe-Rich Intertidal Sediments, Annabelle Keene, Scott Johnston, Richard Bush, Edward Burton, Leigh Sullivan, Matthew Dundoon, Angus Mcelnea, C Smith, Col Ahern, Bernard Powell
Associate Professor Edward D Burton
Redox-interfacial sediments can undergo radical geochemical changes with oscillating tides. In this study, we examine trace element enrichment and availability, at both landscape and pedon-scales, in the surface sediments of a remediating acidic tidal wetland. Fe-rich sediments at the surface-water interface (0–10 mm in depth) were collected across an elevation gradient spanning the supratidal to subtidal range. These sediments were analysed for solid phase Fe fractions and trace elements (As, Pb, Cr, Cu, Mn, Ni, Zn, V, B, Co, Mo, Ba and U) via dilute HCl-extractions and total digests. Their concentrations were compared with those of underlying (0.05–0.65 m in …