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Full-Text Articles in Physical Sciences and Mathematics

Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen Jul 2019

Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen

Doctoral Dissertations

The preservation of soil organic matter (SOM) is an important control on the global cycling of carbon. Long-term preservation of SOM has important implications on soil fertility and climate regulation. Minerals, such as iron oxides, can react with SOM and serve as a preservation mechanism for SOM. Globally, iron oxide-SOM interactions form a “rusty carbon sink” which protects up to 22% of organic carbon in marine sediments. Climate changes, such as warming, may alter the size or efficacy of the “rusty carbon sink.” The effects of temperature, SOM composition, and mineral particle size on the formation and stability of iron …


Root-Driven Weathering Impacts On Mineral-Organic Associations Over Pedogenic Time Scales, Mariela Garcia Arredondo Mar 2019

Root-Driven Weathering Impacts On Mineral-Organic Associations Over Pedogenic Time Scales, Mariela Garcia Arredondo

Masters Theses

Plant roots are critical weathering agents in deep soils, yet the impact of resulting mineral transformations on the vast deep soil carbon (C) reservoir are largely unknown. Root-driven weathering of primary minerals may cause the formation of reactive secondary minerals, which protect mineral-organic associations (MOAs) for centuries or millennia. Conversely, root-driven weathering may also transform secondary minerals, potentially enhancing the bioavailability of C previously protected in MOAs. Here we examined the impact of root-driven weathering on MOAs and their capacity to store C over pedogenic time scales. I compared soil that experienced root-driven weathering, resulting in the formation of discrete …