Physical Sciences and Mathematics Commons^™

Surface Properties Of Titanium Dioxide And Its Structural Modifications By Reactions With Transition Metals, Sandamali Halpegamage

USF Tampa Graduate Theses and Dissertations

Surfaces of metal oxides play a vital role in many technologically important applications. The surfaces of titanium dioxide, in particular, show quite promising properties that can be utilized in solid-state gas sensing and photocatalysis applications. In the first part of this dissertation we investigate these properties of TiO₂ surfaces through a vigorous surface scientific approach. In the second part, we investigate the possibilities of modifying the TiO₂ surfaces by depositing multi-component transition metal oxide monolayers so that the properties of bare TiO₂ surface can be influenced in a beneficial way. For instance, via formation of new surface …