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Articles 1 - 9 of 9
Full-Text Articles in Physical Sciences and Mathematics
Rotational And Hyperfine Analysis Of Aus, Ian A. Wyse
Rotational And Hyperfine Analysis Of Aus, Ian A. Wyse
Macalester Journal of Physics and Astronomy
Gas phase diatomic gold sulfide, AuS, was analyzed using optical spectroscopy. High-resolution spectra were collected and characterized and a global fit of the A2∑+-X2∏3/2 (0,0), B2∑–-X2∏3/2 (0,0), and C2Δ3/2-X2∏1/2 (0,0) transitions at 15570 cm-1, 16290 cm-1, and 17670 cm-1 was compiled and resulted in rotational constant determinations for the A2∑+((2σ)1(4π)4), B2∑–((2σ)2(4π)2(2σ*)1), and C2Δ3/2 …
Searching To Distinguish Defects And The Presence Of Negative Capacitance, Thaddeus Cox
Searching To Distinguish Defects And The Presence Of Negative Capacitance, Thaddeus Cox
Senior Theses
In the search for solar cells with lower manufacturing costs, thin film technology was developed. These thin films are only micrometers thick and are grown at relatively low temperatures, resulting in films with imperfections known as defects. Defects can cause thin film solar cells to have lower efficiencies than their single crystalline counterparts. In order to create more efficient thin film solar cells the physical mechanisms behind defects need to be investigated by sensitive techniques. Capacitance measurements of solar cells detect minute changes in charge in the material. For that reason, capacitance is used to electrically characterize the solar cell. …
Ultracold Trimer Ion Formation Of Rb And K, Michael Cantara
Ultracold Trimer Ion Formation Of Rb And K, Michael Cantara
University Scholar Projects
The cooling of molecules into the ultracold regime allows for high resolution laser spectroscopy that reveals their complex rotational and vibrational structure. As the temperature is lowered towards absolute zero, the kinetic energy of the particles approaches zero, and therefore the Doppler shift approaches zero. With the Doppler shift negligibly small, spectral resolution is now primarily limited by the natural linewidth of the molecular peaks. Further, ultracold temperatures make possible the production of atoms or molecules that will reside in the lowest few states of the system. The high population in a few select states provides stronger and less congested …
Thermal Neutron Analysis For Improvised Explosive Device Detection, Matthew David Marziale
Thermal Neutron Analysis For Improvised Explosive Device Detection, Matthew David Marziale
Open Access Dissertations
In this dissertation, the design of a system to detect improvised explosive devices is considered. The technique utilized is thermal neutron analysis. In this method, thermal neutrons are used to interrogate a volume for the presence of nitrogen, which is used as an indicator of explosive, given its unusual high energy line in the gamma ray spectrum generated by thermal capture reactions on explosive material. The performance of the system is then considered for a number of devices used to represent an improvised explosive device, including a 155 mm shell, an antitank mine, and a air to surface bomb. The …
Observations Of The High Vibrational Levels Of The B′′B̄ 1Σu+ State Of H2, Alexander M. Chartrand, W. Duan, R. C. Ekey, Elizabeth Mccormack
Observations Of The High Vibrational Levels Of The B′′B̄ 1Σu+ State Of H2, Alexander M. Chartrand, W. Duan, R. C. Ekey, Elizabeth Mccormack
Physics Faculty Research and Scholarship
Double-resonance laser spectroscopy via the E F 1Σg+, v'=6, J'=0-2 state was used to probe the high vibrational levels of the B"B-bar 1Σu+ state of molecular hydrogen. Resonantly-enhanced multiphoton ionization spectra were recorded by detecting ion production as a function of energy using a time of flight mass spectrometer. New measurements of energies for the v=51-66 levels for the B"B-bar state of H2 are reported, which, taken with previous results, span the v=46-69 vibrational levels. Results for energy levels are compared to theoretical close-coupled calculations [L. Wolniewicz, T. …
The Virtual Atomic And Molecular Data Centre (Vamdc) Consortium, Marie-Lise Dubernet, B. K. Antony, Ernesto Quintas-Sánchez, For Full List Of Authors, See Publisher's Website.
The Virtual Atomic And Molecular Data Centre (Vamdc) Consortium, Marie-Lise Dubernet, B. K. Antony, Ernesto Quintas-Sánchez, For Full List Of Authors, See Publisher's Website.
Chemistry Faculty Research & Creative Works
The Virtual Atomic and Molecular Data Centre (VAMDC) Consortium is a worldwide consortium which federates atomic and molecular databases through an e-science infrastructure and an organisation to support this activity. About 90% of the inter-connected databases handle data that are used for the interpretation of astronomical spectra and for modelling in many fields of astrophysics. Recently the VAMDC Consortium has connected databases from the radiation damage and the plasma communities, as well as promoting the publication of data from Indian institutes. This paper describes how the VAMDC Consortium is organised for the optimal distribution of atomic and molecular data for …
Identification Of Photocurrents In Topological Insulators, Derek A. Bas, Rodrigo A. Muniz, Sercan Babakiray, David Lederman, J. E. Sipe, Alan D. Bristow
Identification Of Photocurrents In Topological Insulators, Derek A. Bas, Rodrigo A. Muniz, Sercan Babakiray, David Lederman, J. E. Sipe, Alan D. Bristow
Faculty & Staff Scholarship
Optical injection and detection of charge currents is an alternative to conventional transport and photoemission measurements, avoiding the necessity of invasive contact that may disturb the system being examined. This is a particular concern for analyzing the surface states of topological insulators. In this work one- and two-color sources of photocurrents are isolated and examined in epitaxial thin films of Bi2Se3. We demonstrate that optical excitation and terahertz detection simultaneously captures one- and two-color photocurrent contributions, which has not been required for other material systems. A method is devised to extract the two components, and in doing so each can …
Terahertz Spectroscopic Breath Analysis As A Viable Analytical Chemical Sensing Technique, Robert M. Schueler
Terahertz Spectroscopic Breath Analysis As A Viable Analytical Chemical Sensing Technique, Robert M. Schueler
Browse all Theses and Dissertations
The ability to quantify trace chemicals in human breath enables the possibility of identifying breath biomarkers to aid in diagnosis. The vast majority of the studies in the analytical breath analysis rely on GC-MS techniques for quantification of the human breath composition1,2,3,4. THz spectroscopy of breath is rapid, sensitive, and highly specific molecular identification in complex mixtures containing 10-100 analytes with near `absolute' specificity. THz spectroscopic breath analyzers require chemical preconcentration. A newly developed custom preconcentrator was constructed and compared in its performance to a commercial system. Unlike the commercial counterpart, the new system does not require cryogenic liquids, is …
Excitonic States In Crystalline Organic Semiconductors: A Condensed Matter Approach, Lane Wright Manning
Excitonic States In Crystalline Organic Semiconductors: A Condensed Matter Approach, Lane Wright Manning
Graduate College Dissertations and Theses
In this work, a new condensed matter approach to the study of excitons based on crystalline thin films of the organic molecule phthalocyanine is introduced. The premise is inspired by a wealth of studies in inorganic semiconductor ternary alloys (such as AlGaN, InGaN, SiGe) where tuning compositional disorder can result in exciton localization by alloy potential fluctuations. Comprehensive absorption, luminescence, linear dichroism and electron radiative lifetime studies were performed on both pure and alloy samples of metal-free octabutoxy-phthalocyanine and transition metal octabutoxy-phthalocyanines, where the metal is Mn, Co, Ni, and Cu. Varying the ratios of the metal to metal-free phthalocyanines …