Physical Sciences and Mathematics Commons^™

A Combined Chemical And Biological Approach To Transforming And Mineralizing Pahs In Runoff Water, Chainarong Sakulthaew, Steve D. Comfort, Chanat Chokejaroenrat, Clifford Harris, Xu Li

School of Natural Resources: Faculty Publications

The water quality of lakes, rivers and streams associated with metropolitan areas is declining from increased inputs of urban runoff that contain polycyclic aromatic hydrocarbons (PAHs). Our objective was to transform and mineralize PAHs in runoff using a combined chemical and biological approach. Using ¹⁴C-labeled phenanthrene, ¹⁴C-benzo(a)pyrene and a mixture of 16 PAHs, we found that ozone transformed all PAHs in a H₂O matrix within minutes but complete mineralization to CO₂ took several weeks. When urban runoff water (7.6 mg C L−1) replaced H₂O as the background matrix, some delays in degradation rates …