Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Physical Sciences and Mathematics
Nano-Structured Materials For Energy Storage Applications, Dongxue Zhao
Nano-Structured Materials For Energy Storage Applications, Dongxue Zhao
Doctoral Dissertations
"Hydrogen is a non-polluting and efficient energy carrier. One barrier to utilizing hydrogen is a reliable storage method. NaAlH4 is the prototypical example of a complex metal hydride with high hydrogen storage capacities (~ 5.5 wt.%) and acceptable reaction temperatures of around 100⁰ when using catalyst. On decomposition of these complex hydrides, such as NaAlH4, one is left with monohydride NaH. The kinetics of diffusion in the monohydrides is important because reversibility hinges on mass transport and the formation of [AlH4]- anions that must structurally coordinate with the alkali metal cation on hydrogen absorption. …
Silicon Nanostructures For High Capacity Anodes In Lithium Ion Batteries, Tyler M. Selden
Silicon Nanostructures For High Capacity Anodes In Lithium Ion Batteries, Tyler M. Selden
Theses and Dissertations
In this study we looked at several different silicon nanostructures grown for the purpose of optimizing anodes for lithium ion batteries. We primarily focused on two distinct types of structures, nanospirals, and Rugate structures. The samples were designed to have the mechanical robustness to endure the massive expansion caused by lithiation of silicon. All of the samples were grown using an electron beam evaporator. Scanning electron microscope images show that we have achieved the desired structural growth. The spirals were shown to have an average diameter of 343 nm on polished copper, and 366 nm on unpolished copper. The Rugate …