Physical Sciences and Mathematics Commons^™

Can Parallel Gravitational Search Algorithm Effectively Choose Parameters For Photovoltaic Cell Current Voltage Characteristics?, Alan Kirkpatrick

Honors Projects

This study asks the question “Can parallel Gravitational Search Algorithm (GSA) effectively choose parameters for photovoltaic cell current voltage characteristics?” These parameters will be plugged into the Single Diode Model to create the IV curve. It will also investigate Particle Swarm Optimization (PSO) and a population based random search (PBRS) to see if GSA performs the search better and or more quickly than alternative algorithms

Organic-Inorganic Halide Perovskite Nanocrystals And Solar Cells, Rui Guo

FIU Electronic Theses and Dissertations

A great challenge facing humanity in the 21^st century is finding inexhaustible and inexpensive energy sources to power the planet. Renewable energies are the best solutions because of their abundance, diversity, and pollution-free emission. Solar energy is the cleanest and most abundant renewable energy source available. In the continuing quest for efficient and low-cost solar cells, perovskite solar cells (PSCs) have emerged as a potential replacement for silicon solar cells. Since 2009, the record efficiencies of PSCs have been skyrocketing from 3.8 % to 25.2 % and are now approaching the theoretical limit. Along with the three-dimensional perovskites used …

Investigation Into Reduced Thermal Conductivity For Half-Heusler Alloys And Identification Of Novel Multinary Chalcogenides Possessing Intrinsically Low Thermal Conductivity, Dean Hobbis

USF Tampa Graduate Theses and Dissertations

The current climate makes the need for sustainable energy production a priority, leading to keen interest towards the advancement of “green” energy sources and technology. This necessity has led to a multidisciplinary scientific approach with collaborations across various fields that are looking to solve this extremely important problem. One such technology is thermoelectric devices, which are attractive due to the fact that they provide direct solid-state conversion of heat to electrical power, and vice versa. This in turn allows for both waste heat recovery and sustainable refrigeration. One key aspect that is preventing the wide scale commercial use of thermoelectric …

A Review: Thermal Stability Of Methylammonium Lead Halide Based Perovskite Solar Cells, Tanzila Tasnim Ava, Abdullah Al Mamun, Sylvain Marsillac, Gon Namkoong

Electrical & Computer Engineering Faculty Publications

Perovskite solar cells have achieved photo-conversion efficiencies greater than 20%, making them a promising candidate as an emerging solar cell technology. While perovskite solar cells are expected to eventually compete with existing silicon-based solar cells on the market, their long-term stability has become a major bottleneck. In particular, perovskite films are found to be very sensitive to external factors such as air, UV light, light soaking, thermal stress and others. Among these stressors, light, oxygen and moisture-induced degradation can be slowed by integrating barrier or interface layers within the device architecture. However, the most representative perovskite absorber material, CH_{3 …}

Application Of Silicon Nanohair Textured P-N Junctions In A Photovoltaic Device, Michael Small

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for a silicon photovoltaic device which incorporates a nanohair textured p-n junction. The silicon nanowires are etched into a silicon wafer, comprising an epitaxial p-layer on n-substrate, via metal-assisted chemical etching (MACE). The resulting nanowires contain p-n junctions that lie along the length of the vertical nanowires. This construct has the potential to increase the optical bandwidth of a silicon photovoltaic device by allowing a greater amount of short wavelength light to reach the junction. In addition, the MACE method of nanofabrication has the potential for decreasing …

Study On The Design Method Of Integration Of Roof And Photovoltaic Based On Aesthetics, Technology And Energy-Saving Characteristic, Hongxin Feng, Juanli Guo, Gang Liu, Jiehui Wang

International Building Physics Conference 2018

The development and utilization of new energy has been concerned due to the traditional energy is increasingly scarce. In recent years, solar building has developed rapidly in the construction industry which is a major energy consuming component. As an organic part of the building, the combination of roof and solar energy has become the focus of attention because of its large size, less shielding and other characteristics. Based on the works of recent years’ Solar Decathlon, this paper analysed the design and implementation of the integration of solar building’s roof and photovoltaic. Meanwhile, taking an office building in Xinjiang, China …

Photovoltaics: An Investigation Into The Origins Of Efficiency On All Scales, Jeremy Alexander Bannister

Senior Projects Spring 2016

This project is comprised of a set of parallel investigations, which share the common mo- tivation of increasing the efficiency of photovoltaics. First, the reader is introduced to core concepts of photovoltaic energy conversion via a semi-classical description of the phys- ical system. Second, a key player in photovoltaic efficiency calculations, the exciton, is discussed in greater quantum mechanical detail. The reader will be taken through a nu- merical derivation of the low-energy exciton states in various geometries, including a line segment, a circle and a sphere. These numerical calculations are done using Mathematica, a computer program which, due to …

Optical And Scanning Probe Studies Of Isolated Poly (3-Hexylthiophene) Nanofibers, Mina Baghgarbostanabad

Doctoral Dissertations

Plastic electronics have an essential role in the future technologies owing to their compelling characteristics such as light weight, biocompatibity, low cost fabrication, and tunable optoelectronic properties. However, the performance of polymer-based devices strongly depends on the efficiency of exciton formation and dynamics that are themselves strongly sensitive to polymer molecular packing and structural order. Therefore, the current challenge in achieving high efficiency is establishing a correlation between molecular packing and exciton coupling. P3HT nanofibers represent an attractive platform for studying optical and electronic properties of exciton coupling because their nominal (highly crystalline) internal chain packing structure is known. A …

Improving Hybrid Solar Cells: Overcoming Charge Extraction Issues In Bulk Mixtures Of Polythiophenes And Zinc Oxide Nanostructures, Grant T. Olson

Master's Theses

Organic photovoltaics (OPVs) have received a great deal of focus in recent years as a possible alternative to expensive silicon based solar technology. Current challenges for organic photovoltaics are centered around improving their lifetimes and increasing their power conversion efficiencies. One approach to improving the lifetime of such devices has been the inclusion of inorganic metal oxide layers, but interaction between the metal oxides and common conjugated polymers is not favorable. Here we present two methods by which the interactions between polythiophenes and nanostructured ZnO can be made to be more favorable. Using the first method, direct side on attachment …

Investigations Into B-O Defect Formation-Dissociation In Cz-Silicon And Their Effect On Solar Cell Performance, Prakash M. Basnyat

Dissertations

About 30% of the total market share of industrial manufacture of silicon solar cells is taken by single crystalline Czochralski (CZ) grown wafers. The efficiency of solar cells fabricated on boron-doped Czochralski silicon degrades due to the formation of metastable defects when excess electrons are created by illumination or minority carrier injection during forward bias. The recombination path can be removed by annealing the cell at about 200° C but recombination returns on exposure to light.

Several mono-crystalline and multi-crystalline solar cells have been characterized by methods such as laser beam induced current (LBIC), Four-Probe electrical resistivity etc. to better …

Carbon Nitride And Conjugated Polymer Composite Materials, Josh Byers

Electronic Thesis and Dissertation Repository

The semiconductor and photovoltaic properties of carbon nitride (CNx) thin films prepared using a reactive magnetron sputtering technique were investigated both individually and as composites with the organic conjugated polymers polybithiophene (PBT) and poly(3-hextlthiophene) (P3HT). At low nitrogen content, the film structure was dominated by graphitic sp² percolation networks, whereas at higher nitrogen contents CNx films started to demonstrate semiconductor properties, as evidenced by the occurrence of photoconductivity and the development of a space charge region. When CNx was deposited onto a PBT substrate, it was found to function as an acceptor material improving the photocurrent generation both in …

Lamination Of Inverted Organic Photovoltaics And Associated Physical Properties, Brian A. Bailey

Electronic Theses and Dissertations

This dissertation is the result of a series of studies involving hot press lamination of inverted organic photovoltaics. It first gives background and develops a lamination process for fabrication. Then, the process is used to answer fundamental questions about organic photovoltaics and to fabricate previously impossible or overly complicated devices. Finally, the author examines the scientific theory which describes the process and aligns that theory with related measurements.

The field of organic photovoltaics is introduced and the lamination process is developed and optimized. In the lamination process, part of the solar cell is deposited onto a rigid substrate, and the …

Multipolymer Interactions In Bulk Heterojunction Photovoltaic Devices, Grant Olson

Physics

Multipolymer photovoltaics, single layer devices made up of multiple photoactive polymers, can create organic photovoltaics (OPVs) with a wider spectral response than single polymer systems without the difficult fabrication of a tandem. Our group has successfully created multipolymer solar devices with 2% power conversion efficiency. We have analyzed the optical and electrical properties of these devices, and found that it may be possible for polymers to assist each other with charge extraction, though combining polymers disrupts single polymer crystallinity.

Soft X-Ray Spectroscopic Investigation Of Oxides For Renewable Energy Applications, Eric Westbrook Martin

Chancellor’s Honors Program Projects

No abstract provided.

Plasmonic Nanogels With Robustly Tunable Optical Properties, Tao Cong, Satvik N. Wani, Georo Zhou, Elia Baszczuk, Radhakrishna Sureshkumar

Biomedical and Chemical Engineering - All Scholarship

Low viscosity fluids with tunable optical properties can be processed to manufacture thin film and interfaces for molecular detection, light trapping in photovoltaics and reconfigurable optofluidic devices. In this work, self-assembly in wormlike micelle solutions is used to uniformly distribute various metallic nanoparticles to produce stable suspensions with localized, multiple wavelength or broad-band optical properties. Their spectral response can be robustly modified by varying the species, concentration, size and/or shape of the nanoparticles. Structure, rheology and optical properties of these plasmonic nanogels as well as their potential applications to efficient photovoltaics design are discussed.

Growth Of Metamorphic Ingap For Wide-Bandgap Photovoltaic Junction By Mbe, John Simon, Stephanie Tomasulo, Paul J. Simmonds, Manuel J. Romero, Minjoo Larry Lee

Paul J. Simmonds

Metamorphic triple-junction solar cells can currently attain efficiencies as high as 41.1%. Using additional junctions could lead to efficiencies above 50%, but require the development of a wide bandgap (2.0-2.2eV) material to act as the top layer. In this work we demonstrate wide bandgap In_yGa_1-yP grown on GaAs_xP_1-x via solid source molecular beam epitaxy. Unoptimized tensile GaAs_xP_1-x buffers grown on GaAs exhibit asymmetric strain relaxation, along with formation of faceted trenches 100-300 nm deep in the [01-1] direction. Smaller grading step size and higher substrate temperatures minimizes the facet trench …

Electron Injection-Induced Effects In Iii-Nitrides: Physics And Applications, William Charles Burdett

Electronic Theses and Dissertations

This research investigated the effect of electron injection in III-Nitrides. The combination of electron beam induced current and cathodoluminescence measurements was used to understand the impact of electron injection on the minority carrier transport and optical properties. In addition, the application of the electron injection effect in optoelectronic devices was investigated. The impact of electron injection on the minority carrier diffusion length was studied at various temperatures in Mg-doped p-GaN, p-Al[subscript x]Ga[subscript 1-x]N, and p-Al[subscript x]Ga[subscript 1-x] N/GaN superlattices. It was found that Lsubscript n] experienced a multi-fold linear increase and that the rate of change of L[subscript n] decreased …