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Electrochemistry And Staging In La2cuo4+D, P Blakeslee, R J. Birgeneau, F C. Chou, Rebecca J. Christianson, M A. Kastner, Y S. Lee, B O. Wells
Electrochemistry And Staging In La2cuo4+D, P Blakeslee, R J. Birgeneau, F C. Chou, Rebecca J. Christianson, M A. Kastner, Y S. Lee, B O. Wells
Rebecca J. Christianson
Measurements are reported of the time dependence of the current during electrochemical oxidation and reduction at a fixed voltage of single crystals and ceramic samples of La2CuO4+d. Staging peaks in neutron measurements of the single crystals together with the electrochemical measurements and magnetization measurements confirm that stage n=6 corresponds to d=0.055 +/- 0.05, the high-d side of the oxygen-rich–oxygen-poor miscibility gap. Furthermore, stage n=4 occurs at a value of d consistent with d{n^-1. For ceramic samples it is shown that two different superconducting compounds are formed depending on the oxidation voltage used.