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Physical Sciences and Mathematics Commons

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Physics

University of Tennessee, Knoxville

Atomic Spectroscopy

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Full-Text Articles in Physical Sciences and Mathematics

Spectroscopic Imaging Of Aluminum Containing Plasma, David Michael Surmick Aug 2016

Spectroscopic Imaging Of Aluminum Containing Plasma, David Michael Surmick

Doctoral Dissertations

This dissertation aims to characterize laser-induced plasma from a physics point of view as warm, dense matter. Use of nominal nanosecond pulsed laser radiation initiates a plasma with electron temperatures of the order of 10 electron volts and electron densities of the order of air species densities at standard ambient temperature and pressure. For laser ablation and/or optical breakdown at or near a solid surface, the electron density can amount to be 1000 times greater. Spectroscopic investigations of the plasma emissions provide a method by which the electron density, temperature, and shockwave expansion may be determined. Of particular interest are …


Diatomic Carbon Measurements With Laser-Induced Breakdown Spectroscopy, Michael Jonathan Witte May 2015

Diatomic Carbon Measurements With Laser-Induced Breakdown Spectroscopy, Michael Jonathan Witte

Masters Theses

In this thesis, investigation of well-known carbon Swan spectra is of primary interest. Combustion processes and/or explosion of hydrocarbon fuels cause occurrence of the Swan band system that originates from diatomic carbon. Physical characteristics of low-temperature stars and the interstellar medium can also reveal the Swan bands. The diatomic carbon molecule shows that its lowest rotational levels are sensitive to temperature variation, and higher rotational levels are sensitive to the surrounding gas density and the radiation field. In addition, carbon is a crucial element for life and is the 4th most abundant element; therefore, it is important to ascertain accurately …


Aluminum Monoxide Emission Measurements Following Laser-Induced Breakdown For Plasma Characterization, David Michael Surmick Aug 2014

Aluminum Monoxide Emission Measurements Following Laser-Induced Breakdown For Plasma Characterization, David Michael Surmick

Masters Theses

In this work, spectroscopic emissions from laser ablated aluminum samples are used to characterize the time dependent decay of laser-induced plasma. The plasma is created by tightly focusing nanosecond pulsed laser radiation. Time resolved measurements of the plasma are made with a gated, intensified linear diode array coupled to an optical multichannel analyzer and/or an intensified charged coupled device. Time resolution is achieved by synchronizing the laser with the measurement rate of the array detector.

Computed diatomic molecular aluminum monoxide emissions were used to infer the temperature of the plasma as a function of time. This was completed by comparing …