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Physical Sciences and Mathematics Commons

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Full-Text Articles in Physical Sciences and Mathematics

Alicyclic And Aromatic Carboxylic Acids In Soil Organic Matter: An Investigation Of Potential Origin And Association With Plutonium Using Advanced Analytical Techniques, Nicole Didonato Apr 2017

Alicyclic And Aromatic Carboxylic Acids In Soil Organic Matter: An Investigation Of Potential Origin And Association With Plutonium Using Advanced Analytical Techniques, Nicole Didonato

Chemistry & Biochemistry Theses & Dissertations

Carboxylic acids are a defining component of soil organic matter, responsible for many of the physical and chemical properties, including metal-organic matter interactions, which govern its role as an important constituent of soils. However, there is a shortage of detailed molecular level information regarding orientation and structural arrangement of carboxylic acids within soil organic matter. This dissertation utilizes electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS) as well as solid-state and multi-dimensional nuclear magnetic resonance (NMR) to investigate the molecular formula composition within several organic matter sources and the primary structures that feature carboxylic acids. Soil organic matter …


Upscaling Stem To Community-Level Transpiration For Two Sand-Fixing Plants: Salix Gordejevii And Caragana Microphylla, Limin Duan, Yang Li, Xue Yan, Tingxi Liu, Xixi Wang Jan 2017

Upscaling Stem To Community-Level Transpiration For Two Sand-Fixing Plants: Salix Gordejevii And Caragana Microphylla, Limin Duan, Yang Li, Xue Yan, Tingxi Liu, Xixi Wang

Civil & Environmental Engineering Faculty Publications

The information on transpiration is vital for sustaining fragile ecosystem in arid/semiarid environment, including the Horqin Sandy Land (HSL) located in northeast China. However, such information is scarce in existing literature. The objectives of this study were to: (1) measure sap flow of selected individual stems of two sand-fixing plants, namely Salix gordejevii and Caragana microphylla, in HSL; and (2) upscale the measured stem-level sap flow for estimating the community-level transpiration. The measurements were done from 1 May to 30 September 2015 (i.e., during the growing season). The upscaling function was developed to have one dependent variable, namely sap …


Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar Jan 2017

Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar

Civil & Environmental Engineering Faculty Publications

Previous studies of land degradation, topsoil erosion, and hydrologic alteration typically focus on these subjects individually, missing important interrelationships among these important aspects of the Earth's system. However, an understanding of water–soil–vegetation dynamic interactions is needed to develop practical and effective solutions to sustain the globe's eco-environment and grassland agriculture, which depends on grasses, legumes, and other fodder or soil-building crops. This special issue is intended to be a platform for a discussion of the relevant scientific findings based on experimental and/or modeling studies. Its 12 peer-reviewed articles present data, novel analysis/modeling approaches, and convincing results of water–soil–vegetation interactions under …