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Full-Text Articles in Physical Sciences and Mathematics

Rheological Investigations Of Latex-Surfactant-Associative Thickener Aqueous Systems, Bishop I. Hammack Jun 2019

Rheological Investigations Of Latex-Surfactant-Associative Thickener Aqueous Systems, Bishop I. Hammack

Master's Theses

Surfactants and Thickeners are both additives used in fully-formulated waterborne coatings to provide colloidal stability, thickening, and other functionality. The behavior of each ingredient in a coating must be understood and controlled to maintain colloidal stability as well as balance other desired properties of the liquid coating and the dry paint film. In this work, quaternary systems of Water-Latex-Thickener-Surfactant were investigated to further the understanding of their behavior in coatings. The thickener used was a well characterized, hydrophobically-modified, ethoxylated urethane (HEUR) with two C18 terminal hydrophobes and 795 average repeat units of ethylene oxide as the hydrophilic spacer. Two latexes, …


Method Development To Quantify The Reinforcing Properties Of Silica Fillers, Hamid Reza Givehchi Apr 2019

Method Development To Quantify The Reinforcing Properties Of Silica Fillers, Hamid Reza Givehchi

Electronic Theses & Dissertations

Polysiloxane polymers are widely used as a high-temperature resistant materials with the ability to maintain flexibility at extremely low temperatures. Unfortunately, polysiloxane elastomers generally exhibit low strength and poor mechanical properties and have no practical use unless they are reinforced. These elastomers can be mechanically improved through the use of reinforcing silica-based fillers. It is known that silanol groups on the surface of silica filler particles can interact with the polysiloxane backbone. Interactions of silanol groups on the fillers’ surfaces with the polysiloxane backbone through hydrogen bonding may hinder the mobility of the polymer chain and can improve thermal, physical, …